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Gillulyite

A valid IMA mineral species
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About GillulyiteHide

06367070016451996962582.jpg
James C. Gilluly
Formula:
Tl2As7.5Sb0.3S13
Colour:
Deep red
Lustre:
Adamantine
Hardness:
2 - 2½
Specific Gravity:
4.02
Crystal System:
Monoclinic
Name:
Named after USGS geologist James C. Gilluly (24 June 1896, Seattle, Washington, USA - 29 December 1980) for his contributions to the understanding of the fundamental geology of the Mercur, Ophir, and Stockton mining districts of Utah. [http://www.nasonline.org/publications/biographical-memoirs/memoir-pdfs/gilluly-james.pdf]
OD structure; several possible polytypes have been proposed (Makovicky & Balić-Žunić, 1999).

Homeotypic with ambrinoite and gerstleyite.

Also compare jankovićite, rebulite, gillulyite, pierrotite; and gungerite.

Gillulyite is very light sensitive and to preserve the true color and luster must be stored in a dark container (http://www.mindat.org/forum.php?file,7,file=58644).



Unique IdentifiersHide

Mindat ID:
1694
Long-form identifier:
mindat:1:1:1694:6
GUID
(UUID V4):
a985586a-c161-4661-b111-a2e62ef35aef

IMA Classification of GillulyiteHide

Classification of GillulyiteHide

2.JC.10

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
C : Galena derivatives, with Tl
3.8.9.1

3 : SULFOSALTS
8 : 1 < ø < 2
5.5.12

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
5 : Sulpharsenites etc. of Tl

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
GlyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GillulyiteHide

Adamantine
Transparency:
Translucent
Colour:
Deep red
Comment:
Tarnishes rapidly to a near-metallic luster.
Streak:
Brick red
Hardness:
2 - 2½ on Mohs scale
Cleavage:
Perfect
One perfect cleavage and possbly two poor cleavages (based on pitting during polishing).
Density:
4.02(2) g/cm3 (Measured)    4.14 g/cm3 (Calculated)
Comment:
Difference may be due to orpiment inclusions.

Optical Data of GillulyiteHide

Type:
Biaxial
Dispersion:
relatively strong
Reflectivity:
WavelengthR1R2imR1imR2
400nm29.8%32.0%15.0%18.6%
420nm29.3%31.8%14.6%18.1%
440nm28.6%31.55%13.9%17.7%
460nm27.8%31.0%13.2%17.05%
470nm27.3%30.6%12.7%16.65%
480nm27.0%30.4%12.4%16.25%
500nm26.1%29.6%11.6%15.5%
520nm25.1%28.9%10.9%14.8%
540nm24.3%28.2%10.3%14.1%
546nm24.1%28.0%10.1%13.9%
560nm23.6%27.5%9.76%13.5%
580nm23.1%26.9%9.36%12.9%
589nm22.8%26.6%9.19%12.6%
600nm22.6%26.25%9.03%12.4%
620nm22.2%25.8%8.77%12.0%
640nm21.9%25.4%8.59%11.8%
650nm21.7%25.3%8.47%11.7%
660nm21.6%25.2%8.45%11.6%
680nm21.35%24.9%8.27%11.4%
700nm21.2%24.8%8.14%11.2%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 32.0%.
R1 shown in black, R2 shown in red, imR1 shown in green, imR2 shown in blue
Comments:
Reflectivity from Wilson et al. (1993).

Chemistry of GillulyiteHide

Mindat Formula:
Tl2As7.5Sb0.3S13

Crystallography of GillulyiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 9.58 Å, b = 5.67 Å, c = 21.5 Å
β = 100.07°
Ratio:
a:b:c = 1.69 : 1 : 3.792
Unit Cell V:
1,149.86 ų (Calculated from Unit Cell)
Morphology:
Simple monoclinic crystals exhibit forms {110}, {010}, and {01l}.
Twinning:
None observed
Comment:
Space group P2/n (Foit et al., 1995). Re-study revealed OD structure (Makovicky & Balić-Žunić, 1999).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001733GillulyiteFoit F F, Robinson P D, Wilson J R (1995) The crystal structure of gillulyite, Tl2(As,Sb)8S13, from the Mercur gold deposit, Tooele County, Utah, U.S.A American Mineralogist 80 394-39919950293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.14 Å(60)
3.87 Å(60)
3.63 Å(90)
3.077 Å(100)
2.814 Å(100)
2.718 Å(60)
2.613 Å(55)
2.502 Å(70)
2.393 Å(60)
1.766 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4
Geological Setting:
In barite veins and in calcite veins.

Type Occurrence of GillulyiteHide

General Appearance of Type Material:
Cleavable masses up to 2 cm in diameter and, rarely, as crystals to 1 mm in length.
Place of Conservation of Type Material:
Royal Ontario Museum, Toronto, Canada.
Harvard University, Cambridge, Massachusetts, USA, 130781.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 170773.
Geological Setting of Type Material:
A sediment-hosted, disseminated gold deposit.
Associated Minerals at Type Locality:
Reference:
Wilson, J.R., Robinson, P.D., Wilson, P.N., Stanger, L.W., Salmon, G.L. (1991) Gillulyite, Tl2(As,Sb)8S13, a new thallium arsenic sulfosalt from the Mercur gold deposit, Utah. American Mineralogist, 76, 653-656.

Synonyms of GillulyiteHide

Other Language Names for GillulyiteHide

German:Gillulyit
Simplified Chinese:辉砷锑铊矿
Spanish:Gillulyita

Common AssociatesHide

Associated Minerals Based on Photo Data:
9 photos of Gillulyite associated with BaryteBaSO4
6 photos of Gillulyite associated with OrpimentAs2S3
2 photos of Gillulyite associated with RealgarAs4S4
1 photo of Gillulyite associated with PicropharmacoliteCa4Mg(AsO4)2(HAsO4)2 · 11H2O

Related Minerals - Strunz-mindat GroupingHide

2.JC.05EllisiteTl3AsS3Trig. 3m : R3m
2.JC.25eGalenobismutitePbBi2S4Orth. mmm (2/m 2/m 2/m)

Other InformationHide

Special Storage/
Display Requirements:
Protect from light.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GillulyiteHide

References for GillulyiteHide

Localities for GillulyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Sverdlovsk Oblast
    • Serovsky District
      • Turya river
        • Tur'insk
USA (TL)
 
  • Utah
    • Tooele County
      • Mercur Mining District
        • South Mercur Pit
 
and/or  
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