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Bukovskýite

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About BukovskýiteHide

08202580015343686176934.jpg
Antonín Bukovský
Formula:
Fe3+2(AsO4)(SO4)(OH) · 9H2O
Hardness:
5
Crystal System:
Triclinic
Name:
Named in 1967 by František Novák, Pavel Pavondra, and Jiňí Vtělenský in honor of Antonín Bukovský (1865–1950), Professor at the secondary school of Kutná Hora, Czech Republic, who first analyzed the mineral.
Chemically related to zýkaite.

Compare also Sanjuanite-Destinezite Group.


Classification of BukovskýiteHide

Approved
8.DB.40

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1
43.5.1.2

43 : COMPOUND PHOSPHATES, ETC.
5 : Hydrated Compound Phosphates, etc·, Containing Hydroxyl or Halogen
22.3.27

22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates

Physical Properties of BukovskýiteHide

Hardness:

Optical Data of BukovskýiteHide

Type:
Biaxial (+)
Dispersion:
very weak

Chemical Properties of BukovskýiteHide

Formula:
Fe3+2(AsO4)(SO4)(OH) · 9H2O
IMA Formula:
Fe3+2(AsO4)(SO4)(OH) · 7H2O

Crystallography of BukovskýiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.549(1) Å, b = 10.305(1) Å, c = 10.914(2) Å
α = 115.136(3)°, β = 99.798(3)°, γ = 92.864(3)°
Ratio:
a:b:c = 0.733 : 1 : 1.059
Unit Cell V:
750.27 ų (Calculated from Unit Cell)
Z:
4
Comment:
Originally given cell: 10.722, 14.079, 10.284 A, 93.50, 115.96, 90.27°.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.625 Å(43)
9.197 Å(100)
8.884 Å(60)
5.338 Å(20)
3.920 Å(35)
3.077 Å(36)
2.458 Å(23)

Type Occurrence of BukovskýiteHide

Synonyms of BukovskýiteHide

Other Language Names for BukovskýiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Bukovskýite associated with ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2O
1 photo of Bukovskýite associated with GypsumCaSO4 · 2H2O

Related Minerals - Nickel-Strunz GroupingHide

8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 5H2OAmor.
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.05DestineziteFe3+2(PO4)(SO4)(OH) · 6H2OTric. 1 : P1
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm (2/m 2/m 2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.20SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric.
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric.
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2O
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Related Minerals - Dana Grouping (8th Ed.)Hide

43.5.1.1SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
43.5.1.3SanjuaniteAl2(PO4)(SO4)(OH) · 9H2O

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

22.3.1ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2OOrth. mm2 : Pmn21
22.3.2ArdealiteCa2(HPO4)(SO4) · 4H2OMon. m : Bb
22.3.3Machatschkiite(Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2OHex.
22.3.4ClinotyroliteCa2Cu9(AsO4,SO4)4(OH,O)10 · 10H2OMon.
22.3.5PeisleyiteNa2Al9[(P,S)O4]8(OH)6•28H2OTric. 1 : P1
22.3.6ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2OTrig. 3 : R3
22.3.7WoodhouseiteCaAl3(PO4)(SO4)(OH)6Trig. 3m (3 2/m) : R3m
22.3.8Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig.
22.3.9SvanbergiteSrAl3(PO4)(SO4)(OH)6Trig. 3m (3 2/m) : R3m
22.3.10KemmlitziteSrAl3(AsO4)(SO4)(OH)6Trig.
22.3.11SanjuaniteAl2(PO4)(SO4)(OH) · 9H2O
22.3.12KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric. 1 : P1
22.3.13HotsoniteAl11(SO4)3(PO4)2(OH)21 · 16H2OTric.
22.3.14WeileriteBaAl3(AsO4)(SO4)(OH)6
22.3.15TsumebitePb2Cu(PO4)(SO4)(OH)Mon. 2/m : P21/m
22.3.16ArsentsumebitePb2Cu(AsO4)(SO4)(OH)Mon. 2/m : P21/m
22.3.17HinsdalitePbAl3(PO4)(SO4)(OH)6Trig. 3m (3 2/m) : R3m
22.3.18HidalgoitePbAl3(AsO4)(SO4)(OH)6Trig.
22.3.19OrpheitePbAl3(PO4)(SO4)(OH)6Trig.
22.3.20CoconinoiteFe3+2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2OMon.
22.3.21Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
22.3.22Tristramite(Ca,U,Fe)(PO4,SO4) · 2H2OHex.
22.3.23CorkitePbFe3(PO4)(SO4)(OH)6Trig. 3m (3 2/m) : R3m
22.3.24BeudantitePbFe3(AsO4)(SO4)(OH)6Trig. 3m (3 2/m) : R3m
22.3.25DiadochiteFe3+2(PO4)(SO4)(OH) · 5H2OAmor.
22.3.26SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
22.3.28ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2
22.3.29TooeleiteFe3+6(As3+O3)4(SO4)(OH)4 · 4H2OMon. 2/m : B2/m
22.3.30Pitticite(Fe, AsO4, H2O) (?)Amor.
22.3.31Xiangjiangite(Fe3+,Al)(UO2)4(PO4)2(SO4)2(OH) · 22H2OTet.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for BukovskýiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
American Mineralogist: 54: 991.
Johan, Z. (1986): Crystal symmetry and unit-cell of bukovskyite, Fe3+2(AsO4)(SO4)(OH).7H2O. Neues Jahrb. Mineral., Monatsh.: 445–451.
J. Majzlan, B. Lazic, Th. Armbruster, J. Plášil (2011) Crystal structure of bukovskýite, Fe2(AsO4)(SO4)(OH)·7H2O. Poster [http://onlinereg.ru/ccxrds/posters.pdf]
Majzlan, J., Lazic, B., Armbruster, T., Johnson, M.B., White, M.A., Fisher, R.A., Plášil, J., Loun, J., Škoda, R., Novák, M. (2012) Crystal structure, thermodynamic properties, and paragenesis of bukovskýite, Fe2(AsO4)(SO4)(OH)·9H2O. Journal of Mineralogical and Petrological Sciences: 107: 133-148.

