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Manganoneptunite

A valid IMA mineral species - grandfathered

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Photos of Manganoneptunite (136)

Manganoneptunite Gallery Search Photos of Manganoneptunite

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Manganoneptunite

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

Manganoneptunite, etc.

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

Manganoneptunite, etc.

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada

Manganoneptunite

Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada

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About ManganoneptuniteHide

Formula:

KNa₂Li(Mn²⁺)₂Ti₂[Si₄O₁₂]₂

Colour:

Red

Lustre:

Vitreous

Hardness:

5 - 6

Specific Gravity:

3.17 - 3.20

Crystal System:

Monoclinic

Member of:

Neptunite Group

Name:

For being the manganese analogue of neptunite. The earlier name was mangan-neptunite, but it was changed to manganoneptunite by the IMA in 2008 (Burke 2008).

Type Locality:

ⓘ Maly Mannepakhk Mt (Malyi Mannepakhk Mt), Khibiny Massif, Murmansk Oblast, Russia

The Mn(II) analogue of neptunite.

Unique IdentifiersHide

Mindat ID:

2564

Long-form identifier:

mindat:1:1:2564:1

GUID
(UUID V4):

2afbe83f-2150-428b-99b4-1f5a5d11fe12

IMA Classification of ManganoneptuniteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

IMA status notes:

Renamed by the IMA

IMA Formula:

KNa₂LiMn²⁺₂Ti₂Si₈O₂₄

First published:

1923

Type description reference:

Kurbatov, S.M. (1923): Analyse d'une neptounite manganifère des Monts Chibines en Laponie russe. Comptes Rendus de l’Académie des Sciences de Russie, 1, 59-60.

Classification of ManganoneptuniteHide

Strunz-mindat (2024):

9.EH.05

9 : SILICATES (Germanates)
E : Phyllosilicates
H : Transitional structures between phyllosilicate and other silicate units

Dana 7th ed.:

70.4.1.2

Dana 8th ed.:

70.4.1.2

70 : INOSILICATES Column or Tube Structures
4 : Column or Tube Structures with linked chains forming cages

Hey's CIM Ref.:

14.9.27

14 : Silicates not Containing Aluminum
9 : Silicates of Ti

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Mnnpt	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of ManganoneptuniteHide

Pronunciation:

Play	Recorded by	Country
	Jolyon Ralph	United Kingdom

Physical Properties of ManganoneptuniteHide

Lustre:

Vitreous

Transparency:

Translucent

Colour:

Red

Streak:

Brick-red, reddish brown.

Hardness:

5 - 6 on Mohs scale

Tenacity:

Brittle

Cleavage:

Distinct/Good
Distinct in two directions, intersecting at ~80°.

Fracture:

Irregular/Uneven, Conchoidal

Density:

3.17 - 3.20 g/cm³ (Measured) 3.26 g/cm³ (Calculated)

Optical Data of ManganoneptuniteHide

Type:

Biaxial (+)

RI values:

n_α = 1.691 - 1.697 n_β = 1.693 - 1.700 n_γ = 1.713 - 1.728

2V:

Measured: 31° to 36°, Calculated: 40°

Max Birefringence:

δ = 0.022 - 0.031

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

High

Dispersion:

r > v strong

Optical Extinction:

Y = b; Z ∧ c = 16°-20°.

Pleochroism:

Strong

Comments:

X = light yellow; Y = orange or yellow-orange; Z = red-orange.

Comments:

Absorption: Z > Y > X.

Chemistry of ManganoneptuniteHide

Mindat Formula:

KNa₂Li(Mn²⁺)₂Ti₂[Si₄O₁₂]₂

Elements listed:

K, Li, Mn, Na, O, Si, Ti - search for minerals with similar chemistry

Crystallography of ManganoneptuniteHide

Crystal System:

Monoclinic

Class (H-M):

m - Domatic

Space Group:

Setting:

Cell Parameters:

a = 16.4821(6) Å, b = 12.5195(4) Å, c = 10.0292(3) Å
β = 115.474(1)°

Ratio:

a:b:c = 1.317 : 1 : 0.801

Unit Cell V:

1868.31 Å³

Morphology:

Prismatic crystals, elongated along [001]. Forms include {110}, {001}, {100}. Also {111}, {111} and rare {210}.

