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Uranotungstite

A valid IMA mineral species
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About UranotungstiteHide

Formula:
(Ba0.35Pb0.27)Σ0.62[(U6+O2)2(W6+0.98Fe3+0.260.75)O4.7(OH)2.5(H2O)1.75](H2O)1.67
Formular originally assumed to be (Fe2+,Ba,Pb)(UO2)2(WO4)(OH)4 · 12H2O (Walenta, 1985).
Colour:
Yellow, orange, brown, blackish
Lustre:
Pearly, Dull
Hardness:
2
Specific Gravity:
>4.03
Crystal System:
Monoclinic
Name:
The name reflects its composition: Uranium and Tungsten.
Originally assumed to be orthorhombic and having the chemical formula (Fe2+,Ba,Pb)(UO2)2(WO4)(OH)4 · 12H2O (Walenta, 1985). A restudy of type material and other material, including a crystal-structure determination, showed the mineral to be in fact monoclinic, with space group P21/m, and to have a fairly different formula (Steciuk et al., 2022).

Unique combination of elements (status: 2023); the first mineral with species-defining Ba & W (compare ronpetersonite).


Unique IdentifiersHide

Mindat ID:
4115
Long-form identifier:
mindat:1:1:4115:3
GUID
(UUID V4):
33a84997-ae2d-490a-beeb-396515ba1668

IMA Classification of UranotungstiteHide

Classification of UranotungstiteHide

7.HB.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
H : Uranium and uranyl molybdates and wolframates
B : With U6+
49.3.5.1

49 : HYDRATED MOLYBDATES AND TUNGSTATES
3 : Hydrated Molybdates and Tungstates Containing Hydroxyl or Halogen
27.4.12

27 : Sulphites, Chromates, Molybdates and Tungstates
4 : Tungstates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
UtgsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of UranotungstiteHide

Pearly, Dull
Transparency:
Translucent
Colour:
Yellow, orange, brown, blackish
Streak:
Yellow
Hardness:
Cleavage:
Perfect
{010}
Fracture:
Irregular/Uneven
Density:
>4.03 g/cm3 (Measured)    4.27 g/cm3 (Calculated)

Optical Data of UranotungstiteHide

Type:
Biaxial (-)
RI values:
nα = 1.682(5) nβ = 1.845(5) nγ = 1.855(5)
2V:
Measured: 42° , Calculated: 24°
Max Birefringence:
δ = 0.173
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r > v moderate
Pleochroism:
Visible
Comments:
X = nearly colorless, Y = Z = yellow
Comments:
X = b

Chemistry of UranotungstiteHide

Mindat Formula:
(Ba0.35Pb0.27)Σ0.62[(U6+O2)2(W6+0.98Fe3+0.260.75)O4.7(OH)2.5(H2O)1.75](H2O)1.67

Formular originally assumed to be (Fe2+,Ba,Pb)(UO2)2(WO4)(OH)4 · 12H2O (Walenta, 1985).

Crystallography of UranotungstiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 6.318(5) Å, b = 7.388(9) Å, c = 13.71(4) Å
β = 99.04(13)°
Ratio:
a:b:c = 0.855 : 1 : 1.856
Unit Cell V:
632.00 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Tabular, lath-shaped (pseudo-orthorhombic).
Twinning:
Pervasive, parallel to the platey face (Kolitsch and Plášil, unpublished data).
Comment:
Originally assumed to be orthorhombic, with a = 9.22, b = 13.81, c = 7.17 Å (Walenta, 1985).

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.96 Å(10)
4.60 Å(6)
3.46 Å(5)
3.21 Å(7)
3.01 Å(3)
2.77 Å(4)
1.970 Å(4)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶⁺) minerals]

Type Occurrence of UranotungstiteHide

General Appearance of Type Material:
Spherulitic aggregates up to 0.3 mm in diameter.
Place of Conservation of Type Material:
University of Stuttgart, Stuttgart, Germany.
Associated Minerals at Type Locality:
Reference:
Walenta, K. (1985): Uranotungstit, ein neues sekundäres Uranmineral aus dem Schwarzwald. Tschermaks Mineralogische und Petrographische Mitteilungen: 34, 25-34.

Synonyms of UranotungstiteHide

Other Language Names for UranotungstiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Uranotungstite associated with ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
3 photos of Uranotungstite associated with MetatorberniteCu(UO2)2(PO4)2 · 8H2O
2 photos of Uranotungstite associated with GearksutiteCa[Al(F,OH)5(H2O)]
2 photos of Uranotungstite associated with TyuyamuniteCa(UO2)2(VO4)2 · 5-8H2O
2 photos of Uranotungstite associated with NováčekiteMg(UO2)2(AsO4)2 · 10H2O
1 photo of Uranotungstite associated with ProsopiteCaAl2F4[(OH)4-xFx]
1 photo of Uranotungstite associated with TorberniteCu(UO2)2(PO4)2 · 12H2O
1 photo of Uranotungstite associated with FluoriteCaF2

Related Minerals - Strunz-mindat GroupingHide

7.HB.15CalcurmoliteCa[(UO2)3(MoO4)2(OH)4](H2O)~5.0Mon.
7.HB.20TengchongiteCa(UO2)6(MoO4OH)2O2(OH)4 · 9H2OOrth. 2 2 2

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for UranotungstiteHide

References for UranotungstiteHide

Localities for UranotungstiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France
 
  • Auvergne-Rhône-Alpes
    • Allier
      • Vichy
        • Échassières
          • Montmins mining district
Cuchet et al. (2000)
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • Le Pradet
          • Cap Garonne Mine
Georges FAVREAU collection & EDX ...
Germany (TL)
 
  • Baden-Württemberg
    • Freiburg Region
      • Ortenaukreis
        • Oberwolfach
Walenta (1985) +2 other references
      • Waldshut
        • St Blasien
          • Menzenschwand
Walenta (1985) +1 other reference
Namibia
 
  • Erongo Region
    • Dâures Constituency
Schnaitmann et al. (2007)
    • Karibib Constituency
von Bezing (2007)
Russia
 
  • Chukotka Autonomous Okrug
    • Iultinsky District
Alekseev et al. (2015)
 
矿物 and/or 产地  
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