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Shibkovite

A valid IMA mineral species

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Photos of Shibkovite (5)

Shibkovite Gallery Search Photos of Shibkovite

Edit Add Synonym Edit CIF structures Clear Cache

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Shibkovite, etc.

Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

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About ShibkoviteHide

Formula:

K(◻K)Ca₂Zn₃[Si₁₂O₃₀]

Previously given as K(□,K,Na)₂Zn₃Ca₂[Si₁₂O₃₀].

Colour:

Colourless, white

Lustre:

Vitreous

Hardness:

5½ - 6

Specific Gravity:

2.89

Crystal System:

Hexagonal

Member of:

Osumilite Group

Name:

Named after two prominent Russian geologists, Viktor Sergeevitch Shibkov (Виктор Сергеевич Шибков) (1926-1992) and Nikolai Viktorovitch Shibkov (Николай Викторович Шибков) (1951-1991), who both spent their professional lives working on the geology of Soviet Asia.

Type Locality:

ⓘ Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

Osumilite Group. A possibly related mineral is known as UM1990-73-SiO:KMnNaZn.

Unique IdentifiersHide

Mindat ID:

7290

Long-form identifier:

mindat:1:1:7290:4

GUID
(UUID V4):

b3a6f10d-d3aa-4662-970b-344b6aa444b6

IMA Classification of ShibkoviteHide

IMA status:

Approved

IMA Formula:

K₂Ca₂(Zn₃Si₁₂)O₃₀

First published:

1998

Type description reference:

Pautov, L. A., Agakhanov, A. A., Sokolova, E. V. (1998) Shibkovite K(Ca,Mn,Na)₂(K_2-x□_x)₂Zn₃Si₁₂O₃₀ — the new mineral from the milarite group. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 127 (4) 89-94

Classification of ShibkoviteHide

Strunz-mindat (2024):

9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si₆O₁₈]₁₂- 6-membered double rings (sechser-Doppelringe)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Sko	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ShibkoviteHide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

Colourless, white

Streak:

White

Hardness:

5½ - 6 on Mohs scale

Hardness:

VHN₅₀=609 kg/mm² - Vickers

Tenacity:

Brittle

Density:

2.89(2) g/cm³ (Measured) 2.90(5) g/cm³ (Calculated)

Optical Data of ShibkoviteHide

Type:

Uniaxial (+)

RI values:

n_ω = 1.561 n_ε = 1.563

Max Birefringence:

δ = 0.002

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Low

Chemistry of ShibkoviteHide

Mindat Formula:

K(◻K)Ca₂Zn₃[Si₁₂O₃₀]

Previously given as K(□,K,Na)₂Zn₃Ca₂[Si₁₂O₃₀].

Elements listed:

Ca, K, O, Si, Zn - search for minerals with similar chemistry

Crystallography of ShibkoviteHide

Crystal System:

Hexagonal

Class (H-M):

6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal

Space Group:

P6/mcc

Cell Parameters:

a = 10.505 Å, c = 14.185 Å

Ratio:

a:c = 1 : 1.35

Unit Cell V:

1,355.66 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0012494	Shibkovite	Sokolova E V, Rybakov V B, Pautov L A (1999) Crystal structure of shibkovite Doklady Akademii Nauk SSSR 369 378-380		1999		0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Shibkovite'
loop_
_publ_author_name
'Sokolova E V'
'Rybakov V B'
'Pautov L A'
_journal_name_full 'Doklady Akademii Nauk SSSR'
_journal_volume 369 
_journal_year 1999
_journal_page_first 378
_journal_page_last 380
_publ_section_title
;
 Crystal structure of shibkovite
;
_database_code_amcsd 0012494
_chemical_formula_sum '(Ca1.26 Mn.4 Na.34) K2.26 Zn3 Si12 O30'
_cell_length_a 10.502
_cell_length_b 10.502
_cell_length_c 14.184
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1354.794
_exptl_crystal_density_diffrn      2.897
_symmetry_space_group_name_H-M 'P 6/m c c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-x+y,1/2+z'
  'x,x-y,1/2-z'
  '-x+y,-x,-z'
  'x-y,x,z'
  '-y,-x,1/2+z'
  'y,x,1/2-z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x-y,-y,1/2+z'
  '-x+y,y,1/2-z'
  'x,y,-z'
  '-x,-y,z'
  'x,x-y,1/2+z'
  '-x,-x+y,1/2-z'
  'x-y,x,-z'
  '-x+y,-x,z'
  'y,x,1/2+z'
  '-y,-x,1/2-z'
  '-y,x-y,-z'
  'y,-x+y,z'
  '-x+y,y,1/2+z'
  'x-y,-y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
CaA   0.33333   0.66667   0.25000   0.63000   0.01026
MnA   0.33333   0.66667   0.25000   0.20000   0.01026
NaA   0.33333   0.66667   0.25000   0.17000   0.01026
KB   0.33333   0.66667   0.00000   0.63000   0.01760
KC   0.00000   0.00000   0.25000   1.00000   0.01482
ZnT2   0.00000   0.50000   0.25000   1.00000   0.01001
SiT1   0.09800   0.33580   0.11210   1.00000   0.00507
O1   0.10980   0.36760   0.00000   1.00000   0.01520
O2   0.20450   0.27070   0.13930   1.00000   0.01343
O3   0.14030   0.48310   0.16740   1.00000   0.01026