Twinning:

Contact twinning on {001}.

Crystal StructureHide

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Unit Cell | Unit Cell Packed
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CIF File Best | x | y | z | a | b | c

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0018809	Manganoneptunite	Borisov S V, Klevtsova R F, Bakakin V V, Belov N V (1966) The crystal structure of neptunite Soviet Physics Crystallography 10 684-689		1966	Lovozero, Russia	0	293
0015717	Manganoneptunite	Zolotarev A A, Krivovichev S V, Yakovenchuk V N (2007) Refinement of the mangan-neptunite structure Zapiski Vserossijskogo Mineralogicheskogo Obshchestva 136 118-123		2007	Mt. Kaskasnyuncharr, the Khibiny alkaline pluton, Russia	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Manganoneptunite'
loop_
_publ_author_name
'Borisov S V'
'Klevtsova R F'
'Bakakin V V'
'Belov N V'
_journal_name_full 'Soviet Physics Crystallography'
_journal_volume 10 
_journal_year 1966
_journal_page_first 684
_journal_page_last 689
_publ_section_title
;
 The crystal structure of neptunite
;
_database_code_amcsd 0018809
_chemical_compound_source 'Lovozero, Russia'
_chemical_formula_sum 'K Na2 Li (Mn1.46 Fe.54) Ti2 Si8 O24'
_cell_length_a 16.41
_cell_length_b 12.55
_cell_length_c 10.03
_cell_angle_alpha 90
_cell_angle_beta 115.5
_cell_angle_gamma 90
_cell_volume 1864.410
_exptl_crystal_density_diffrn      3.231
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
K   0.00000   0.56900   0.25000   1.00000   0.00380
Na   0.24100   0.22000   0.80500   1.00000   0.02862
Li   0.00000   0.07400   0.25000   1.00000   0.00317
Mn   0.16000   0.18500   0.39800   0.73000   0.00659
Fe   0.16000   0.18500   0.39800   0.27000   0.00659
Ti   0.09000   0.93900   0.11600   1.00000   0.00481
Si1   0.02600   0.27800   0.09100   1.00000   0.00887
Si2   0.10300   0.84400   0.41400   1.00000   0.00697
Si3   0.23200   0.52400   0.39900   1.00000   0.00595
Si4   0.14700   0.41100   0.55900   1.00000   0.01267
O1   0.10600   0.28600   0.25000   1.00000   0.00089
O2   0.03300   0.17200   0.41800   1.00000   0.03800
O3   0.21000   0.30700   0.58700   1.00000   0.03800
O4   0.12300   0.04300   0.25300   1.00000   0.01393
O5   0.20200   0.07100   0.58000   1.00000  -0.00697
O6   0.04900   0.94800   0.43100   1.00000   0.01634
O7   0.11300   0.81800   0.27700   1.00000   0.02102
O8   0.16400   0.51700   0.48400   1.00000   0.00241
O9   0.16600   0.45700   0.72900   1.00000   0.00760
O10   0.03900   0.37400   0.47100   1.00000   0.01013
O11   0.28900   0.63100   0.47000   1.00000   0.01469
O12   0.43100   0.75800   0.52400   1.00000   0.00861

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
2.485 Å	(100)
1.506 Å	(100)
1.483 Å	(90)
2.170 Å	(80)
1.924 Å	(70)
2.841 Å	(60)
2.948 Å	(50)

Comments:

Lovozero massif, Russia.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ManganoneptuniteHide

Type Locality:

ⓘ Maly Mannepakhk Mt (Malyi Mannepakhk Mt), Khibiny Massif, Murmansk Oblast, Russia

General Appearance of Type Material:

Dark cherry-red crystalline granular aggregates, some of significant size and included with aegirine.

