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Trilithionite

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About TrilithioniteHide

Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
Colour:
Pink-violet
Crystal System:
Monoclinic
Name:
When the formula above is doubled, so the subscripts are whole numbers, there are three ('tri') lithium atoms.
Mica Group.
Polylithionite-Trilithionite Series.

Several polytypes are known (see below).



Classification of TrilithioniteHide

Approved
9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets

Physical Properties of TrilithioniteHide

Colour:
Pink-violet

Chemical Properties of TrilithioniteHide

Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
IMA Formula:
KLi1.5Al1.5(Si3Al)O10F2

Crystallography of TrilithioniteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Trilithionite-2M2
 
Monoclinic 
2/m - Prismatic
B2/b
C2/c
a = 9.056 Å, b = 5.216 Å, c = 20.282 Å
β = 99.64°
a:b:c = 1.736 : 1 : 3.888
V 944.51 ų
(Calculated from Unit Cell)
 

Other Language Names for TrilithioniteHide

Varieties of TrilithioniteHide

Manganoan TrilithioniteA Manganoan variety

Relationship of Trilithionite to other SpeciesHide

Other Members of this group:
AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
BalestraiteKLi2V5+Si4O12Mon. 2 : B2
BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg)([Si/Al]Si2O10)(OH/F)2
EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric.
GarmiteCsLiMg2(Si4O10)F2Mon.
HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
LepidoliteA Li-rich mica in, or close to, the so-called Polylithionite-Trilithionite series.Mon.
Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon.
NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon.
ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
SokolovaiteCsLi2Al(Si4O10)F2Mon.
Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
TainioliteKLiMg2(Si4O10)F2Mon.
Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
ZinnwalditeMica Group.
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Trilithionite associated with QuartzSiO2
3 photos of Trilithionite associated with FluoriteCaF2
3 photos of Trilithionite associated with AquamarineBe3Al2Si6O18
3 photos of Trilithionite associated with MicroclineK(AlSi3O8)
1 photo of Trilithionite associated with ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)
1 photo of Trilithionite associated with MontebrasiteLiAl(PO4)(OH)
1 photo of Trilithionite associated with AlbiteNa(AlSi3O8)
1 photo of Trilithionite associated with LithiophiliteLiMn2+PO4

Related Minerals - Nickel-Strunz GroupingHide

9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.51.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon.
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon.
9.EC.15CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon.
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon.
9.EC.15AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2Mon.
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2Mon.
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon.
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon.
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon.
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon.
9.EC.20ShirokshiniteKNaMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(AlSi3O10)(F,OH)2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon.
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteLiCaAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon.
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon.
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)4((Si,Al)4O10)2(OH,F)4 · nH2OMon.
9.EC.45ZincsiliteZn3(Si4O10)(OH)2 · 4H2OMon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8Mon.
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(Al2Li)Al2(AlSi3O10)(OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon.
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon.
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon.
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for TrilithioniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Rieder, M., Cavazzini, G., D'Yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardi, G., Guggenheim, S., Koval', P.V., Müller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.-L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R. (1998) Nomenclature of the micas. The Canadian Mineralogist: 36: 905-912.
Brigatti, M. F., Caprilli E., Malferrari D., Medici L., Poppi L. (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2. European Journal of Mineralogy: 17(3): 475-481.

Internet Links for TrilithioniteHide

Localities for TrilithioniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Nepean
Peter Keller Collection
    • Upper Gascoyne Shire
      • Yinnietharra (Yinnietharra Station; Yinnetharra)
R. Bottrill, unpub data
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
Wilson, W E (2012) Famous Mimeral localities: The Jonas Mine, Itatiaia, Minas Gerais, Brazil. Mineralogical Record 43:289-317.
Canada
 
  • British Columbia
    • Revelstoke Mining Division
      • Revelstoke
RRUFF Database Specimen No. RO60004; Dixon, A. (2014, October). Mount Begbie Pegmatite Group, British Columbia, Canada–evolution from Barren to Complex Rare-element Pegmatites. In 2014 GSA Annual Meeting in Vancouver, British Columbia.
  • Manitoba
    • Red Cross Lake
Cerny et al. 2012; Černý, O., Teertstra, D.K., Chapman, R., Selway, J.B., Hawthorne, F.C., Ferreira, K., Chackowsky, L.E., Wang, X.J. & and Meintzer, R.E. (2012)
China
 
  • Henan
    • Sanmenxia
      • Lushi County
        • Guanpo
          • Guanpo pegmatite field
Fan G., Li G., Shen G., Xu J., Dai J. (2013): Luanshiweiite: A New Member of Lepidolite Series. Acta Mineralogica Sinica, 33, 713-721.
  • Jiangxi
    • Yichun
      • Yifeng Co.
Ganfu Shen and Jinsha Xu (2006): Acta Petrologica et Mineralogica 25(6), 463-472
  • Xinjiang
    • Yili Hasake Autonomous Prefecture (Ili Kazakh Autonomous Prefecture)
      • Aletai Prefecture (Altay Prefecture)
        • Fuyun Co. (Koktokay Co.)
          • Koktokay pegmatite field (Keketuohai pegmatite field)
            • Altay Mine
Wang, R.C., Hu, H., Zhang, A.C., Fontan, F., de Parseval, P., and Jiang, S.Y. (2007): Contributions to Mineralogy and Petrology 153, 355-367.
Czech Republic
 
