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Manganberzeliite

A valid IMA mineral species - grandfathered
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About ManganberzeliiteHide

08854280014946275137709.jpg
Jöns Jakob Berzelius
Formula:
(NaCa2)Mn2+2(AsO4)3
Colour:
Yellow-orange, yellowish red; colorless to orange in transmitted light.
Lustre:
Sub-Vitreous, Resinous, Greasy
Hardness:
4½ - 5
Specific Gravity:
4.28 - 4.46
Crystal System:
Isometric
Name:
Named (as Mangan-Berzeliit) in 1894 by Lars Johan Igelström for Jöns Jakob Berzelius, Swedish chemist [August 20, 1779 Linköping, Sweden - August 7, 1848 Stockholm, Sweden] and the prefix MANGAN-, in allusion to its being the manganese dominant member of the series with berzeliite. Berzelius is the father of analytical chemistry, inventor of chemical symbol notation. and discoverer of cerium, selenium, silicon, thorium, titanium, and zirconium, in addition to other elements that he gave to his students to work on.
The mineral, which Igelström found in 1886 at Sjögruvan, Grythyttan, Örebro county, Sweden was already described by him as Pyrrhoarsénite in 1878 (Igelström 1878, 1894).
Berzeliite-Manganberzeliite Series. The manganese analogue of Berzeliite. Structurally related to Palenzonaite and to the Garnet Group of silicates.

Chemically very similar to caryinite.


Unique IdentifiersHide

Mindat ID:
2480
Long-form identifier:
mindat:1:1:2480:4
GUID
(UUID V4):
96004e13-7f9c-41ae-b610-d1bb1c9c3f0c

IMA Classification of ManganberzeliiteHide

Classification of ManganberzeliiteHide

8.AC.25

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.2.1.2
38.2.1.2

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
20.8.18

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
MbzlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ManganberzeliiteHide

Sub-Vitreous, Resinous, Greasy
Transparency:
Transparent, Translucent
Colour:
Yellow-orange, yellowish red; colorless to orange in transmitted light.
Comment:
Depth of red tint increases with increase in the Mn content.
Streak:
White to orange
Hardness:
4½ - 5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
4.28 - 4.46 g/cm3 (Measured)    4.38 g/cm3 (Calculated)
Comment:
Measured values are for the middle of the series with berzeliite to the Mn end member.

Optical Data of ManganberzeliiteHide

Type:
Isotropic
RI values:
n = 1.770 - 1.781
Birefringence:
Exhibits weak anomalous birefringence at times.
Surface Relief:
Very High
Pleochroism:
Non-pleochroic

Chemistry of ManganberzeliiteHide

Mindat Formula:
(NaCa2)Mn2+2(AsO4)3

Crystallography of ManganberzeliiteHide

Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Ia3d
Setting:
Ia3d
Cell Parameters:
a = 12.52 Å
Unit Cell V:
1,962.52 ų (Calculated from Unit Cell)
Morphology:
Crystals very rare, as trapezohedrons with small modifying faces. Commonly massive or as rounded grains.
Comment:
Nagashima & Armbruster (2012) give, for two crystals from different occurrences: 12.4829(1) and 12.4929(2) Å.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019614ManganberzeliiteNagashima M, Armbruster T (2012) Palenzonaite, berzeliite, and manganberzeliite:(As5+,V5+,Si4+)O4 tetrahedra in garnet structures Mineralogical Magazine 76 1081-10972012Varenche, Italy0293
0019615ManganberzeliiteNagashima M, Armbruster T (2012) Palenzonaite, berzeliite, and manganberzeliite:(As5+,V5+,Si4+)O4 tetrahedra in garnet structures Mineralogical Magazine 76 1081-10972012Gozaisho mine, Japan0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.10 Å(40)
3.34 Å(30)
3.13 Å(50)
2.80 Å(100)
2.67 Å(40)
2.56 Å(90)
1.736 Å(40)
1.673 Å(80)
Comments:
ICDD 20-1089 (synthetic)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits
Geological Setting:
Metamorphosed Mn deposits.

Type Occurrence of ManganberzeliiteHide

Geological Setting of Type Material:
Metamorphosed Mn deposit.
Associated Minerals at Type Locality:
Reference:
Igelström, L. J. (1878) Pyrrhoarsénite, nouveau minéral de Sjoegrufvan, paroisse de Grythyttan, gouvernement d'OErebro, Suède. Bulletin de la Société Française de Minéralogie, 9: 218-220

Synonyms of ManganberzeliiteHide

Other Language Names for ManganberzeliiteHide

Varieties of ManganberzeliiteHide

PyrrhoarseniteAn Sb-bearing variety of manganberzeliite (or berzeliite).
The valency of Sb is uncertain(?).
SilicomanganberzeliiteA silicate-bearing manganberzeliite.