Place of Conservation of Type Material:

No designated type material.

Geological Setting of Type Material:

Pegmatite in nepheline syenite.

Associated Minerals at Type Locality:

Natrolite

Aegirine

Reference:

Kurbatov, S.M. (1923): Analyse d'une neptounite manganifère des Monts Chibines en Laponie russe. Comptes Rendus de l’Académie des Sciences de Russie, 1, 59-60.

Download:

https://rruff.info/rruff_1.0/uploads/CRASS1-59.pdf

Synonyms of ManganoneptuniteHide

Mangan-neptunite

Manganneptunite

Mn-Neptunite

Other Language Names for ManganoneptuniteHide

German:Manganneptunit
Manganoneptunit

Simplified Chinese:锰柱星叶石

Traditional Chinese:錳柱星葉石

Relationship of Manganoneptunite to other SpeciesHide

Member of:

Neptunite Group

Other Members of this group:

Magnesioneptunite	KNa₂Li(Mg)₂Ti₂[Si₄O₁₂]₂	Mon. 2/m : B2/b
Neptunite	KNa₂Li(Fe²⁺)₂Ti₂[Si₄O₁₂]₂	Mon. m : Bb
Rotherkopfite	KNa₂Fe²⁺(Fe²⁺)₂(Ti_1.5Fe²⁺_0.5)[Si₄O₁₂]₂	Mon. 2/m : B2/b
Watatsumiite	KNa₂Li(Mn²⁺)₂V⁴⁺₂[Si₄O₁₂]₂	Mon. m : Bb

Forms a series with:

Neptunite

Manganoneptunite-Neptunite Series

Common AssociatesHide

Associated Minerals Based on Photo Data:

65 photos of Manganoneptunite associated with Serandite	NaMn²⁺₂Si₃O₈(OH)
58 photos of Manganoneptunite associated with Aegirine	NaFe³⁺Si₂O₆
25 photos of Manganoneptunite associated with Catapleiite	Na₂Zr(Si₃O₉) · 2H₂O
25 photos of Manganoneptunite associated with Albite	Na(AlSi₃O₈)
24 photos of Manganoneptunite associated with Shkatulkalite	Na₂Nb₂Na₃Ti(Si₂O₇)₂O₂(FO)(H₂O)₄(H₂O)₃
22 photos of Manganoneptunite associated with Natrolite	Na₂Al₂Si₃O₁₀ · 2H₂O
21 photos of Manganoneptunite associated with Microcline	K(AlSi₃O₈)
20 photos of Manganoneptunite associated with Analcime	Na(AlSi₂O₆) · H₂O
19 photos of Manganoneptunite associated with Ussingite	Na₂AlSi₃O₈OH
18 photos of Manganoneptunite associated with Eudialyte Group	[N(1)N(2)N(3)N(4)N(5)]₃[M(1.1)M(1.2)]₃[M(2.1)M(2.2)M(2.3)]_3-6[M(3)M(4)]Z₃[Si₂₄O₇₂]Θ₄X(1)X(2)

