Zemannite
A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
About Zemannite
Formula:
Mg0.5ZnFe3+(Te4+O3)3 · 4.5H2O
Colour:
Light brown to dark brown
Lustre:
Adamantine
Specific Gravity:
4.36 (Calculated)
Crystal System:
Trigonal
Member of:
Name:
Named after Josef Zemann (born 25 May 1923 in Vienna, Austria, died 16 October 2022 in Vienna, Austria), Professor of Mineralogy, University of Vienna (Austria), in recognition of his outstanding work in crystallography, crystal chemistry, optical mineralogy and spectroscopy, and other fields. In particular, his contributions to the knowledge of tellurium and selenium oxysalts.
Zn-analogue of kinichilite and keystoneite. Fe-analogue of ilirneyite.
According to Mandarino et al. (1976) zemannite has zeolite-like framework of negatively charged [Zn^2(TeO^3)^3], with large channels parallel to [0001].
According to Mandarino et al. (1976) zemannite has zeolite-like framework of negatively charged [Zn^2(TeO^3)^3], with large channels parallel to [0001].
Unique Identifiers
Mindat ID:
4392
Long-form identifier:
mindat:1:1:4392:8
GUID
(UUID V4):
(UUID V4):
5700a056-0b53-4803-ad47-96c1fac2e4a7
IMA Classification of Zemannite
Approved
IMA Formula:
Mg0.5ZnFe3+(Te4+O3)3 · nH2O (3≤n≤4.5)
Approval year:
1968
First published:
1969
Classification of Zemannite
4.JM.05
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
M : Tellurites without additional anions, with H2O
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
M : Tellurites without additional anions, with H2O
34.3.2.1
34 : SELENITES, TELLURITES AND SULFITES
3 : A2(XO3)3·xH2O
34 : SELENITES, TELLURITES AND SULFITES
3 : A2(XO3)3·xH2O
28.3.8
28 : Selenites, Selenates, Tellurites, and Tellurates
3 : Tellurites
28 : Selenites, Selenates, Tellurites, and Tellurates
3 : Tellurites
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Zem | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Zemannite
Adamantine
Transparency:
Transparent, Translucent
Colour:
Light brown to dark brown
Streak:
White
Hardness Data:
Could not be measured
Comment:
Quite soft.
Tenacity:
Brittle
Density:
4.36(8) g/cm3 (Calculated)
Comment:
Measured as >4.05.
Optical Data of Zemannite
Type:
Uniaxial (+)
RI values:
nω = 1.850 nε = 1.930
Max Birefringence:
δ = 0.080
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Pleochroism:
Visible
Comments:
Dichroic with ω = reddish brown and ε = yellowish brown.
Comments:
Absorption, ω > ε.
Chemistry of Zemannite
Mindat Formula:
Mg0.5ZnFe3+(Te4+O3)3 · 4.5H2O
Crystallography of Zemannite
Crystal System:
Trigonal
Class (H-M):
3 - Pyramidal
Space Group:
P3
Cell Parameters:
a = 9.41(2) Å, c = 7.64(2) Å
Ratio:
a:c = 1 : 0.812
Unit Cell V:
585.87 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Prisms with bipyramidal terminations, {1010} and {1011}.
Twinning:
None observed.
Comment:
For a long time, the space group was assumed to be P63/m. Effenberger et al. (2023) showed it to be P3.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0006591 | Zemannite | Miletich F (1995) Crystal chemistry of the microporous tellurite minerals zemannite and kinichilite, Mg0.5[MeFe(TeO3)3].4.5H2O, (Me=Zn;Mn) European Journal of Mineralogy 7 509-523 | 1995 | Moctezuma Mine, Moctezuma, Sonora, Mexico | 0 | 293 | |
0006592 | Zemannite | Miletich F (1995) Crystal chemistry of the microporous tellurite minerals zemannite and kinichilite, Mg0.5[MeFe(TeO3)3].4.5H2O, (Me=Zn;Mn) European Journal of Mineralogy 7 509-523 | 1995 | Bambolla Mine, Moctezuma, Sonora, Mexico | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Image Loading
Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
8.15 Å | (100) |
2.778 Å | (90) |
4.07 Å | (80) |
2.96 Å | (60) |
2.845 Å | (60) |
1.726 Å | (60) |
2.345 Å | (50) |
2.160 Å | (50) |
1.504 Å | (50) |
3.07 Å | (40) |
2.207 Å | (40) |
1.794 Å | (40) |
1.686 Å | (40) |
Comments:
Moctezuma Mine, Sonora, Mexico. Data from Mandarino et al. (1976).
