Boussingaultite
A valid IMA mineral species - grandfathered
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About Boussingaultite
Formula:
(NH4)2Mg(SO4)2 · 6H2O
Colour:
Colourless, yellowish-pink; colourless in transmitted light.
Lustre:
Silky
Hardness:
2
Specific Gravity:
1.722
Crystal System:
Monoclinic
Member of:
Name:
Named by E. Bechi in 1864 in honor of Jean-Baptiste Joseph Dieudonné Boussingault (1 February 1801, Paris, France - 11 May 1887, Paris, France), chemist and professor at Lyon University, Lyon, France. He made significant contributions to agricultural science, petroleum science and metallurgy. He also discovered gaylussite.
Type Locality:
Picromerite Group, Boussingaultite-Mohrite Series.
May originate as an alteration (hydration) product of efremovite.
May originate as an alteration (hydration) product of efremovite.
Unique Identifiers
Mindat ID:
743
Long-form identifier:
mindat:1:1:743:4
GUID
(UUID V4):
(UUID V4):
4ab6f276-6ae1-4495-901d-f365c706ca74
IMA Classification of Boussingaultite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1864
Classification of Boussingaultite
7.CC.60
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.3.7.2
29 : HYDRATED ACID AND NORMAL SULFATES
3 : A2B(XO4)2·xH2O
29 : HYDRATED ACID AND NORMAL SULFATES
3 : A2B(XO4)2·xH2O
25.3.17
25 : Sulphates
3 : Sulphates of Mg
25 : Sulphates
3 : Sulphates of Mg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Bsg | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Boussingaultite
Silky
Transparency:
Transparent
Colour:
Colourless, yellowish-pink; colourless in transmitted light.
Hardness:
2 on Mohs scale
Cleavage:
Perfect
{_201}, perfect.
{_201}, perfect.
Density:
1.722 g/cm3 (Measured) 1.722 g/cm3 (Calculated)
Comment:
Measured on artificial material.
Optical Data of Boussingaultite
Type:
Biaxial (+)
RI values:
nα = 1.472 nβ = 1.473 nγ = 1.479
2V:
Measured: 51°
Max Birefringence:
δ = 0.007
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
perceptible r > v
Chemistry of Boussingaultite
Mindat Formula:
(NH4)2Mg(SO4)2 · 6H2O
Crystallography of Boussingaultite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 9.324(7) Å, b = 12.597(9) Å, c = 6.211(5) Å
β = 107.1°
β = 107.1°
Ratio:
a:b:c = 0.74 : 1 : 0.493
Unit Cell V:
697.26 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Short prismatic [001] with {001} prominent. Massive, crusts, stalactites.
Comment:
Synthetic
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0020241 | Boussingaultite | Montgomery H, Lingafelter E C (1964) The crystal structure of Tutton's salts. II. Magnesium ammonium sulfate hexahydrate and nickel ammonium sulfate hexahydrate Acta Crystallographica 17 1478-1479 | 1964 | synthetic | 0 | 293 | |
0010599 | Boussingaultite | Margulis T N, Templeton D H (1962) Crystal structure and hydrogen bonding of magnesium ammonium sulfate hexahydrate Zeitschrift fur Kristallographie 117 344-357 | 1962 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
4.22 Å | (100) |
2.085 Å | (95) |
5.11 Å | (85) |
7.20 Å | (70) |
3.79 Å | (70) |
1.818 Å | (65) |
2.189 Å | (55) |
Comments:
Synthetic, ICDD 17-135
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 3b: Earth’s earliest hydrosphere | >4.45 |
14 : Hot springs, geysers, and other subaerial geothermal minerals | |
Near-surface Processes | |
25 : Evaporites (prebiotic) | |
Stage 7: Great Oxidation Event | <2.4 |
45a : [Sulfates, arsenates, selenates, antimonates] | |
45b : [Other oxidized fumarolic minerals] | |
47a : [Near-surface hydration of prior minerals] | |
47b : [Sulfates and sulfites] | |
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
49 : Oxic cellular biomineralization (see also #44) | <0.54 |
50 : Coal and/or oil shale minerals | <0.36 |
Stage 10b: Anthropogenic minerals | <10 Ka |
54 : Coal and other mine fire minerals (see also #51 and #56) |
Geological Setting:
Geysers; anthracite mine dump fires (anthropogenic).