Related Minerals - Strunz-mindat Grouping Hide

9.EH.05	Neptunite	KNa₂Li(Fe²⁺)₂Ti₂[Si₄O₁₂]₂	Mon. m : Bb
9.EH.05	Watatsumiite	KNa₂Li(Mn²⁺)₂V⁴⁺₂[Si₄O₁₂]₂	Mon. m : Bb
9.EH.05	Magnesioneptunite	KNa₂Li(Mg)₂Ti₂[Si₄O₁₂]₂	Mon. 2/m : B2/b
9.EH.05	Rotherkopfite	KNa₂Fe²⁺(Fe²⁺)₂(Ti_1.5Fe²⁺_0.5)[Si₄O₁₂]₂	Mon. 2/m : B2/b
9.EH.10	Grumantite	Na(HSi₂O₅) · H₂O	Orth. mm2 : Fdd2
9.EH.15	Sarcolite	Na₄Ca₁₂Al₈Si₁₂O₄₆(SiO₄,PO₄)(OH,H₂O)₄(CO₃,Cl)	Tet. 4/m : I4/m
9.EH.20	Ussingite	Na₂AlSi₃O₈OH	Tric. 1 : P1
9.EH.25	Leifite	(Na,H₂O)Na₆[Be₂Al₂(Al,Si)Si₁₅O₃₉]F₂	Trig. 3m : P3m1
9.EH.25	Telyushenkoite	(Cs,Na,K)Na₆[Be₂Al₃Si₁₅O₃₉]F₂	Trig. 3m (3 2/m) : P3 1m
9.EH.25	Eirikite	KNa₆Be₂(Si₁₅Al₃)O₃₉F₂	Trig. 3m (3 2/m) : P3m1
9.EH.30	Nafertisite	Na₃Fe²⁺₁₀Ti₂(Si₆O₁₇)₂O₂(OH)₆F(H₂O)₂	Mon. 2/m
9.EH.35	Veblenite	KNa(Fe²⁺₅Fe³⁺₄Mn₇)Nb₄(Si₂O₇)₂(Si₈O₂₂)₂O₆(OH)₁₀(H₂O)₃	Tric. 1 : P1

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ManganoneptuniteHide

mindat.org URL:

https://www.mindat.org/min-2564.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for ManganoneptuniteHide

Reference List:

Kurbatov, S.M. (1923): Analyse d'une neptounite manganifère des Monts Chibines en Laponie russe. Comptes Rendus de l’Académie des Sciences de Russie, 1, 59-60.

Fersman, A. E. (1926) Minerals of the Kola Peninsula. American Mineralogist: 11: 289-299.

Foshag, W.F., Schairer, J.F. (1927): New mineral names. American Mineralogist, 12, 95-98.

BØGGILD, O.B. (1953): The Mineralogy of Greenland. C.A. Reitzels Forlag, Copenhagen, 439 p.

Mandarino, J.A., Harris, D.C., Bradley, J. (1965): Mangan neptunite, epididymite, and new species from Mont St. Hilaire. The Canadian Mineralogist, 8, 398. (Abstract)

Borisov, S.V., Klevtsova, R.F., Bakakin, V.V., Belov, N.V. (1966): The crystal structure of neptunite. Soviet Physics - Crystallography, 10, 684-689.

Zolotarev, A.A., Krivovichev, S.V., Yakovenchuk, V.N. (2007): Refinement of the mangan-neptunite crystal structure. Geology of Ore Deposits, 49, 835-838.

Burke, Ernst A. J. (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks. The Mineralogical Record, 39 (2) 131-135

(2023) Manganoneptunite. Handbook of Mineralogy. Mineralogical Society of America

Localities for ManganoneptuniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Canada
Québec Montérégie La Vallée-du-Richelieu RCM Mont Saint-Hilaire ⓘ Poudrette quarry (De-Mix quarry; Demix quarry; Uni-Mix quarry; Carrière Mont Saint-Hilaire; MSH)	166-175. +2 other references
Lajemmerais RCM Varennes & St-Amable ⓘ Saint-Amable sill	Horváth et al. (1998)
ⓘ Demix-Varennes quarry	Horváth et al. (1998)
Montréal Montréal-Est ⓘ Lafarge Montreal East quarry (Carrière Lafarge Montréal-Est; Francon Montréal-Est quarry; Canada Cement quarry)	Horváth collection

Greenland
Kujalleq ⓘ Ilímaussaq complex	Petersen (2001)

Malawi
Southern Region Zomba ⓘ Mount Malosa ?	Petersen et al. (1994)

Morocco
Drâa-Tafilalet Region Midelt Province Midelt Cercle Aït Oufella Caïdat Amersid ⓘ Jebel Bou-Agrao	Khadem Allah (1993)