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47e : [Vanadates, chromates, manganates] |
Type Occurrence of Zemannite
General Appearance of Type Material:
Hexagonal prisms terminated by a bipyramid. Crystals are less than 1 mm.
Place of Conservation of Type Material:
Natural History Museum, Paris, France.
Royal Ontario Museum, Toronto, Canada, M25933.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 128390.
Royal Ontario Museum, Toronto, Canada, M25933.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, 128390.
Geological Setting of Type Material:
Tellurium deposit.
Synonyms of Zemannite
Other Language Names for Zemannite
Relationship of Zemannite to other Species
Member of:
Other Members of this group:
Ilirneyite | Mg0.5ZnMn3+(Te4+O3)3 · 4.5H2O | Hex. 6/m : P63/m |
Keystoneite | Mg0.5Ni2+Fe3+(Te4+O3)3 · 4.5H2O | Hex. 6 : P63 |
Kinichilite | Mg0.5Mn2+Fe3+(Te4+O3)3 · 4.5H2O | Hex. 6/m : P63/m |
Common Associates
Associated Minerals Based on Photo Data:
28 photos of Zemannite associated with Quartz | SiO2 |
12 photos of Zemannite associated with Baryte | BaSO4 |
9 photos of Zemannite associated with Tellurite | TeO2 |
5 photos of Zemannite associated with Paratellurite | TeO2 |
4 photos of Zemannite associated with Cuzticite | Fe3+2(TeO6) · 3H2O |
3 photos of Zemannite associated with Poughite | Fe3+2(TeO3)2(SO4)(H2O)2 · H2O |
3 photos of Zemannite associated with Denningite | (Mn2+,Ca,Zn)Te4+2O5 |
3 photos of Zemannite associated with Zincospiroffite | Zn2Te4+3O8 |
2 photos of Zemannite associated with Gold | Au |
2 photos of Zemannite associated with Eurekadumpite | (Cu,Zn)16(TeO3)2(AsO4)3Cl(OH)18 · 7H2O |
Related Minerals - Strunz-mindat Grouping
4.JM. | Rudolfhermannite | Fe(Te4+O3)3 · H2O |
4.JM. | Wortupaite | MgNi2+2(Te4+O3)3 · 3H2O |
4.JM.05 | Keystoneite | Mg0.5Ni2+Fe3+(Te4+O3)3 · 4.5H2O |
4.JM.05 | Kinichilite | Mg0.5Mn2+Fe3+(Te4+O3)3 · 4.5H2O |
4.JM.05 | Ilirneyite | Mg0.5ZnMn3+(Te4+O3)3 · 4.5H2O |
4.JM.10 | Blakeite | Fe3+2[TeO3]3 (?) |
4.JM.10 | Emmonsite | Fe3+2(TeO3)3 · 2H2O |
4.JM.15 | Graemite | Cu[TeO3] · H2O |
4.JM.20 | Teineite | Cu2+(Te4+O3) · 2H2O |
4.JM.20 | Telluromandarinoite | Fe3+2Te3O9 · 6H2O |
4.JM.25 | Millsite | Cu2+(Te4+O3) · 2H2O |
Fluorescence of Zemannite
Not fluorescent.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Zemannite
mindat.org URL:
https://www.mindat.org/min-4392.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Zemannite
Reference List:
Mandarino, J. A., Williams, S. J. (1961) Five new minerals from Moctezuma, Sonora, Mexico. Science, 133 (3469) 2017 doi:10.1126/science.133.3469.2017
Mandarino, J. A., Matzat, E., Williams, S. J. (1976) Zemannite, a zinc tellurite from Moctezuma, Sonora, Mexico. The Canadian Mineralogist, 14 (3) 387-390
Localities for Zemannite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Belgium | |
| perso.infonie.be (2004) |
Japan | |
| Hori (1996) |
Mexico (TL) | |
| MinRec 8:390 +2 other references |
USA | |
| Joy Desor |
| Collected by and in the collection of ... |
| Collected and analyzed by John Dagenais |
Collected by and in the collection of ... | |
Collected by and in the collection of ... | |
| SEM-EDS analyzed by Dr. Rob Bowell. |
Quick NavTopAbout ZemanniteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List
Moctezuma Mine, Moctezuma, Moctezuma Municipality, Sonora, Mexico