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Camaronesite

A valid IMA mineral species
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About CamaronesiteHide

07947300016114496285720.jpg
Camarones Valley, Chile
Formula:
[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O
Colour:
Lavender
Lustre:
Vitreous
Hardness:
Specific Gravity:
2.43
Crystal System:
Trigonal
Name:
Named for the Camarones Valley, Chile; the type locality.
Structurally related to taranakite and synthetic NASICON-type compounds.


Unique IdentifiersHide

Mindat ID:
43753
Long-form identifier:
mindat:1:1:43753:8
GUID
(UUID V4):
09882b95-c4b6-43a9-90e6-5fa29c1e61e1

IMA Classification of CamaronesiteHide

Classification of CamaronesiteHide

8.DB.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CmrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CamaronesiteHide

Vitreous
Transparency:
Transparent
Colour:
Lavender
Comment:
The pale lavender colour of camaronesite is a direct result of the placement of Fe3+ in the crystal structure and, in particular, the isolation of each Fe3+ octahedron from other Fe3+ octahedra by intervening sulfate or phosphate tetrahedra such that no two Fe3+ octahedra share a common face, edge or vertex
Streak:
white
Hardness:
2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{001}
Fracture:
Irregular/Uneven, Conchoidal, Step-Like
Density:
2.43(1) g/cm3 (Measured)    2.383 g/cm3 (Calculated)
Comment:
crystals generally contain inclusions of anhydrite, this value is probably too high

Optical Data of CamaronesiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.612(1) nε = 1.621(1)
Max Birefringence:
δ = 0.009
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
O (pale lavender) > E (colourless).

Chemistry of CamaronesiteHide

Mindat Formula:
[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2O

Crystallography of CamaronesiteHide

Crystal System:
Trigonal
Class (H-M):
3 2 - Trapezohedral
Space Group:
R3 2
Cell Parameters:
a = 9.0833(5) Å, c = 42.944(3) Å
Ratio:
a:c = 1 : 4.728
Unit Cell V:
3068.5 ų
Z:
9

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.74 Å(45)
7.415 Å(100)
4.545 Å(72)
4.426 Å(26)
3.862 Å(32)
3.298 Å(93)
3.179 Å(25)
2.818 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of CamaronesiteHide

General Appearance of Type Material:
crystals up to several mm across form dense intergrowths. More rarely crystals occur as drusy aggregates of tablets up to 0.5 mm in diameter and 0.02 mm thick
Place of Conservation of Type Material:
Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, California 90007, USA under catalogue numbers 64023, 64024, 64025, 64026 and 64027. Specimens 64023–64026 are from the first boulder found. Specimen 64027 is from the sec
Geological Setting of Type Material:
a low-temperature, secondary mineral occurring in a sulfate assemblage
Associated Minerals at Type Locality:
Reference:
Kampf, A.R., Mills, S.J., Nash, B.P., Housley, R.M., Rossman, G.R., Dini, M., Gatta G.D. (2013) Camaronesite, [Fe3+(H2O)2(PO3OH)]2(SO4)•1–2H2O, a new phosphate-sulfate from the Camarones Valley, Chile, structurally related to taranakite. Mineralogical Magazine: 77: 453-465.

Synonyms of CamaronesiteHide

Related Minerals - Strunz-mindat GroupingHide

8.DB.ArangasiteAl2F(PO4)(SO4) · 9H2O Mon. 2/m : P2/b
8.DB.HösliteFe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2OMon. 2/m : P21/b
8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 6H2OAmor.
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.05DestineziteFe3+2(PO4)(SO4)(OH) · 6H2OTric. 1 : P1
8.DB.07WilhelmgümbeliteZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2OOrth. mmm (2/m 2/m 2/m)
8.DB.07Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
8.DB.07WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm (2/m 2/m 2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.20SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric. 1 : P1
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric. 1 : P1
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.40BukovskýiteFe3+2(AsO4)(SO4)(OH) · 9H2OTric. 1 : P1
8.DB.40FlurliteZn3Mn2+Fe3+(PO4)3(OH)2 · 9H2OMon. 2/m : P21/m
8.DB.40ManganflurliteZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2OMon. 2/m : P21/m
8.DB.42BohuslaviteFe3+4(PO4)3(SO4)(OH) · nH2OTric. 1 : P1
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2
8.DB.47LapeyreiteCu3O[AsO3(OH)]2 · 0.75H2OMon. 2/m : B2/m
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.50RossiantoniteAl3(PO4)(SO4)2(OH)2(H2O)14Tric. 1 : P1
8.DB.52ArctowskiteAl9(PO4)8(OH)3 · 27H2OOrth.
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Other InformationHide

Notes:
A small crystal of camaronesite requires several hours to dissolve in cold, concentrated HCl and several days to dissolve in concentrated H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CamaronesiteHide

References for CamaronesiteHide

Localities for CamaronesiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile (TL)
 
  • Arica y Parinacota
    • Arica Province
      • Los Camarones valley
        • Cuya
Kampf et al. (2013)
 
and/or  
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