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Bornemanite

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About BornemaniteHide

04298080015611523783915.jpg
Irina D. Borneman-Starynkevich
Formula:
Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F
Colour:
pale yellow
Lustre:
Pearly
Hardness:
3½ - 4
Specific Gravity:
3.47 - 3.5
Crystal System:
Triclinic
Name:
Named in honor of Irina Dmitrievna Borneman-Starynkevich (Ирины Дмитриевны Борнеман-Старынкевич) (31 December 1890 (12 January 1891), St. Petersburg, Russian Empire - 18 September 1988, Moscow, USSR), mineralogist at the Russian Academy of Sciences in Moscow, in recognition of her great contribution to the study of rare minerals and mineralogy of the Khibiny and Lovozero massif Kola Peninsula.
A heterophyllosilicate, related to bykovaite.


Classification of BornemaniteHide

Approved
Approval Year:
1973
First Published:
1975
9.BE.50

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.4.2.1

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
4 : Si2O7 Groups and O, OH, F, and H2O with [Si2O7] with other cation groups
17.6.8

17 : Silicates Containing other Anions
6 : Silicates with phosphate

Pronounciation of BornemaniteHide

Pronounciation:
PlayRecorded byCountry
Jolyon & Katya RalphUnited Kingdom

Physical Properties of BornemaniteHide

Pearly
Transparency:
Transparent, Translucent
Colour:
pale yellow
Hardness:
3½ - 4 on Mohs scale
Hardness:
VHN100=257 - 283 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
on {001}
Density:
3.47 - 3.5 g/cm3 (Measured)    3.49 g/cm3 (Calculated)

Optical Data of BornemaniteHide

Type:
Biaxial (+)
RI values:
nα = 1.682 - 1.683 nβ = 1.687 - 1.695 nγ = 1.718 - 1.720
2V:
Measured: 66° , Calculated: 46° to 72°
Max Birefringence:
δ = 0.036 - 0.037
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
strong
Pleochroism:
Weak
Comments:
X = Y = colourless; Z = brownish. Orientation X = c: Y = b: Z = a

Chemical Properties of BornemaniteHide

Formula:
Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F
IMA Formula:
Na6(Na◻)Ba2Ti2Nb2(Si2O7)4(PO4)2O4(OH)2F2
Common Impurities:
Zr,Al,Fe,Mn,Mg,Ca,Sr,Li,K,Rb

Crystallography of BornemaniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.4587(3) Å, b = 7.1421(5) Å, c = 24.528(2) Å
α = 96.790(1)°, β = 96.927(1)°, γ = 90.326(1)°
Ratio:
a:b:c = 0.764 : 1 : 3.434
Unit Cell V:
942.4 ų
Z:
2
Comment:
Pseudo-Ibam, 5.48, 7.10, 48.21 A.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
24.1 Å(100)
8.04 Å(100)
3.44 Å(100)
3.02 Å(100)
2.682 Å(80)
1.781 Å(70)
1.610 Å(80)

Type Occurrence of BornemaniteHide

General Appearance of Type Material:
platy aggregrates, to 1 cm, of fine leaflets along cleavages and on the surface of lomonossovite and in natrolite
Place of Conservation of Type Material:
Mining Institute, St. Petersberg, Russia; Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia; A.E.Fersman Mineralogical Museum, Moscow, Russia; The Natural History Museum, London, England; National Museum of Natural History, Washington, DC,
Geological Setting of Type Material:
In the natrolite zone of alkalic pegmatites in a differentiated alkalic massif
Reference:
Men'shikov, Y.P., Bussen, I.V., Goyko, Y.A., Zabavnikova, N.I., Mer'kov, A.N., Khomyakov, A.P. (1975) Bornemanite, a new silicophosphate of sodium, titanium, niobium, and barium. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 104(3): 322-326.

Synonyms of BornemaniteHide

Other Language Names for BornemaniteHide

German:Bornemanit
Simplified Chinese:磷硅铌钠钡石
Spanish:Bornemanita
Traditional Chinese:磷矽鈮鈉鋇石

Relationship of Bornemanite to other SpeciesHide

Other Members of this group:
Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon.
EmmerichiteBa2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
EpistoliteNa2(Nb,Ti)2(Si2O7)O2 · nH2OTric.
Fluorbarytolamprophyllite(Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
FluorlamprophylliteNa3(SrNa)Ti3(Si2O7)2O2F2Mon. 2/m : B2/m
InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4Tric. 1 : P1
KazanskyiteBaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon.
LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
NabalamprophylliteNa3(Ba,Na)2Ti3(Si2O7)2O2(OH,F)2Mon. 2/m
Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
SaamiteBa☐Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2Tric. 1 : P1
VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
ZvyaginiteNaZnNb2Ti[Si2O7]20(OH,F)3(H2O)4 + (x < 1)Tric. 1 : P1