Internet Links for BukovskýiteHide

Localities for BukovskýiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Carinthia
    • Spittal an der Drau District
      • Rennweg am Katschberg
        • Pölla valley
          • Lanisch
            • Arsenic mine
Niedermayr, Gerhard, (1999) Neue Mineralfunde aus Osterreich, XLVIII, p.213; Niedermayr, Gerhard, (1999) Neue Mineralfunde aus Osterreich, XLVIII, p.213
A.Pichler, A. (2009) Bergbau in Westkärnten, Eine Bestandsaufnahme der noch sichtbaren Merkmale der historischen Bergbaue in Westkärnten. Verlag des Naturwissenschaftlichen Vereins für Kärnten, Klagenfurt, Sonderheft 63, 416 pages [in German].
  • Salzburg
    • St. Johann im Pongau District
      • Bad Gastein
        • Siglitz - Bockhart gold mining district
A. Strasser: Die Minerale Salzburgs, 1989
      • Dorfgastein
A. Strasser: Die Minerale Salzburgs, 1989
    • Tamsweg District
      • Murwinkel
        • Rotgülden
          • Lower Rotgülden lake
W.H. Paar, J. Weidinger, R. Mrazek, H. Heiss: Lapis 18(5):13-28 (1993)
    • Zell am See District
      • Rauris
        • Alteck - Hoher Sonnblick area
Collection of NHM, Vienna
Czech Republic (TL)
 
  • Central Bohemian Region
    • Kutná Hora District
Acta Univ. Carolinae, Geol.(1967) 4, 297-325; Dobešová, B. (2012). Halda Kaňk: hydrogeochemie pórových vod. Masters Thesis MASARYKOVA UNIVERZITA
Aleš Tomek specimen
No reference listed
Germany
 
  • Saxony
    • Mittelsachsen
      • Großschirma
        • Großvoigtsberg
T. Witzke & M. Hocker (1993): Neue Vorkommen von Bukovskyit, Zykait und Kankit. Lapis 18(6), 49-50; Majzlan, J., Lazic, B., Armbruster, T., Johnson, M.B., White, M.A., Fisher, R.A., Plášil, J., Loun, J., Škoda, R., Novák. M. (2012): Crystal structure, thermodynamic properties, and paragenesis of bukovskýite, Fe2(AsO4)(SO4)(OH)·9H2O. Journal of Mineralogical and Petrological Sciences, 107, 133-148.
Ghana
 
  • Western Region
    • Ashanti gold belt
      • Obuasi
Craw, D., & Bowell, R. J. (2014). The characterization of arsenic in mine waste. Reviews in Mineralogy and Geochemistry, 79(1), 473-505.
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
Fritz Schreiber collection (analysed by Branko Rieck)
              • Hilarion area
Wendel, W. (2000): Lavrion-News 2000. Lapis 25 (10), 45-47; Kolitsch, U., Rieck, B., Brandstätter, F., Schreiber, F., Fabritz, K. H., Blaß, G. & Gröbner, J. (2014): Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (I). Mineralien-Welt 25 (1), 60-75 (in German). (p. 75)
  • East Macedonia and Thrace
    • Evros
      • Kirki Mines (Kirka)
Triantafyllidis, S. & Skarpelis, N. (2006): Mineral formation in an acid pit lake from a high-sulfidation ore deposit: Kirki, NE Greece. Journal of Geochemical Exploration 88, 68-71.
Italy
 
  • Liguria
    • Savona Province
      • Murialdo
Siuk-AMI /University of Turin - Italy
USA
 
  • Nevada
    • Humboldt Co.
      • Osgood Mts
        • Potosi Mining District
          • Adam Peak
            • Getchell Mine
Bowell, R. J., & Parshley, J. V. (2005). Control of pit-lake water chemistry by secondary minerals, Summer Camp pit, Getchell mine, Nevada. Chemical Geology, 215(1-4), 373-385.
 
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