Namibia
Khomas Region Windhoek Rural Aris ⓘ Aris Quarries ?	Uwe Kolitsch (single-crystal X-ray diffraction + SEM-EDS) +6 other references

Russia
Buryatia Mama River Basin Maigunda River ⓘ Burpala alkaline massif	Vladykin et al. (2017)
Murmansk Oblast Khibiny Massif Eveslogchorr Mt Astrophyllite Stream ⓘ Pegmatite	Pekov et al. (2005)
ⓘ IGC Stop 4-2	Arzamastsev et al. (2008)
Koashva Mt ⓘ Koashva Open Pit	American Mineralogist
ⓘ Kukisvumchorr Mt	Pekov et al. (2004)
Kirovskii apatite mine ⓘ Hilairitovoye pegmatite	Pekov et al. (2006)
ⓘ Marchenko Peak	Collection of the Fersman's ...
ⓘ Maly Mannepakhk Mt (Malyi Mannepakhk Mt) (TL)	Kurbatov (1923) +1 other reference
ⓘ Poachvumchorr Mountain	Pavel.M. Kartashov (n.d.)
ⓘ Rischorr Mt	various added photos
Lovozersky District ⓘ Alluaiv Mountain	[World of Stones 95:5-6 +1 other reference
Umbozero mine ⓘ Shkatulka pegmatite	Th. Witzke collection +1 other reference
ⓘ Sirenevaya pegmatite	Pavel.M. Kartashov (n.d.)
ⓘ Umbozero North quarry	Pavel.M. Kartashov (n.d.)
ⓘ Karnasurt Mountain	Arzamastsev et al. (2008)
ⓘ Karnasurt mine	Kasatkin (2019)
ⓘ Palitra pegmatite	Pekov (2005)
ⓘ Natrolite Stock	New Data on Minerals M. +1 other reference
ⓘ Yubileinaya-2 pegmatite	Kasatkin (2019)
ⓘ Yubileinaya pegmatite	Pekov (1998) +2 other references
ⓘ Kedykverpakhk Mountain	Pekov (1998)
Kuftnyun Mountain ⓘ Pegmatite No. 19	Pekov (1998)
ⓘ Malyi Punkaruaiv Mountain	Pekov (1998) +2 other references
ⓘ Pegmatite No. 71	Ermolaeva et al. (2007)
Seidozero Lake ⓘ Lepkhe-Nel'm Mt	Yakovenchuk et al. (2007)
ⓘ Pegmatite No. 47	Semenov E.I. (1972)
ⓘ Sengischorr Mountain
ⓘ Tavaiok River Valley	Ermolaeva et al. (2007)

Spain
Canary Islands Santa Cruz de Tenerife Province Tenerife Candelaria Barranco Hondo ⓘ Lava flow	Dill et al. (2023)

USA
Montana Meagher County ⓘ Gordon Butte	Mitchell (2000) +1 other reference
New Mexico Colfax County Springer Point of Rocks Mesa (Pecks Mesa) ⓘ Point of Rocks Quarry	Rocks & Min.:60:229.

Manganoneptunite

About ManganoneptuniteHide

Unique IdentifiersHide

IMA Classification of ManganoneptuniteHide

Classification of ManganoneptuniteHide

Mineral SymbolsHide

Pronunciation of ManganoneptuniteHide

Physical Properties of ManganoneptuniteHide

Optical Data of ManganoneptuniteHide

Chemistry of ManganoneptuniteHide

Crystallography of ManganoneptuniteHide

Crystal StructureHide

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Type Occurrence of ManganoneptuniteHide

Synonyms of ManganoneptuniteHide

Other Language Names for ManganoneptuniteHide

Relationship of Manganoneptunite to other SpeciesHide

Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

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Internet Links for ManganoneptuniteHide

References for ManganoneptuniteHide

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Locality ListHide

Related Minerals - Strunz-mindat Grouping Hide