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
7.11 Å	(35)
3.830 Å	(100)
3.345 Å	(60)
3.304 Å	(40)
2.940 Å	(50)
2.795 Å	(85)
2.627 Å	(35)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ShibkoviteHide

Type Locality:

ⓘ Dara-i-Pioz Massif, Districts of Republican Subordination, Tajikistan

General Appearance of Type Material:

Occurs as white to colorless equant grains, to 0.5 mm, resembling quartz.

Place of Conservation of Type Material:

Museum of the Ilmensky National Park at Miass, Russia, and in the A. E. Fersman Mineralogical Museum, Moscow, Russia.

Associated Minerals at Type Locality:

Turkestanite	Sogdianite	Reedmergnerite	Pyrochlore Group	Polylithionite
Pectolite	Eudialyte Group	Albite	Aegirine

Reference:

Pautov, L.A., Agakhanov, A.A., Sokolova, E.V. (1998) Shibkovite K(Ca,Mn,Na)2(K2-x□x)2Zn3Si12O30 — the new mineral from the milarite group. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 127(4): 89-94.

Download:

https://rruff.info/rruff_1.0/uploads/ZVMO127N4_89.pdf

Synonyms of ShibkoviteHide

IMA1997-018

Other Language Names for ShibkoviteHide

German:Shibkovit

Simplified Chinese:钾钙锌大隅石

Spanish:Shibkovita

Traditional Chinese:鉀鈣鋅大隅石

Relationship of Shibkovite to other SpeciesHide

Member of:

Osumilite Group

Other Members of this group:

Agakhanovite-(Y)	K◻₂(YCa)Be₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Almarudite	K◻₂Mn²⁺₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
Aluminosugilite	KNa₂Al₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Armenite	Ba(H₂O)₂Ca₂Al₃[Al₃Si₉O₃₀]	Orth. mmm (2/m 2/m 2/m) : Pnna
Berezanskite	K◻₂Ti₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Brannockite	K◻₂Sn₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Chayesite	K◻₂Mg₂(Mg₂Fe³⁺)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Darapiosite	KNa₂Mn₂(Zn₂Li)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Dusmatovite	K(K◻)Mn²⁺₂Zn₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Eifelite	KNa₂(MgNa)Mg₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Friedrichbeckeite	K(◻Na)Mg₂(Be₂Mg)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Klöchite	K◻₂(Fe²⁺Fe³⁺)Zn₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mmc
Laurentthomasite	K◻₂Mg₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Merrihueite	K(◻Na)Fe²⁺₂Fe²⁺₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Milarite	K(◻H₂O)Ca₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Oftedalite	K◻₂(ScCa)Be₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Osumilite	K◻₂Fe²⁺₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Osumilite-(Mg)	K◻₂Mg₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Poudretteite	K◻₂Na₂B₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Roedderite	K(◻Na)Mg₂Mg₃[Si₁₂O₃₀]	Hex. 6 m2 : P6₂c
Sogdianite	K◻₂Zr₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Sugilite	KNa₂Fe³⁺₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Trattnerite	◻(◻)₂Fe³⁺₂Mg₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
UM1990-73-SiO:KMnNaZn	K(KNa_0.5◻_0.5)(Mn_1.5Na_0.5)Zn₃[Si₁₂O₃₀]	Hex.
Unnamed (Mn3+-dominant analog of Sugilite)	KNa₂Mn³⁺₂Li₃[Si₁₂O₃₀]
Yagiite	Na◻₂Mg₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc

Common AssociatesHide

Associated Minerals Based on Photo Data:

4 photos of Shibkovite associated with Reedmergnerite	NaBSi₃O₈
4 photos of Shibkovite associated with Telyushenkoite	(Cs,Na,K)Na₆[Be₂Al₃Si₁₅O₃₉]F₂
3 photos of Shibkovite associated with Pyrochlore Group	A₂Nb₂(O,OH)₆Z
3 photos of Shibkovite associated with Quartz	SiO₂
1 photo of Shibkovite associated with Polylithionite	KLi₂Al(Si₄O₁₀)(F,OH)₂

