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Sphalerite Group

A material that is NOT an approved mineral species
This page kindly sponsored by Nathaniel "Sandy" Ludlum
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About Sphalerite GroupHide

Formula:
AX
A = Cd, Hg, Zn, Mn, Fe, Cu; X = S, Se, Te
Crystal System:
Isometric
The diamond structure has two interpenetrating cubic close packed carbon lattices. Each atom of theses lattices is tetrahedrally coordinated by 4 atoms of the other lattice. If one of these lattices is replaced by cations (A) and the other replaced by anions (X), where X = S, Se, Te we get the sphalerite group.

Although the members can be lab grown as solution series, geochemical segregation usually gives fairly pure end members.

Compare Wurtzite Group.


Unique IdentifiersHide

Mindat ID:
29333
Long-form identifier:
mindat:1:1:29333:2
GUID
(UUID V4):
7a07536d-696e-450c-b61c-baa9f03baee1

Chemistry of Sphalerite GroupHide

Mindat Formula:
AX

A = Cd, Hg, Zn, Mn, Fe, Cu; X = S, Se, Te

Crystallography of Sphalerite GroupHide

Crystal System:
Isometric
Class (H-M):
4 3m - Hextetrahedral
Morphology:
Composite and twinned crystals are common.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0017666Coloradoitede Jong W (1926) Die Struktur des Tiemannit und Koloradoit. _cod_database_code 1010945 Zeitschrift fur Kristallographie 63 466-47219260293
0011528ColoradoiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0017442ColoradoiteZachariasen W (1926) Die Kristallstruktur der Telluride von Zink, Cadmium und Quecksilber _cod_database_code 1010537 Norsk Geologisk Tidsskrift 8 302-30619260293
0000070HawleyiteTraill R J, Boyle R W (1955) Hawleyite, isometric cadmium sulphide, a new mineral American Mineralogist 40 555-55919550293
0000111HawleyiteSkinner B J (1961) Unit-cell edges of natural and synthetic sphalerites American Mineralogist 46 1399-14111961synthetic0293
0018121HawleyiteUlrich F, Zachariasen W (1925) Ueber die Kristallstruktur des alpha und beta Cd S, sowie des Wurtzits _cod_database_code 1011260 Zeitschrift fur Kristallographie 62 260-27319250293
0011517HawleyiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0018113HawleyiteMueller W, Loeffler G (1933) Zur Kenntnis der Faerbung von gefaelltem Cadmiumsulfid _cod_database_code 1011251 Angewandte Chemie (German Edition) 46 538-53919330293
0018202MetacinnabarLehmann W (1924) Roentgenographische Untersuchungen an natuerlichem und synthetischem Metacinnabarit (Hg S). _cod_database_code 1011368 Zeitschrift fur Kristallographie 60 379-41319240293
0011526MetacinnabarWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0000110SphaleriteSkinner B J (1961) Unit-cell edges of natural and synthetic sphalerites American Mineralogist 46 1399-14111961synthetic0293
0018098Sphaleritede Jong W (1927) Marmatit und christophit _cod_database_code 1011232 Zeitschrift fur Kristallographie 66 515-51519270293
0018099Sphaleritede Jong W (1927) Marmatit und christophit _cod_database_code 1011233 Zeitschrift fur Kristallographie 66 515-51519270293
0018328SphaleriteNitta E, Kimata M, Hoshino M, Echigo T, Hamasaki S, Nishida N, Shimizu M, Akasak T (2008) Crystal chemistry of ZnS minerals formed as high-temperature volcanic sublimates: matraite identical with sphalerite Journal of Mineralogical and Petrological Sciences 103 145-1512008Iwodake volcano, Satsuma-Iwojima, Kyushu, SW Japan0293
0011535StilleiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0000050TiemanniteEarley J W (1950) Description and syntheses of the selenide minerals American Mineralogist 35 337-36419500293
0018070Tiemannitede Jong W (1926) Die Struktur des Tiemannit und Koloradoit _cod_database_code 1011199 Zeitschrift fur Kristallographie 63 466-47219260293
0011527TiemanniteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0004582RudashevskyiteBritvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-9092008Indarch meteorite0293
0004583RudashevskyiteBritvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-9092008Indarch meteorite0293
0004584RudashevskyiteBritvin S N, Bogdanova A N, Boldyreva M M, Aksenova G Y (2008) Rudashevskyite, the Fe-dominant analogue of sphalerite, a new mineral: Description and crystal structure American Mineralogist 93 902-9092008Indarch meteorite0293
0019735BrowneiteMa C, Beckett J R, Rossman G R (2012) Browneite, MnS, a new sphalerite-group mineral from the Zaklodzie meteorite American Mineralogist 97 2056-20592012Zaklodzie meteorite0293
0011532BrowneiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0018216BrowneiteMehmed F, Haraldsen H (1938) Das magnetische Verhalten der allotropen Modifikationen des Mangan(II)- Sulfides Zeitschrift fur Anorganische und Allgemeine Chemie 235 193-20019380293
0020262IshiharaiteMarquez-Zavalia M F, Galliski M A, Drabek M, Vymazalova A, Watanabe Y, Murakami H, Bernhardt H J (2015) Ishiharaite, (Cu,Ga,Fe,In,Zn)S, a new mineral from the Capillitas mine, Northwestern Argentina The Canadian Mineralogist 52 969-9802015Capillitas mine, Argentina0293
CIF Raw Data - click here to close

Relationship of Sphalerite Group to other SpeciesHide

Group Members:
Browneite MnS Iso. 4 3m : F4 3m
Coloradoite HgTeIso. 4 3m : F4 3m
Hawleyite CdSIso. 4 3m : F4 3m
Ishiharaite (Cu,Ga,Fe,In,Zn)SIso. 4 3m : F4 3m
Metacinnabar HgSIso. 4 3m : F4 3m
Rudashevskyite (Fe,Zn)SIso. 4 3m : F4 3m
Sphalerite ZnSIso. 4 3m : F4 3m
Stilleite ZnSeIso. 4 3m : F4 3m
Tiemannite HgSeIso. 4 3m : F4 3m
Minerals structurally related to group:
IsocubaniteCuFe2S3
Sakuraiite(Cu,Zn,Fe)3(In,Sn)S4

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Sphalerite Group in petrologyHide

An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.

Internet Links for Sphalerite GroupHide

References for Sphalerite GroupHide

Reference List:
 
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