Type Occurrence of Boussingaultite
Place of Conservation of Type Material:
Natural History Museum, Paris, France, number 99.494.
National School of Mines, Paris, France, number 17853.
National School of Mines, Paris, France, number 17853.
Geological Setting of Type Material:
Boric acid fumaroles.
Reference:
Bechi, E. (1864) Mémoire sur les soffioni boracifères de Travale, en Toscane. Comptes Rendus Hebdomadaires des Séances de l'Académie des Sciences: 58: 583-584.
Other Language Names for Boussingaultite
Relationship of Boussingaultite to other Species
Member of:
Other Members of this group:
Cyanochroite | K2Cu(SO4)2 · 6H2O | Mon. 2/m : P21/b |
Katerinopoulosite | (NH4)2Zn(SO4)2 · 6H2O | Mon. 2/m : P21/b |
Mohrite | (NH4)2Fe(SO4)2 · 6H2O | Mon. 2/m : P21/b |
Nickelboussingaultite | (NH4)2Ni(SO4)2 · 6H2O | Mon. 2/m : P21/b |
Nickelpicromerite | K2Ni(SO4)2 · 6H2O | Mon. 2/m : P21/b |
Picromerite | K2Mg(SO4)2 · 6H2O | Mon. 2/m : P2/b |
Forms a series with:
Common Associates
Associated Minerals Based on Photo Data:
4 photos of Boussingaultite associated with Efremovite | (NH4)2Mg2(SO4)3 |
2 photos of Boussingaultite associated with Metavoltine | K2Na6Fe2+Fe3+6O2(SO4)12 · 18H2O |
2 photos of Boussingaultite associated with Hexahydrite | MgSO4 · 6H2O |
2 photos of Boussingaultite associated with Clairite | (NH4)2Fe3(SO4)4(OH)3 · 3H2O |
2 photos of Boussingaultite associated with Tschermigite | (NH4)Al(SO4)2 · 12H2O |
1 photo of Boussingaultite associated with Salammoniac | NH4Cl |
1 photo of Boussingaultite associated with Jarosite-Natrojarosite Series | |
1 photo of Boussingaultite associated with Lonecreekite | (NH4)Fe3+(SO4)2 · 12H2O |
1 photo of Boussingaultite associated with Sabieite | (NH4)Fe3+(SO4)2 |
1 photo of Boussingaultite associated with Chabazite-K | (K2,Ca,Na2,Sr,Mg)2[Al2Si4O12]2 · 12H2O |
Related Minerals - Strunz-mindat Grouping
7.CC. | Cobaltoblödite | Na2Co(SO4)2 · 4H2O |
7.CC. | Andychristyite | PbCu2+Te6+O5(H2O) |
7.CC. | Ammoniovoltaite | (NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18 |
7.CC.05 | Krausite | KFe(SO4)2 · H2O |
7.CC.10 | Tamarugite | NaAl(SO4)2 · 6H2O |
7.CC.15 | Kalinite | KAl(SO4)2 · 11H2O |
7.CC.15 | Mendozite | NaAl(SO4)2 · 11H2O |
7.CC.20 | Lonecreekite | (NH4)Fe3+(SO4)2 · 12H2O |
7.CC.20 | Alum-(K) | KAl(SO4)2 · 12H2O |
7.CC.20 | Alum-(Na) | NaAl(SO4)2 · 12H2O |
7.CC.20 | Tschermigite | (NH4)Al(SO4)2 · 12H2O |
7.CC.20 | Lanmuchangite | Tl+Al(SO4)2 · 12H2O |
7.CC.25 | Voltaite | K2Fe2+5Fe3+3Al(SO4)12 · 18H2O |
7.CC.25 | Zincovoltaite | K2Zn5Fe3+3Al(SO4)12 · 18H2O |
7.CC.25 | Pertlikite | K2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2O |
7.CC.25 | Ammoniomagnesiovoltaite | (NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2O |
7.CC.25 | Magnesiovoltaite | K2Mg5Fe3+3Al(SO4)12 · 18H2O |
7.CC.30 | Kröhnkite | Na2Cu(SO4)2 · 2H2O |
7.CC.35 | Ferrinatrite | Na3Fe(SO4)3 · 3H2O |
7.CC.40 | Goldichite | KFe(SO4)2 · 4H2O |