Related Minerals - Strunz-mindat Grouping Hide

9.CM.	Agakhanovite-(Y)	K◻₂(YCa)Be₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Armenite	Ba(H₂O)₂Ca₂Al₃[Al₃Si₉O₃₀]	Orth. mmm (2/m 2/m 2/m) : Pnna
9.CM.05	Brannockite	K◻₂Sn₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Chayesite	K◻₂Mg₂(Mg₂Fe³⁺)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Darapiosite	KNa₂Mn₂(Zn₂Li)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Eifelite	KNa₂(MgNa)Mg₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Merrihueite	K(◻Na)Fe²⁺₂Fe²⁺₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Milarite	K(◻H₂O)Ca₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Osumilite-(Mg)	K◻₂Mg₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Osumilite	K◻₂Fe²⁺₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Poudretteite	K◻₂Na₂B₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Roedderite	K(◻Na)Mg₂Mg₃[Si₁₂O₃₀]	Hex. 6 m2 : P6₂c
9.CM.05	Sogdianite	K◻₂Zr₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Sugilite	KNa₂Fe³⁺₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Yagiite	Na◻₂Mg₂Al₃[Al₂Si₁₀O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Berezanskite	K◻₂Ti₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Dusmatovite	K(K◻)Mn²⁺₂Zn₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Almarudite	K◻₂Mn²⁺₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.CM.05	Trattnerite	◻(◻)₂Fe³⁺₂Mg₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Oftedalite	K◻₂(ScCa)Be₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	Klöchite	K◻₂(Fe²⁺Fe³⁺)Zn₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mmc
9.CM.05	Friedrichbeckeite	K(◻Na)Mg₂(Be₂Mg)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05	UM1990-73-SiO:KMnNaZn	K(KNa_0.5◻_0.5)(Mn_1.5Na_0.5)Zn₃[Si₁₂O₃₀]	Hex.
9.CM.05	Laurentthomasite	K◻₂Mg₂(Be₂Al)[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.9.CM.	Aluminosugilite	KNa₂Al₂Li₃[Si₁₂O₃₀]	Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.10	Faizievite	K₂Na(Ca₆Na)Ti₄Li₆[Si₆O₁₈]₂[Si₁₂O₃₀]F₂	Tric. 1 : P1

Fluorescence of ShibkoviteHide

In UV light:

Bright red fluorescence in short-wave ultraviolet light

Other InformationHide

IR Spectrum:

Bands at 495, 530, 575, 700, 790, 920, 940, 1000, 1048, and 1105 cm–1.

Notes:

Insoluble in water and 1:1 HCl

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ShibkoviteHide

mindat.org URL:

https://www.mindat.org/min-7290.html
Please feel free to link to this page.

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External Links:

Look for Shibkovite on Webmineral

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for ShibkoviteHide

Reference List:

Sokolova, E.V., Rybakov, V.B., Pautov, L.A. (1999) Crystal structure of shibkovite. Doklady Akademii Nauk: 369: 378-380.

Sokolova, E.V., Rybakov, V.B., Pautov, L.A. (1999) Crystal structure of shibkovite. Doklady Earth Sciences: 369A: 1288-1290.

Jambor, John L., Puziewicz, Jacek, Roberts, Andrew C. (2000) New Mineral Names. American Mineralogist, 85. 627-630

Pekov, I.V. (2007) New minerals from former Soviet Union countries, 1998-2006: new minerals approved by the IMA commission on new minerals and mineral names. Mineralogical Almanac: 11: 9-51.

Gagné, Olivier C., Hawthorne, Frank C. (2016) Chemographic Exploration of the Milarite-Type Structure. The Canadian Mineralogist, 54 (5) 1229-1247 doi:10.3749/canmin.1500088

(2023) Shibkovite. Handbook of Mineralogy. Mineralogical Society of America

Localities for ShibkoviteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Tajikistan (TL)

Districts of Republican Subordination

ⓘ Dara-i-Pioz Massif (TL)

Pautov et al. (1998) +1 other reference

Shibkovite

About ShibkoviteHide

Unique IdentifiersHide

IMA Classification of ShibkoviteHide

Classification of ShibkoviteHide

Mineral SymbolsHide

Physical Properties of ShibkoviteHide

Optical Data of ShibkoviteHide

Chemistry of ShibkoviteHide

Crystallography of ShibkoviteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of ShibkoviteHide

Synonyms of ShibkoviteHide

Other Language Names for ShibkoviteHide

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Related Minerals - Strunz-mindat GroupingHide

Fluorescence of ShibkoviteHide

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Related Minerals - Strunz-mindat Grouping Hide