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Bornemanite associated with LomonosoviteNa5Ti2(Si2O7)(PO4)O2

Related Minerals - Nickel-Strunz GroupingHide

9.BE.02Wadsleyite(Mg,Fe2+)2(SiO4)Orth.
9.BE.05HennomartiniteSrMn3+2(Si2O7)(OH)2 · H2OOrth.
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05NoelbensoniteBaMn3+2(Si2O7)(OH)2 · H2OOrth.
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2OOrth.
9.BE.07IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)Orth. mmm (2/m 2/m 2/m)
9.BE.07ManganilvaiteCaFe2+Fe3+Mn2+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.10SuoluniteCa2(H2Si2O7) · H2OOrth.
9.BE.12JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
9.BE.15FresnoiteBa2Ti(Si2O7)OTet. 4mm : P4bm
9.BE.17BaghdaditeCa3(Zr,Ti)(Si2O7)O2Mon.
9.BE.17BurpaliteNa2CaZr(Si2O7)F2Mon.
9.BE.17CuspidineCa4(Si2O7)(F,OH)2Mon. 2/m : P21/b
9.BE.17Hiortdahlite(Na,Ca)2Ca4Zr(Mn,Ti,Fe)(Si2O7)2(F,O)4Tric.
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
9.BE.17Låvenite(Na,Ca)2(Mn2+,Fe2+)(Zr,Ti)(Si2O7)(O,OH,F)2Mon. 2/m : P21/b
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2Mon.
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OFMon. 2/m : P21/b
9.BE.17WöhleriteNaCa2(Zr,Nb)(Si2O7)(O,OH,F)2Mon. 2 : P21
9.BE.17Hiortdahlite INa4Ca8Zr2(Nb,Mn,Ti,Fe,Mg,Al)2(Si2O7)4O3F5
9.BE.17MarianoiteNa2Ca4(Nb,Zr)2(Si2O7)2(O,F)4Mon. 2 : P21
9.BE.20Mosandrite-(Ce)(Ca3REE)[(H2O)2Ca0.50.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Ce)NbNa3Ca3(Ce,REE )(Si2O7)2OF3Mon.
9.BE.22GötzeniteNaCa6Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22Hainite-(Y)Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22RosenbuschiteNa6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
9.BE.22KochiteNa3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4Orth. mmm (2/m 2/m 2/m) : Pnnm
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
9.BE.25EricssoniteBaMn2+2Fe3+(Si2O7)O(OH)Mon. 2/m : B2/m
9.BE.25Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon.
9.BE.25Ericssonite-2OBaMn2+2Fe3+(Si2O7)O(OH)Orth.
9.BE.25SeidozeriteNa4MnZr2Ti(Si2O7)2O2F2Mon.
9.BE.25NabalamprophylliteNa3(Ba,Na)2Ti3(Si2O7)2O2(OH,F)2Mon. 2/m
9.BE.25GrenmariteNa4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25EmmerichiteBa2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25Fluorbarytolamprophyllite(Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2OTric.
9.BE.30EpistoliteNa2(Nb,Ti)2(Si2O7)O2 · nH2OTric.
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric.
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
9.BE.40InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4Tric. 1 : P1
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
9.BE.45QuadruphiteNa14Ca2Ti4(Si2O7)2(PO4)2O2FTric.
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
9.BE.50ShkatulkaliteNa5(Nb1−xTix)2(Ti1−yMn2+y)[Si2O7]2O2(OH)2·nH2O (x + y = 0.5; n <= 10)Mon. 2/m : P2/m
9.BE.55BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
9.BE.55HejtmaniteBa2(Mn2+,Fe2+)4Ti2(Si2O7)2O2(OH)2F2Tric. 1
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2OMon. 2/m
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon.
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
9.BE.67JinshajiangiteBaNaFe2+4Ti2(Si2O7)2O2(OH)2FTric. 1 : P1
9.BE.67PerraultiteBaNaMn2+4Ti2(Si2O7)2O2(OH)2FMon. 2/m : B2/m
9.BE.67SurkhobiteNaCaBa2Mn8Ti4(Si2O7)4O5F5Mon. 2 : B2
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2OAmor.
9.BE.70Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon.
9.BE.70Chevkinite-(Ce)(Ce,La,Ca,Th)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe,Mn2+,Mg)Fe3+2(Ti,Fe3+)2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70UKI-2008-(SiO:SrTiZr)Sr4ZrTi4(Si2O7)2O8Orth. mmm (2/m 2/m 2/m) : Pbca
9.BE.70Hezuolinite(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3Tric.
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12Hex.
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2Hex.
9.BE.80KentrolitePb2Mn3+2(Si2O7)O2Orth. mmm (2/m 2/m 2/m) : Pbcm
9.BE.80MelanotekitePb2Fe3+2(Si2O7)O2Orth. 2 2 2 : C2 2 21
9.BE.82TilleyiteCa5(Si2O7)(CO3)2Mon.
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon.
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30Trig. 3 : P31
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)Mon. 2/m : P21/b
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m
9.BE.95BatisiviteBaV3+8Ti6(Si2O7)O22Tric. 1 : P1

