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Keckite

A valid IMA mineral species
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07653140014977220069255.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
01597370014947557481751.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
00487570015861717922341.jpg
Keckite, etc.

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
02860040014947556859840.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
01597370014947557481751.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
05933250015812904638986.jpg
Keckite, etc.

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
07653140014977220069255.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
01597370014947557481751.jpg
Keckite

Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
Hide all sections | Show all sections

About KeckiteHide

02077230015365741789753.jpg
Erich Keck
Formula:
CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O
Colour:
Golden brown, orange brown
Lustre:
Sub-Vitreous, Resinous
Hardness:
4½
Specific Gravity:
2.6
Crystal System:
Monoclinic
Name:
Named by Arno Mücke in 1979 in honor of Erich Keck (b. 1938) of Germany, mineral collector specializing in Hagendorf minerals. His large collection of Hagendorf minerals is now preserved at Mineralogische Staatssammlung, Munich, Germany.
A member of the jahnsite group which contains trivalent iron not only at the C site but also at the B site.

Note: According to Hochleitner & Fehr (2010), keckite from Hagendorf forms golden-yellow to orange fibrous crusts which are intimately associated with rockbridgeite-frondelite. Specimens showing distinct "keckite" crystals in collections were found to be always either jahnsite-(CaMnFe) or jahnsite-(CaMnMn).

Compare Jahnsite-(CaMnFe).

Possibly intermediate between Jahnsite-(CaMnMn) and Jahnsite-(CaMnFe) and not a valid species, requires investigation into valance state and occupancy of the Fe.


Unique IdentifiersHide

Mindat ID:
2174
Long-form identifier:
mindat:1:1:2174:2
GUID
(UUID V4):
8a72b7c0-dd22-4531-9530-0c6abe4e6e50

IMA Classification of KeckiteHide

Classification of KeckiteHide

Strunz-mindat (2024):
8.DH.15

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Dana 8th ed.:
42.11.4.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Hey's CIM Ref.:
19.12.44

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KecIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of KeckiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of KeckiteHide

Lustre:
Sub-Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Golden brown, orange brown
Comment:
Possibly sore are red brown, but these tend to be other jahnsites.
Streak:
Yellow brown
Hardness:
4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
{001}, {100}
Fracture:
Irregular/Uneven, Splintery
Density:
2.6 g/cm3 (Measured)    2.682 g/cm3 (Calculated)
Comment:
Also D= 2.649

Optical Data of KeckiteHide

Type:
Biaxial (-)
Dispersion:
weak to distinct
Optical Extinction:
X ^ c = 15-20 degrees
Pleochroism:
Strong
Comments:
X reddish brown, Y yellow, Z bright yellow
Comments:
Undulatory extinction; Birefringence probably similar to other jahnsites

Chemistry of KeckiteHide

Mindat Formula:
CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O
Elements listed:
Ca, Fe, H, Mn, O, P - search for minerals with similar chemistry
Common Impurities:
Mg

Crystallography of KeckiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/a
Cell Parameters:
a = 15.02 Å, b = 7.19 Å, c = 19.74 Å
β = 110.5°
Ratio:
a:b:c = 2.089 : 1 : 2.745
Unit Cell V:
1,996.80 ų (Calculated from Unit Cell)
Morphology:
Tightly clustered bladed to stout crystals arranged in subparallel groups.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.3 Å(80)
4.98 Å(50)
4.63 Å(30)
3.51 Å(50)
2.86 Å(100)
2.59 Å(40)
2.34 Å(30)
1.879 Å(40)
Comments:
ICDD 33-289

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of KeckiteHide

Type Locality:
ⓘ Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany
General Appearance of Type Material:
Crusts of yellow-brown to golden brown indistinct crystals.
Geological Setting of Type Material:
Late stage oxidized mineralization in secondary phosphate-rich granite pegmatites.
Associated Minerals at Type Locality:
VivianiteStrengiteScholziteRockbridgeitePhosphosiderite
PhosphophylliteHureauliteApatiteApatite
Reference:
Mücke, A. (1979) Keckit, (Ca,Mg)(Mn,Zn)2Fe3+3[(OH)3|(PO4)4]·2H2O, ein neues Mineral von Hagendorf/Opf. und seine genetische Stellung. Neues Jahrbuch für Mineralogie, Abhandlungen: 134: 183-192.

Synonyms of KeckiteHide

Other Language Names for KeckiteHide

German:Keckit
Spanish:Keckita

Relationship of Keckite to other SpeciesHide

Member of:
Jahnsite Subgroup > Jahnsite Group
Other Members of this group:
Jahnsite-(CaFeFe){Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
Jahnsite-(CaFeMg)CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(CaMnZn)CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(MnMnFe)Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(MnMnMg)Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(MnMnMn){Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
Jahnsite-(MnMnZn)Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(NaFeMg)NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(NaMnMg){(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Jahnsite-(NaMnMn)NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Keckite associated with StrengiteFePO4 · 2H2O
5 photos of Keckite associated with RockbridgeiteFe2+Fe3+4(PO4)3(OH)5
4 photos of Keckite associated with PhosphophylliteZn2Fe(PO4)2 · 4H2O
4 photos of Keckite associated with StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2O
3 photos of Keckite associated with KingsmountiteCa3MnFeAl4(PO4)6(OH)4 · 12H2O
3 photos of Keckite associated with ScholziteCaZn2(PO4)2 · 2H2O
2 photos of Keckite associated with CryptomelaneK(Mn4+7Mn3+)O16
1 photo of Keckite associated with SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2O
1 photo of Keckite associated with PhosphosideriteFePO4 · 2H2O
1 photo of Keckite associated with BerauniteFe3+6(PO4)4O(OH)4 · 6H2O

