Tilleyite
A valid IMA mineral species - grandfathered
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About Tilleyite
Formula:
Ca5(Si2O7)(CO3)2
Colour:
Colourless, white
Lustre:
Vitreous, Dull
Specific Gravity:
2.838
Crystal System:
Monoclinic
Name:
Named after Cecil Edgar Tilley (May 14, 1894 Unley, Adelaide, South Australia - January 24, 1973 Cambridge, UK), Professor of Petrology, University of Cambridge (England).
This page provides mineralogical data about Tilleyite.
Unique Identifiers
Mindat ID:
3964
Long-form identifier:
mindat:1:1:3964:8
GUID
(UUID V4):
(UUID V4):
68e774fa-8455-415c-bd47-dd5814fd38a5
IMA Classification of Tilleyite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca5Si2O7(CO3)2
First published:
1933
Classification of Tilleyite
9.BE.82
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.2.9.1
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
17.4.1
17 : Silicates Containing other Anions
4 : Silicates with carbonates
17 : Silicates Containing other Anions
4 : Silicates with carbonates
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Tly | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Tly | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Til | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Tilleyite
Vitreous, Dull
Transparency:
Transparent, Translucent
Colour:
Colourless, white
Streak:
White
Cleavage:
Perfect
Perfect on {201}; poor on {100} and {010}; very poor on
{001}.
Perfect on {201}; poor on {100} and {010}; very poor on
{001}.
Density:
2.838 g/cm3 (Measured) 2.88 g/cm3 (Calculated)
Optical Data of Tilleyite
Type:
Biaxial (+)
RI values:
nα = 1.605 - 1.617 nβ = 1.626 - 1.635 nγ = 1.651 - 1.654
2V:
Measured: 85° to 89°, Calculated: 88° to 90°
Max Birefringence:
δ = 0.046
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v
Comments:
Y = b; X Λ c = 24°; Z Λ a = 38°.
Chemistry of Tilleyite
Mindat Formula:
Ca5(Si2O7)(CO3)2
Elements listed:
Crystallography of Tilleyite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 15.108(3) Å, b = 10.241(1) Å, c = 7.579(1) Å
β = 105.17(1)°
β = 105.17(1)°
Ratio:
a:b:c = 1.475 : 1 : 0.74
Unit Cell V:
1,131.77 ų (Calculated from Unit Cell)
Z:
4
Twinning:
On {100} simple; rarely, lamellar.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0006060 | Tilleyite | Grice J D (2005) The structure of spurrite, tilleyite and scawtite, and relationships to other silicate-carbonate minerals The Canadian Mineralogist 43 1489-1500 | 2005 | Cornet Hill, Apuseni Mountains, Romania | 0 | 293 | |
0009150 | Tilleyite | Smith J V (1953) The crystal structure of tilleyite Acta Crystallographica 6 9-18 | 1953 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
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Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.01 Å | (100) |
3.10 Å | (60) |
1.896 Å | (45) |
2.982 Å | (40) |
2.803 Å | (40) |
2.100 Å | (40) |
3.19 Å | (30) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
31 : Thermally altered carbonate, phosphate, and iron formations | |
Stage 5: Initiation of plate tectonics | <3.5-2.5 |
40 : Regional metamorphism (greenschist, amphibolite, granulite facies) |
Type Occurrence of Tilleyite
General Appearance of Type Material:
White patches
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, 97301.
National Museum of Natural History, Washington, D.C., USA, 97246.
National Museum of Natural History, Washington, D.C., USA, 97246.
Geological Setting of Type Material:
Contact metamorphic zone between igneous rocks and limestones; low pressure and high temperature.
Associated Minerals at Type Locality:
Reference:
Larsen, E.S., Dunham, K.C. (1933) Tilleyite, a new mineral from the contact zone at Crestmore, California. American Mineralogist: 18: 469-473.