Relationship of Manganberzeliite to other SpeciesHide

Other Members of this group:
Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
Palenzonaite(NaCa2)Mn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
Schäferite(NaCa2)Mg2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
Unnamed (Na-Ca-Ni Vanadate Garnet){NaCa2}[Ni2](V5+3)O12Iso. m3m (4/m 3 2/m) : Ia3d
Unnamed (Na-Fe Vanadate Garnet){Na3}[Fe3+2](V5+3)O12
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Manganberzeliite associated with FrankliniteZn2+Fe3+2O4
3 photos of Manganberzeliite associated with WillemiteZn2SiO4
3 photos of Manganberzeliite associated with Berzeliite(NaCa2)Mg2(AsO4)3
3 photos of Manganberzeliite associated with Magnetoplumbite(Pb,Mn)(Fe,Mn)12O19
3 photos of Manganberzeliite associated with Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3
2 photos of Manganberzeliite associated with RhodoniteCaMn3Mn[Si5O15]
2 photos of Manganberzeliite associated with Birnessite(Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O
2 photos of Manganberzeliite associated with RichteriteNa(NaCa)Mg5(Si8O22)(OH)2
1 photo of Manganberzeliite associated with TyroliteCa2Cu9(AsO4)4(CO3)(OH)8 · 11H2O
1 photo of Manganberzeliite associated with Actinolite◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2

Related Minerals - Strunz-mindat GroupingHide

8.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2O Orth. 2 2 2 : C2 2 21
8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3m : R3c
8.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric. 1 : P1
8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 : P1
8.AC.CrocobeloniteCaFe3+2O(PO4)2Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m : P21/m
8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric. 1 : P1
8.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth. mmm (2/m 2/m 2/m) : Pbca
8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m : R3c
8.AC.Crocobelonite-1MCaFe3+2O(PO4)2Mon. 2/m : P21/m
8.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 : P63
8.AC.MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m
8.AC.Epiebnerite(NH4)Zn(PO4)Mon. 2 : P21
8.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric. 1 : P1
8.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric. 1 : P1
8.AC.02ZiminaiteFe3+ 6 (VO4)6Tric. 1 : P1
8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Na□4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Ca□4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O Mon. 2/m : B2/m
8.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Zn-H Arsenate Hydrxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b
8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
8.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
8.AC.05ManganohatertiteNaNaCa(MnFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m : P21/m
8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.18ManitobaiteNa16Mn2+ 25Al8(PO4)30Mon. m : Pb
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m : R3c
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.47IwateiteNa2BaMn(PO4)2Trig. 3 : P3
8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47OzerovaiteNa2KAl3(AsO4)4Orth. mmm (2/m 2/m 2/m) : Cmca
8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth. mmm (2/m 2/m 2/m)
8.AC.50ChladniiteNa3CaMg11(PO4)9Trig. 3 : R3
8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig. 3 : R3
8.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig. 3 : R3
8.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.50UdinaiteNaMg4(VO4)3Tet. 4 2m : I4 2d
8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet. 4 2m : I4 2d
8.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth. mmm (2/m 2/m 2/m) : Pbcn
8.AC.55PharmazinciteKZnAsO4Hex. 6 : P63
8.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 : B2
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.70StanfielditeCa4Mg5(PO4)6Mon.
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Fluorescence of ManganberzeliiteHide

Not fluorescent.

Other InformationHide

Notes:
Readily soluble in HNO3 or HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ManganberzeliiteHide

References for ManganberzeliiteHide

Reference List:

Localities for ManganberzeliiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Salzburg
    • Tamsweg District
      • Tweng
Kolitsch et al. (2023)
  • Tyrol
    • Innsbruck-Land District
      • Navis
Kolitsch et al. (2019)
        • Staffelsee
Kolitsch et al. (2019)
BRANDSTÄTTER et al. (2015)
      • Obernberg am Brenner
Kolitsch (2020)
      • Pfons
Kolitsch et al. (2017)
    • Lienz District
      • Prägraten am Großvenediger
        • Timmelbach valley
Kolitsch et al. (2019)
Italy
 
  • Aosta Valley
    • Nus
      • Saint-Barthélemy
• Barresi et al. (2005)
  • Liguria
    • Genoa
      • Ne
Balestra (1991) +1 other reference
        • Reppia
Bracco et al. (2003)
        • Statale
//doi.org/10.57635/MICRO.2023.21.7
  • Lombardy
    • Sondrio Province
      • Lanzada
Bedognè et al. (1993) +1 other reference
  • Piedmont
    • Cuneo Province
      • Canosio
        • Vallone della Valletta
Cámara et al. (2014) +3 other references
      • Montaldo di Mondovì
        • Borgata Oberti
www.socgeol.it (n.d.) +1 other reference
Japan
 
  • Fukushima Prefecture
    • Iwaki City
Matsubara (1975) +2 other references
Kazakhstan
 
  • Ulytau Region
    • Zhanaarka District
      • Atasu Mine
Kayupova (1963)
Namibia
 
  • Otjozondjupa Region
    • Otavi Constituency
      • Kombat
Dunn (1991)
Portugal
 
  • Aveiro
    • Albergaria-a-Velha
      • Branca
Marques de Sá et al. (2010)
Slovakia
 
  • Košice Region
    • Spišská Nová Ves District
      • Poráč
Martin Števko & Pavol Myšľan
Sweden (TL)
 
  • Örebro County
    • Hällefors
      • Grythyttan
Igelström (1886)
  • Värmland County
    • Filipstad
      • Långban Ore District
American Mineralogist et al. (1968) +1 other reference
      • Nordmark mining district
        • Jakobsberg ore field
Holtstam (2001)
Switzerland
 
  • Grisons
    • Albula Region
      • Surses
        • Tinizong (Tinzen)
Stalder et al. (1998)
    • Viamala Region
      • Ferrera
        • Ausserferrera
Roth et al. (2013)
Brugger J. (1996)
Brugger (1996) +2 other references
      • Rheinwald
        • Splügen
Stalder et al. (1998) +1 other reference
USA
 
  • New Jersey
    • Sussex County
      • Franklin
Frondel et al. (1963) +1 other reference
Venezuela
 
  • Miranda
Onac et al. (2011)
Franco Urbani (2009)
 
矿物 and/or 产地  
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