Related Minerals - Strunz-mindat GroupingHide

8.DH.FerroberauniteFe2+Fe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DH.Rowleyite[Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl]Iso.
8.DH.Ammoniotinsleyite(NH4)Al2(PO4)2(OH) · 2H2OMon. 2/m : P21/m
8.DH.Thebaite-(NH4)(NH4)3Al(C2O4)(PO3OH)2(H2O)Mon. 2/m : P21/b
8.DH.Dendoraite-(NH4)(NH4)2NaAl(C2O4)(PO3OH)2(H2O)2Mon. 2/m
8.DH.Whiteite-(MnMnMn)Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.Whiteite-(CaMnFe)CaMnFe2Al2(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.HochleitneriteMn2Ti3(PO4)4O2(H2O)2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.RegeriteKFe6(PO4)4(OH)7(H2O)6 · 4H2OMon. 2/m : P21/b
8.DH.05MinyuliteKAl2(PO4)2F · 4H2OOrth. mm2 : Pba2
8.DH.10LeucophosphiteKFe3+2(PO4)2(OH) · 2H2OMon. 2/m : P21/b
8.DH.10Spheniscidite(NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2OMon. 2/m
8.DH.10TinsleyiteKAl2(PO4)2(OH) · 2H2OMon.
8.DH.15Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.15Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Jahnsite-(MnMnMn){Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Kaluginite(Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2OOrth.
8.DH.15Jahnsite-(CaFeFe){Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Jahnsite-(NaFeMg)NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMg){(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMgMg){Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.15Whiteite-(CaMnMn){Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(MnMnMg)MnMnMg2Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnMg)Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaFeMg)CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnFe)Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(CaMgMg)CaMg3Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnZn)Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMn)NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnZn)CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.20Lun'okite(Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20Manganosegelerite(Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20OveriteCaMgAl(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20SegeleriteCa2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pcca
8.DH.20WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20JuonniiteCaMgSc(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.25CalcioferriteCa2Fe3+2(PO4)3(OH) · 7H2OMon. 2/m : B2/b
8.DH.25KingsmountiteCa3MnFeAl4(PO4)6(OH)4 · 12H2OTric. 1 : P1
8.DH.25MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMon. 2 : B2
8.DH.25ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
8.DH.25FanfaniiteCa4MnAl4(PO4)6(OH)4 · 12H2OMon. 2/m : B2/b
8.DH.30ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30KolfaniteCa2Fe3+3O2(AsO4)3 · 2H2OMon.
8.DH.30MitridatiteCa2Fe3+3(PO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
8.DH.30RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
8.DH.30Sailaufite(Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2OMon. m : Bm
8.DH.35MantienneiteKMg2Al2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OMon. m
8.DH.35Benyacarite(H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35Hydroxylbenyacarite(H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O Orth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35MacraeiteK(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2OMon. 2/m : P21/b
8.DH.40XanthoxeniteCa4Fe3+2(PO4)4(OH)2 · 3H2OTric. 1 : P1
8.DH.45MahnertiteNaCu3(AsO4)2Cl · 5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.DH.50AndyrobertsiteKCdCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.50CalcioandyrobertsiteKCaCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.55EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2OMon. 2/m
8.DH.60BouazzeriteBi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2OMon. 2/m
8.DH.65GalliskiiteCa4Al2(PO4)2F8 · 5H2OTric. 1 : P1
8.DH.70JoteiteCa2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2OTric. 1 : P1
8.DH.75KampeliteBa6Mg3Sc8(PO4)12(OH)6 · 7H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DH.80KapundaiteNaCaFe4(PO4)4(OH)3 · 5H2OTric. 1 : P1
8.DH.85VaniniiteCa2Mn2+3Mn3+2O2(AsO4)4 · 2H2OMon. 2/m : P21/b

Fluorescence of KeckiteHide

In UV light:
Not fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KeckiteHide

References for KeckiteHide

Localities for KeckiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Victoria
    • East Gippsland Shire
      • Omeo
        • Mt Wills mining district
          • Dorchap Dyke Swarm
Dr. Bill Birch - Museum Victoria
DR Congo
 
  • South Kivu
    • Mwenga Territory
Mills et al. (2010)
Germany
 
  • Bavaria
    • Lower Bavaria
      • Regen District
        • Zwiesel
          • Rabenstein
Weiß (1990)
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Pleystein
Dill et al. (2008)
        • Waidhaus
Dill (2009)
Neues Jahrb.Min. (1979) +2 other references
Wittern (2001) +1 other reference
Portugal
 
  • Guarda
    • Gouveia
      • Folgosinho
    • Sabugal
      • Bendada
Schnorrer-Köhler (1991)
Spain
 
  • Castile and Leon
    • Salamanca
      • Navasfrías
www.foro-minerales.com (n.d.)
USA
 
  • New Hampshire
    • Grafton County
      • Groton
Whitmore et al. (2004) +2 other references
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