7.CC.45 | Löweite | Na12Mg7(SO4)13 · 15H2O |
7.CC.50 | Blödite | Na2Mg(SO4)2 · 4H2O |
7.CC.50 | Nickelblödite | Na2(Ni,Mg)(SO4)2 · 4H2O |
7.CC.50 | Changoite | Na2Zn(SO4)2 · 4H2O |
7.CC.55 | Leonite | K2Mg(SO4)2 · 4H2O |
7.CC.55 | Mereiterite | K2Fe(SO4)2 · 4H2O |
7.CC.60 | Cyanochroite | K2Cu(SO4)2 · 6H2O |
7.CC.60 | Mohrite | (NH4)2Fe(SO4)2 · 6H2O |
7.CC.60 | Nickelboussingaultite | (NH4)2Ni(SO4)2 · 6H2O |
7.CC.60 | Picromerite | K2Mg(SO4)2 · 6H2O |
7.CC.60 | Nickelpicromerite | K2Ni(SO4)2 · 6H2O |
7.CC.60 | Katerinopoulosite | (NH4)2Zn(SO4)2 · 6H2O |
7.CC.65 | Polyhalite | K2Ca2Mg(SO4)4 · 2H2O |
7.CC.70 | Leightonite | K2Ca2Cu(SO4)4 · 2H2O |
7.CC.75 | Amarillite | NaFe(SO4)2 · 6H2O |
7.CC.80 | Konyaite | Na2Mg(SO4)2 · 5H2O |
7.CC.85 | Wattevilleite | Na2Ca(SO4)2 · 4H2O (?) |
7.CC.85 | Xocolatlite | Ca2Mn4+2(Te6+O6)2 · H2O |
7.CC.90 | Eckhardite | (Ca,Pb)Cu2+Te6+O5(H2O) |
Fluorescence of Boussingaultite
Not fluorescent in UV
Other Information
Notes:
Water soluble, sharply astringent and saline taste
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Boussingaultite
mindat.org URL:
https://www.mindat.org/min-743.html
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References for Boussingaultite
Localities for Boussingaultite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Botswana | |
| Martini (1996) +1 other reference |
Canada | |
| Greengrass et al. (1999) |
Czech Republic | |
| Zacek et al. (1995) |
| Hyrsl J. +2 other references |
| Jirásek (2001) |
| Dalibor Matýsek |
Dalibor Matýsek | |
Germany | |
| Blaß et al. (1993) +1 other reference |
| T. Witzke & F. Rüger: Lapis 1998 (7/8) |
| T. Witzke & F. Rüger: Lapis 1998 (7/8) |
Hungary | |
| Szakáll et al. (2008) |
Italy | |
| Campostrini I. et al - Vulcano: ein ... |
| GARAVELLI A. et al. (1996) |
| Bechi (1864) +1 other reference |
Japan | |
| Shimobayashi et al. (2011) |
Lebanon | |
| Kruszewski et al. (South Lebanon) |
Netherlands | |
| De Wit et al. (2003) |
Peru | |
| Ciesielczuk et al. (2013) |
Poland | |
| Lukasz Kruszewski 2005: Minerals arising in cause of underground fires of "Skalny" coal mine dump in Laziska (Upper Silesia, Poland) +1 other reference |
| Kruszewski et al. (2019) |
| Parafiniuk et al. (2009) |
| Łukasz Kruszewski (2012) |
| Kruszewski et al. (2018) |
Russia | |
| Cesnokov et al. (1998) |
| Pekov (1998) |
Tajikistan | |
| D.I.Belakovskiy data |
USA | |
| Adams et al. (2014) |
Adams et al. (2014) | |
| Mineralogical Record: 9: 113 |
| e-rocks.com (n.d.) |
| Goldsmith (1877) +7 other references |
Goldsmith (1877) +2 other references | |
| Van Nostrand Reinholt Press: 270 +3 other references |
| Hower et al. (2013) |
| Carlson (2010) +1 other reference |
| Grant (Sep, 1974) +1 other reference |
| Grant (Jul, 1974) +3 other references |
| Wendlandt et al. (2006) |
| Hålenius et al. (2015) +1 other reference |
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Pécs-Vasas, Pécs District, Baranya County, Hungary