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Tetraferriannite

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About TetraferrianniteHide

Formula:
KFe2+3(Si3Fe3+)O10(OH)2
Fe(III) may be replaced by minor Al.
Colour:
Brown to black
Lustre:
Adamantine, Vitreous
Hardness:
2½ - 3
Crystal System:
Monoclinic
Name:
In allusion to its composition and crystal structure, containing iron 3+ cations (FERRIc, from Latin ferrum = 'iron') in TETRAhedrally coordinated sites, and its chemical relationship to annite.
Mica Group. The ferric iron analogue of annite and ferrous iron analogue of tetraferriphlogopite.

The original name, ferri-annite, was changed by the CNMMN in 1998, Canadian Mineralogist 36, 905-12.


Classification of TetraferrianniteHide

Approved, 'Grandfathered' (first described prior to 1959)
8/H.11-120
9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.2b.4

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers

Physical Properties of TetraferrianniteHide

Adamantine, Vitreous
Colour:
Brown to black
Streak:
Light brown
Hardness:
2½ - 3 on Mohs scale

Optical Data of TetraferrianniteHide

Type:
Biaxial (-)
RI values:
nα = 1.660 nβ = 1.720 nγ = 1.728
Max Birefringence:
δ = 0.068
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
weak

Chemical Properties of TetraferrianniteHide

Formula:
KFe2+3(Si3Fe3+)O10(OH)2

Fe(III) may be replaced by minor Al.

Crystallography of TetraferrianniteHide

Crystal System:
Monoclinic

Type Occurrence of TetraferrianniteHide

Synonyms of TetraferrianniteHide

Other Language Names for TetraferrianniteHide

Relationship of Tetraferriannite to other SpeciesHide

Other Members of this group:
AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
FluoranniteKFe2+3(Si3Al)O10F2Mon.
FluorophlogopiteKMg3(AlSi3O10)(F,OH)2Mon. 2/m : B2/m
FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2

Related Minerals - Nickel-Strunz GroupingHide

9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.51.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon.
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon.
9.EC.15CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon.
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon.
9.EC.15AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2Mon.
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2Mon.
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon.
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon.
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon.
9.EC.20ShirokshiniteKNaMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(AlSi3O10)(F,OH)2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon.
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteLiCaAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon.
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon.
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)4((Si,Al)4O10)2(OH,F)4 · nH2OMon.
9.EC.45ZincsiliteZn3(Si4O10)(OH)2 · 4H2OMon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8Mon.
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(Al2Li)Al2(AlSi3O10)(OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon.
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon.
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon.
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Related Minerals - Dana Grouping (8th Ed.)Hide

71.2.2b.1PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
71.2.2b.3AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
71.2.2b.5SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
71.2.2b.6HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
71.2.2b.8PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
71.2.2b.9TainioliteKLiMg2(Si4O10)F2Mon.
71.2.2b.11NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
71.2.2b.12Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon.
71.2.2b.13Sodium PhlogopiteNaMg3(AlSi3O10)(OH)2
71.2.2b.14Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
71.2.2b.15PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon.
71.2.2b.16EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for TetraferrianniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Wones, D.R. (1963): Phase equilibria of “ferriannite”, KFe32+Fe3+Si3O10(OH)2. American Journal of Science 261, 581-596.
Donnay, G., Morimoto, N., Donnay, J.D.H., Takeda, H. (1964): Trioctahedral one-layer micas. I. Crystal structure of a synthetic iron mica. Acta Crystallographica 17, 1369-1373.
Miyano, T., Miyano, S. (1982): Ferri-annite from the Dales Gorge Member iron-formations, Wittenoom area, Western Australia. American Mineralogist 67, 1179-1194.
Canadian Mineralogist (1998): 36: 905-912. [The Nomenclature of Minerals: A Compilation of IMA Reports (1998) http://pubsites.uws.edu.au/ima-cnmnc/]
Burke, E.A.J. (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks. The Mineralogical Record 39, 131-135.

Internet Links for TetraferrianniteHide

Localities for TetraferrianniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia (TL)
 
  • Western Australia
    • Ashburton Shire
Miyano, T., Klein, C. (1983): Conditions of Reibeckite Formation In The Iron Formation Of The Dales Gorge Member, Hamersley Group, Western Australia, American Mineralogist (1983): 68: 517-529
AM 1982, 1179-94; CM 1998, 905-12
Austria
 
  • Burgenland
    • Oberpullendorf District
      • Kobersdorf
        • Pauliberg
Exel, R. (1993): Die Mineralien und Erzlagerstätten Österreichs. - Eigenverlag des Autors, Wien, 447 pp.
  • Carinthia
    • Villach
      • Afritz Mountains
        • Gummern
Canada
 
  • Nunavut
    • Qikiqtaaluk Region
      • Baffin Island
Hogarth (1997) Canadian Mineralogist 35, 53-78.
  • Ontario
www.excaliburmineral.com
Germany
 
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
Bender, D. and Krimmelbein, W. (1994) Aktuelle Übersicht: Mineralien der Zinkhütte Genna/Sauerland. Stand Juni 1994. Mineralien-Welt, 4/94, 10.
Italy
 
  • Abruzzo
    • Pescara Province
      • Pescosansonesco
Vichi, G., Stoppa, F., Wall, F. (2005): The carbonate fraction in carbonatitic Italian lamprophyres. Lithos, 85, 154-170.
Japan
 
  • Fukushima Prefecture
Introduction to Japanese Minerals (Geological Survey of Japan, 1970)
Niger
 
  • Agadez
    • Aïr Mountains
      • South Aïr
J. Fabriès and G. Rocci, Bull. Soc. Franç. Minéral. Cristallo., 1965, LXXXVIII, 319-340
South Africa
 
  • Northern Cape
    • Kalahari manganese field
      • Hotazel
No reference listed
South Korea
 
  • North Gyeongsang Province
    • Gyeongju City
Choi, H. O., Choi, S. H., Lee, D. C., & Kang, H. C. (2013). Geochemical evolution of basaltic volcanism within the tertiary basins of southeastern Korea and the opening of the East Sea (Sea of Japan). Journal of Volcanology and Geothermal Research, 249, 109-122.
Lee, M. J., Lee, J. I., & Lee, M. S. (1995). Mineralogy and major element geochemistry of A-type alkali granite in the Kyeongju area, Korea. 지질학회지, 31(6), 583-607.
USA
 
  • Arkansas
    • Hot Spring Co.
      • Magnet Cove
Henry Barwood - unpublished (2010)
 
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