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Patrónite

A valid IMA mineral species - grandfathered
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About PatróniteHide

Formula:
VS4
Colour:
Lead-gray on fresh surface, gray-black on exposed surface
Lustre:
Metallic
Hardness:
2
Specific Gravity:
2.82
Crystal System:
Monoclinic
Name:
Named in honor of Antenor Rizo-Patrona (1866–1948) metallurgist of the Huaraucaca smelter, who discovered the ore.
Chemically similar to eliopoulosite.


Unique IdentifiersHide

Mindat ID:
3131
Long-form identifier:
mindat:1:1:3131:4
GUID
(UUID V4):
3f3c6561-27ef-45ff-b658-ccfcecb5b191

IMA Classification of PatróniteHide

Approved, 'Grandfathered' (first described prior to 1959)
First published:
1906

Classification of PatróniteHide

2.EC.10

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
C : M:S = 1:>2
2.16.21.1

2 : SULFIDES
16 : Miscellaneous
3.7.1

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
7 : Sulphides etc. of V, As, Sb and Bi

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
PatIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PatróniteHide

Metallic
Transparency:
Opaque
Colour:
Lead-gray on fresh surface, gray-black on exposed surface
Hardness:
Cleavage:
Very Good
Pronounced columnar cleavage
Density:
2.82(1) g/cm3 (Measured)    2.834 g/cm3 (Calculated)

Optical Data of PatróniteHide

Reflectivity:
WavelengthR1R2
400nm20.2% 29.9%
420nm20.0% 30.0%
440nm19.8% 30.1%
460nm19.8% 30.8%
480nm20.0% 31.9%
500nm20.1% 32.6%
520nm20.1% 32.9%
540nm20.0% 32.8%
560nm19.8% 32.4%
580nm19.6% 31.4%
600nm19.1% 30.5%
620nm18.9% 29.6%
640nm18.8% 29.6%
660nm19.0% 29.8%
680nm19.2% 30.3%
700nm19.5% 31.0%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 32.9%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Dark gray
Pleochroism:
Strong

Chemistry of PatróniteHide

Mindat Formula:
VS4

Crystallography of PatróniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 12.11(1) Å, b = 10.42(1) Å, c = 6.775(5) Å
β = 100.8°
Ratio:
a:b:c = 1.162 : 1 : 0.65
Unit Cell V:
839.77 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Massive, and as aggregates of columnar crystals
Comment:
Space Group: I2/c.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.604 Å(100)
5.181 Å(65)
2.473 Å(30)
2.216 Å(30)
2.047 Å(25)
3.151 Å(20)
2.962 Å(20)
Comments:
Synthetic

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36

Type Occurrence of PatróniteHide

General Appearance of Type Material:
Massive and aggregates of columnar crystals.
Place of Conservation of Type Material:
Harvard Mineralogical Museum, Cambridge, Massachusetts, USA, number 100822 (holotype).
Geological Setting of Type Material:
Ore mineral in vanadium deposit.
Reference:
Hewett, F. (1906) A new occurrence of vanadium in Peru. Engineering and Mining Journal: 82: 385-385.

Synonyms of PatróniteHide

Other Language Names for PatróniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
47 photos of Patrónite associated with MelanovanaditeCa(V5+,V4+)4O10 · 5H2O
10 photos of Patrónite associated with Minasragrite(V4+O)(SO4) · 5H2O
7 photos of Patrónite associated with PyriteFeS2
3 photos of Patrónite associated with Stanleyite(V4+O)(SO4) · 6H2O
3 photos of Patrónite associated with Fernandinite(Ca,K)(V5+,V4+,Fe2+)8O20 · 10H2O
3 photos of Patrónite associated with BarianditeAl0.6(V5+,V4+)8O20 · 9H2O
2 photos of Patrónite associated with RetgersiteNiSO4 · 6H2O
1 photo of Patrónite associated with DwornikiteNi(SO4) · H2O
1 photo of Patrónite associated with Bravoite(Fe,Ni)S2

Related Minerals - Strunz-mindat GroupingHide

2.EC.05KieftiteCoSb3Iso. m3 (2/m 3) : Im3
2.EC.05Nickelskutterudite(Ni,Co,Fe)As3Iso. m3 (2/m 3) : Im3
2.EC.05SkutteruditeCoAs3Iso. m3 (2/m 3) : Im3
2.EC.05Ferroskutterudite(Fe,Co)As3Iso. m3m (4/m 3 2/m) : Im3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PatróniteHide

References for PatróniteHide

Localities for PatróniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • West Coast municipality
Stillwell (1932) +1 other reference
El Salvador
 
  • Sonsonate Department
Joan Rosell (2023)
Finland
 
  • North Karelia
    • Outokumpu
Peltola (1960)
Kazakhstan
 
  • Turkistan Region
    • Sozak District
      • Budenovskoye Uranium ore field
Karpenko et al. (2011)
Bernard et al. (2004)
Namibia
 
  • Oshikoto Region
    • Tsumeb
Gebhard (1999)
Peru
 
  • Pasco
    • Pasco province
      • Cerro de Pasco
Hewett (1910)
      • Huayllay District
Hewett (1906) +3 other references
Russia
 
  • Amur Oblast
    • Urusha-Oldoi ore district
Vakh et al. (2009, March) +1 other reference
  • Nenets Autonomous Okrug
    • Yugorskii Peninsula
      • Pai-Khoi Range (Paikhoi; Pay Khoy)
        • Middle Silova-Yakha River
Koval'chuk et al. (2008)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
Dill et al. (2023)
Dill et al. (2023)
 
矿物 and/or 产地  
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