Other Language Names for Tilleyite
Common Associates
Associated Minerals Based on Photo Data:
4 photos of Tilleyite associated with Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
4 photos of Tilleyite associated with Wollastonite | Ca3(Si3O9) |
3 photos of Tilleyite associated with Calcite | CaCO3 |
1 photo of Tilleyite associated with Magnetite | Fe2+Fe3+2O4 |
1 photo of Tilleyite associated with Diopside | CaMgSi2O6 |
Related Minerals - Strunz-mindat Grouping
9.BE. | Paralomonosovite | Na6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF) |
9.BE. | Cámaraite | Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7 |
9.BE. | Christofschäferite-(Ce) | Ce3CaMnTiFe(3+)Ti2(Si2O7)2O8 |
9.BE. | Bobshannonite | Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2 |
9.BE. | Calciomurmanite | (Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4 |
9.BE. | Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 |
9.BE. | Delhuyarite-(Ce) | Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2 |
9.BE.X | Asimowite | Fe2+4O(Si2O7) |
9.BE. | Moxuanxueite | NaCa6Zr(Si2O7)2OF3 |
9.BE. | Alexkuznetsovite-(Ce) | Ce2Mn(CO3)(Si2O7) |
9.BE. | Biraite-(La) | La2Fe2+(CO3)(Si2O7) |
9.BE. | Zinkgruvanite | Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2 |
9.BE. | Madeiraite | Na2Ca2Fe2Zr2(Si2O7)2O2F2 |
9.BE. | Bortolanite | Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2 |
9.BE. | Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 |
9.BE. | Pilanesbergite | Na2Ca2Fe2Ti2(Si2O7)2O2F2 |
9.BE. | Alfredcasparite | Sr2TiO(Si2O7) |
9.BE.02 | Wadsleyite | Mg4O(Si2O7) |
9.BE.05 | Hennomartinite | SrMn3+2(Si2O7)(OH)2 · H2O |
9.BE.05 | Lawsonite | CaAl2(Si2O7)(OH)2 · H2O |
9.BE.05 | Noelbensonite | BaMn3+2(Si2O7)(OH)2 · H2O |
9.BE.05 | Itoigawaite | SrAl2(Si2O7)(OH)2 · H2O |
9.BE.05 | Cortesognoite | CaV2(Si2O7)(OH)2 · H2O |
9.BE.07 | Ilvaite | CaFe3+Fe2+2(Si2O7)O(OH) |
9.BE.07 | Manganilvaite | CaFe2+Fe3+Mn2+(Si2O7)O(OH) |
9.BE.07 | Amamoorite | CaMn2+2Mn3+(Si2O7)O(OH) |
9.BE.10 | Suolunite | Ca2(H2Si2O7) · H2O |
9.BE.12 | Jaffeite | Ca6(Si2O7)(OH)6 |
9.BE.15 | Fresnoite | Ba2Ti(Si2O7)O |
9.BE.17 | Baghdadite | Ca6Zr2(Si2O7)2O4 |
9.BE.17 | Burpalite | Na2CaZr(Si2O7)F2 |
9.BE.17 | Cuspidine | Ca8(Si2O7)2F4 |
9.BE.17 | Hiortdahlite | Na2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3 |
9.BE.17 | Janhaugite | (Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2 |
9.BE.17 | Låvenite | Na2Ca2Mn2Zr2(Si2O7)2O2F2 |
9.BE.17 | Niocalite | (Ca,Nb)4(Si2O7)(O,OH,F)2 |
9.BE.17 | Normandite | NaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OF |
9.BE.17 | Wöhlerite | Na2Ca4ZrNb(Si2O7)2O3F |
9.BE.20 | Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2 |
9.BE.20 | Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 |
9.BE.20 | Roumaite | (Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3 |
9.BE.20 | Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 |
9.BE.22 | Götzenite | NaCa6Ti(Si2O7)2OF3 |
9.BE.22 | Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 |
9.BE.22 | Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 |
9.BE.22 | Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 |
9.BE.22 | Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 |
9.BE.23 | Dovyrenite | Ca6Zr(Si2O7)2(OH)4 |
9.BE.25 | Barytolamprophyllite | (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F) |
9.BE.25 | Ericssonite | BaMn2+2Fe3+(Si2O7)O(OH) |
9.BE.25 | Lamprophyllite | (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2 |
9.BE.25 | Ericssonite-2O | BaMn2+2Fe3+(Si2O7)O(OH) |
9.BE.25 | Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 |
9.BE.25 | Nabalamprophyllite | (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2 |
9.BE.25 | Grenmarite | Na4MnZr3(Si2O7)2O2F2 |
9.BE.25 | Schüllerite | Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4 |
9.BE.25 | Kazanskyite | BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4 |
9.BE.25 | Lileyite | Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2 |
9.BE.25 | Emmerichite | Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2 |
9.BE.25 | Saamite | Ba◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2 |
9.BE.25 | Fluorlamprophyllite | Na3(SrNa)Ti3(Si2O7)2O2F2 |
9.BE.25 | Fluorbarytolamprophyllite | (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2] |
9.BE.27 | Murmanite | Na2Ti2(Si2O7)O2 · 2H2O |
9.BE.27 | Vigrishinite | NaZnTi4(Si2O7)2O3(OH)(H2O)4 |
9.BE.27 | Kolskyite | CaNa2Ti4(Si2O7)2O4(H2O)7 |
9.BE.27 | Selivanovaite | NaFe3+Ti4(Si2O7)2O4(H2O)4 |
9.BE.30 | Epistolite | (Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4 |
9.BE.32 | Lomonosovite | Na5Ti2(Si2O7)(PO4)O2 |
9.BE.35 | Vuonnemite | Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH) |
9.BE.37 | Sobolevite | Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3 |