  • South Bohemian Region
    • Český Krumlov District
Welser, P. et al.: Lithný pegmatit Nová Ves. Minerál, Special volume, 2007, roč. 15.; Novák, M., Ertl, A., Povondra, P., Vašinová Galiová, M., Rossman, G. R., Pristacz, H., ... & Škoda, R. (2013). Darrellhenryite, Na (LiAl2) Al6 (BO3) 3Si6O18 (OH) 3O, a new mineral from the tourmaline supergroup. American Mineralogist, 98(10), 1886-1892.
  • Ústí nad Labem Region
    • Krupka (Graupen)
      • Knöttel area (Knötel; Knödel; Knödlberg)
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
  • Vysočina Region
    • Třebíč District
      • Hrotovice
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
    • Žďár nad Sázavou District
      • Křižanov
Novák, M., Staněk, J.: Lepidolitový pegmatit od Dobré Vody u Velkého Meziříčí, západní Morava. Acta Musei Moraviae, Scientiae geologicae, 1999, roč. 84, s. 3 - 44.
      • Rožná
Novák, M., Houzar, S., Pfeiferová, A.: Přehled mineralogie, petrografie a historie klasické lokality lepidolitového pegmatitu v Rožné u Bystřice nad Pernštejnem, západní Morava. Acta Musei Moraviae, Sci. geol., 83:3-48.
P. Pauliš (2001): Nejzajímavější naleziště Moravy a Slezska. Kuttna, Kutná Hora.
P. Pauliš (2001): Nejzajímavější naleziště Moravy a Slezska. Kuttna, Kutná Hora.
Europe
 
  • Ore Mountains
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
Finland
 
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
Sandström, F. & Lahti, S.I. (2009): Viitaniemipegmatiten i Eräjärvi, Orivesi, Finland. Litiofilen 26 (1): 11-38
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Ambazac
Brigatti, M. F., Caprilli E., Malferrari D., Medici L. and Poppi L. (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2. European Journal of Mineralogy: 17(3): 475-481.
Germany
 
  • Saxony
    • Bautzen District
      • Weißenberg
        • Döbschütz
          • Arnsdorf-Melaune Quarry
T. Witzke & T. Giesler (2001): Neufunde aus Sachsen (VII): Bazzit, Bertrandit, Euxenit-(Y), Powellit und andere aus dem Königshainer Granit in der Lausitz.- Lapis 26 (1), 43-48
Italy
 
  • Trentino-Alto Adige
    • Trento Province (Trentino)
      • Canal San Bovo
        • Vanoi Valley
          • Pralongo
Venzo, Z., Bittarello, E., Canal, A., Ciriotti, M.E., Gasparetto, P., Pegoraro, S., Toffolo, L., Tosato, F. (2017): La Cava di granito "Grisotto" in località Pralongo, Valle del Vanoi, Canal San Bovo. Trento. Micro, 15, 1-2017, 44-62.
Japan
 
  • Fukuoka prefecture
    • Munakata City
www.petrovrareminerals.com/articles02.html
  • Ibaraki Prefecture
    • Hitachiota City
Kataoka & Uehara (2000) Koubutsu-Gakkai Kou'en-Youshi, 101.
Mozambique
 
University of Arizona Mineral Museum 13619
Norway
 
  • Telemark
    • Drangedal
      • Tørdal
Rosing-Schow, N., Müller, A. & Friis, H. (2017): Composition and classification of mica from south Norwegian pegmatites. PEG2017. NGF Abstracts and Proceedings, 2017 (2): 78-79.
Portugal
 
  • Castelo Branco
    • Covilhã
      • Barco
B. Charoy et al. , Eur.Journ. Mineral. , 1995, 7, pp. 335-352.
Spain
 
  • Community of Madrid
Tanago, J. G., Lozano, P. L., Larios, A. , La Iglesia, A. (2012) Stokesite crystals from La Cabrera, Madrid, Spain. Mineralogical Record 43:499-508
Ukraine
 
  • Zhytomyr Oblast
Lyckberg, P., Chornousenko, V. & Wilson, W. E. (2009): Volodarsk-Volynski, Zhitomir Oblast, Ukraine. Mineralogical Record, 40, 473-506.
USA
 
  • Colorado
    • Fremont Co.
      • Cotopaxi Mining District
RRUFF Database Specimen No. RO50486
    • Gunnison Co.
      • Quartz Creek Pegmatite Mining District
University of Arizona Mineral Museum 5528
 
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