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

17.6.1NagelschmidtiteCa7(SiO4)2(PO4)2Hex. 6 : P61
17.6.2PerhamiteCa3Al7.7Si3P4O23.5(OH)14.1 · 8H2OTrig. 3m (3 2/m) : P3m1
17.6.3Viséite
17.6.4PhosinaiteNa13Ca2(Ce,La,Th,Nd,Pr)(Si4O12)(PO4)4
17.6.5ClinophosinaiteNa12(Ca,Sr)4(Si4O12)(PO4)4Mon.
17.6.6Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2OAmor.
17.6.7LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric.
17.6.9SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
17.6.10Laplandite-(Ce)Na4CeTiPO4Si7O18 · 5H2OOrth. mmm (2/m 2/m 2/m) : Pmmm
17.6.11 VunonnemiteNa5TiNb3Si6O25F2 · 2Na3PO4
17.6.12Saryarkite-(Y)Ca(Y,Th)Al5(SiO4)2(PO4,SO4)2(OH)7 · 6H2OTet. 4 2 2
17.6.13Steenstrupine-(Ce)Na14Mn2+2(Fe3+,Mn3+)2Ce6(Zr,Th)(Si6O18)2(PO4)6(HPO4)(OH)2 · 2H2OTrig.
17.6.14WaylanditeBiAl3(PO4)2(OH)6Trig. 3m (3 2/m) : R3m
17.6.15Britholite-(Ce)(Ce,Ca)5(SiO4)3OHHex. 6/m : P63/m
17.6.16Britholite-(Y)(Y,Ca)5(SiO4)3OHHex. 6/m : P63/m
17.6.17EylettersiteTh0.75Al3(PO4)2(OH)6Trig.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for BornemaniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Men'shikov, Y.P., Bussen, I.V., Goyko, Y.A., Zabavnikova, N.I., Mer'kov, A.N., Khomyakov, A.P. (1975) Bornemanite, a new silicophosphate of sodium, titanium, niobium, and barium. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 104(3): 322-326.
Men'shikov, Y.P., Bussen, I.V., Goyko, Y.A., Zabavnikova, N.I., Mer'kov, A.N., Khomyakov, A.P. (1976) Bornemanite, a new silicophosphate of sodium, titanium, niobium, and barium. International Geology Review: 18: 940-944.
Fleischer, M., Chao, G.Y., Mandarino, J.A. (1976) New mineral names. American Mineralogist: 61: 338-341.
Ferraris, G., Belluso, E., Gula, A., Soboleva, S. V., Ageeva, O. A., Borutskii, B. E. (2001) A structural model of the layer titanosilicate bornemanite based on seidozerite and lomonosovite modules. Canadian Mineralogist: 39: 1665-1673.
Cámara, F. and Sokolova, E. (2007) From structure topology to chemical composition. VI. Titanium silicates: the crystal structure and crystal chemistry of bornemanite, a group-III Ti-disilicate mineral. Mineralogical Magazine: 71: 593-610.
Sokolova, E. & Camara, F. (2017) The seidozerite supergroup of TS-block minerals: nomenclature and classification, with change of the following names: rinkite to rinkite-(Ce), mosandrite to mosandrite-(Ce), hainite to hainite-(Y) and innelite-1T to innelite-1A. Mineralogical Magazine: 81: 1457–1484

Internet Links for BornemaniteHide

Localities for BornemaniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Russia
 
  • Murmansk Oblast
www.koeln.netsurf.de/~w.steffens/khib.htm
    • Lovozersky District
      • Alluaiv Mt
        • Umbozero mine (Umbozerskii mine; Umba Mine)
A. P. Khomyakov et al., 2005
Pavel M. Kartashov data
Pakhomovsky, Y. A., Ivanyuk, G. Y., & Yakovenchuk, V. N. (2014). Loparite-(Ce) in rocks of the Lovozero layered complex at Mt. Karnasurt and Mt. Kedykvyrpakhk. Geology of Ore Deposits, 56(8), 685-698.
Men'shikov, Y.P., et al.: (1975): Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 104(3): 322-326.; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
      • Kedykverpakhk Mountain
        • Karnasurt mine (Kedyk area)
Mineralogical Record: 36(4): 397-416.
 
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