9.BE.40 | Innelite | Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)] |
9.BE.40 | Phosphoinnelite | Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2F |
9.BE.42 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) |
9.BE.45 | Quadruphite | Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2 |
9.BE.47 | Polyphite | Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2 |
9.BE.50 | Bornemanite | Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F |
9.BE.50 | Shkatulkalite | Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3 |
9.BE.55 | Bafertisite | Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2 |
9.BE.55 | Hejtmanite | Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2 |
9.BE.55 | Bykovaite | (Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2O |
9.BE.55 | Nechelyustovite | (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2O |
9.BE.60 | Delindeite | (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2O |
9.BE.62 | Orthochevkinite | (Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22 |
9.BE.62 va | Strontium Perrierite | (Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8 |
9.BE.62 | Chevkinite-(Nd) | (Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ? |
9.BE.62 | Perrierite-(Nd) | Nd4MgFe3+2Ti2(Si2O7)2O8 ? |
9.BE.65 | Bussenite | Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3F |
9.BE.67 | Jinshajiangite | BaNaFe2+4Ti2(Si2O7)2O2(OH)2F |
9.BE.67 | Perraultite | BaNaMn2+4Ti2(Si2O7)2O2(OH)2F |
9.BE.70 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O |
9.BE.70 | Perrierite-(Ce) | Ce4MgFe3+2Ti2(Si2O7)2O8 |
9.BE.70 | Strontiochevkinite | (Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8 |
9.BE.70 | Chevkinite-(Ce) | Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2 |
9.BE.70 | Polyakovite-(Ce) | (Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8 |
9.BE.70 | Rengeite | Sr4ZrTi4(Si2O7)2O8 |
9.BE.70 | Matsubaraite | Sr4Ti5(Si2O7)2O8 |
9.BE.70 | Dingdaohengite-(Ce) | (Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8 |
9.BE.70 | Maoniupingite-(Ce) | (Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8 |
9.BE.70 | Perrierite-(La) | (La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2 |
9.BE.70 | UM2008-53-SiO:SrTiZr | Sr4ZrTi4(Si2O7)2O8 |
9.BE.70 | Hezuolinite | (Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8 |
9.BE.72 | Fersmanite | Ca4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3 |
9.BE.75 | Belkovite | Ba3(Nb,Ti)6(Si2O7)2O12 |
9.BE.77 | Nasonite | Pb6Ca4(Si2O7)3Cl2 |
9.BE.80 | Kentrolite | Pb2Mn3+2(Si2O7)O2 |
9.BE.80 | Melanotekite | Pb2Fe3+2(Si2O7)O2 |
9.BE.82 | Alexkuznetsovite-(La) | La2Mn(CO3)(Si2O7) |
9.BE.85 | Killalaite | Ca6.4(H0.6Si2O7)2(OH)2 |
9.BE.87 | Stavelotite-(La) | (La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30 |
9.BE.90 | Biraite-(Ce) | Ce2Fe2+(Si2O7)(CO3) |
9.BE.90 | Magnesiorowlandite-(Y) | Y4(Mg,Fe)(Si2O7)2F2 |
9.BE.92 | Cervandonite-(Ce) | (Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH) |
9.BE.92 | Chirvinskyite | (Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2O |
9.BE.95 | Batisivite | BaV3+8Ti6(Si2O7)O22 |
9.BE.95 | Rusinovite | Ca10(Si2O7)3Cl2 |
9.BE.97 | Schlüterite-(Y) | (Y,REE)2AlSi2O7(OH)2F |
Other Information
Notes:
Effervesces vigorously with cold dilute hydrochloric acid, and gelatinizes.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tilleyite
mindat.org URL:
https://www.mindat.org/min-3964.html
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References for Tilleyite
Reference List:
Localities for Tilleyite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Rubenach et al. (1985) +1 other reference |
Ireland | |
| S. R. Nockolds and H. G. C. Vincent (1947) |
Japan | |
| Kusachi et al (1971) |
Yamada (2004) | |
| Anthony et al. (1990) |
| Dr. Matsuo Nambu ore collection (curated at Geological Survey of Japan) +1 other reference |
| Henmi et al. (1973) +1 other reference |
Jordan | |
| Fleurance et al. (2013) |
| Sokol +9 other references |
Norway | |
| Jamtveit et al. (1997) |
Romania | |
| Constantinescu et al. (1988b) +3 other references |
| The Canadian Mineralogist Vol. 39 (2001) |
Canadian Mineralogist: 39: 1435-1453. +2 other references | |
Marincea et al. (2001) +2 other references | |
Russia | |
| Sokol et al. (2019) +1 other reference |
| Reverdatto et al. (1979) |
Tanzania | |
| Mineralogical Magazine 1997 61 : 779-789 +1 other reference |
Turkey | |
| Taner et al. (2013) |
UK | |
| Tilley (1947) |
| Beard et al. (2007) |
| Agrell (1965) |
USA (TL) | |
| Larsen et al. (1933) |
| American Mineralogist: 26: 367. +2 other references |
| Northrop et al. (1996) |
| Rocks & Minerals (1991) |
| Rocks & Minerals: 66 (3) |
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Crestmore quarries, Crestmore, Jurupa Valley, Riverside County, California, USA