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Ferro-ferri-nybøite

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About Ferro-ferri-nybøiteHide

Formula:
NaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2
The nybøite group minerals are sodium amphiboles defined with A(Na+K+2Ca)> 0.5 apfu and C(Al+Fe3++2Ti) > 1.5 apfu

Ferro-ferri-nybøite is defined with

A position: Na dominant
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
Colour:
Black
Hardness:
6
Specific Gravity:
3.424 (Calculated)
Crystal System:
Monoclinic
Ferro-ferri-nybøite is related to endmember nybøite, NaNa2(Mg3Al2)Si8O22(OH)2 by the substitutions Fe2+ → Mg and Fe3+ → Al.


Classification of Ferro-ferri-nybøiteHide

Approved
Approval Year:
2013
9.DE.25

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles

Physical Properties of Ferro-ferri-nybøiteHide

Colour:
Black
Streak:
Greyish-green to black
Hardness:
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Perfect
on {110}
Fracture:
Splintery
Density:
3.424 g/cm3 (Calculated)

Chemical Properties of Ferro-ferri-nybøiteHide

Formula:
NaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2

The nybøite group minerals are sodium amphiboles defined with A(Na+K+2Ca)> 0.5 apfu and C(Al+Fe3++2Ti) > 1.5 apfu

Ferro-ferri-nybøite is defined with

A position: Na dominant
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
IMA Formula:
NaNa2(Fe2+3Fe3+2)(Si7Al)O22(OH)2
Idealised Formula:
NaNa2(Fe2+3Fe3+2)(Si7Al)O22(OH)2

Crystallography of Ferro-ferri-nybøiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 9.9190(5) Å, b = 18.0885(8) Å, c = 5.3440(3) Å
β = 103.813(1)°
Ratio:
a:b:c = 0.548 : 1 : 0.295
Unit Cell V:
931.09 ų
Z:
2
Morphology:
Prismatic parallel to [001]. Showing the forms: {100} and {110}. Grains, blocky aggregates.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.520Å(100)
3.298Å(7)
3.162Å(55)
2.834Å(24)
2.732Å(10)
2.552Å(10)
2.344Å(9)
1.671Å(19)

Type Occurrence of Ferro-ferri-nybøiteHide

General Appearance of Type Material:
Prismatic parallel to [001] showing {100} and {110} forms and cleavage surfaces. The prism direction is terminated by irregular fractures.
Place of Conservation of Type Material:
In the collections of the Department of Natural History, Royal Ontario Museum, Toronto, Ontario, Canada, catalogue number M55980
Geological Setting of Type Material:
Igneous microbreccia
Associated Minerals at Type Locality:

Synonyms of Ferro-ferri-nybøiteHide

Relationship of Ferro-ferri-nybøite to other SpeciesHide

Other Members of this group:
Ferri-fluoro-nybøiteNaNa2(Mg3Fe3+2)(AlSi7O22)F2
Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
Ferro-ferri-fluoro-nybøiteNaNa2(Fe2+3Fe3+2)(AlSi7O22)F2
Ferro-fluoro-nybøiteNaNa2(Fe2+3Al2)(AlSi7O22)F2
Ferro-nybøiteNaNa2(Fe2+3Al2)(AlSi7)O22(OH)2Mon.
Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon. 2/m : B2/m

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Ferro-ferri-nybøite associated with Ceriopyrochlore (of Hogarth 1977)A2Nb2(O,OH)6Z
1 photo of Ferro-ferri-nybøite associated with AlbiteNa(AlSi3O8)

Related Minerals - Nickel-Strunz GroupingHide

9.DE.Clino-suenoite□{Mn2+2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Cummingtonite☐{Mg2}{Mg5}(Si8O22)(OH)2Mon.
9.DE.05Clino-holmquistite Root Name Group☐{Li2}{Z2+3Z3+2}(Si8O22)(OH,F,Cl)2Mon.
9.DE.05Grunerite☐{Fe2+2}{Fe2+5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Permanganogrunerite☐{Mn2+2}{Mn2+5}(Si8O22)(OH)2Mon.
9.DE.05Ferri-fluoro-leakeite{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Actinolite☐{Ca2}{Mg4.5-2.5Fe0.5-2.5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe3+2}(Al2Si6O22)(OH)2Mon.
9.DE.10Ferro-actinolite☐{Ca2}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.10Ferro-hornblende☐{Ca2}{Fe2+4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Ferro-tschermakite☐{Ca2}{Fe2+3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10Joesmithite{Pb}{Ca2}{Mg3Fe3+2}(Be2Si6O22)(OH)2Mon.
9.DE.10Magnesio-hornblende☐{Ca2}{Mg4Al}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tschermakite☐(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2Mon.
9.DE.10Fluoro-cannilloite{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2Mon.
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Fluoro-tremolite☐{Ca2}{Mg5}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Ferro-ferri-hornblende☐Ca2(Fe2+4Fe3+)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Edenite{Na}{Ca2}{Mg5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-edenite{Na}{Ca2}{Fe2+5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe2+3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Ferro-pargasite{Na}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Kaersutite{Na}{Ca2}{Mg3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Si5Al3O22)(OH)2Mon.
9.DE.15Fluoro-edenite{Na}{Ca2}{Mg5}(AlSi7O22)(F,OH)2Mon. 2/m : P2/m
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe2+3Fe3+2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe2+3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Magnesio-fluoro-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Fluoro-pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe2+5}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsite{K}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-pargasite{K}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Ferri-kaersutiteNaCa2(Mg3Fe3+Ti)(Al2Si6O22)O2Mon. 2/m : B2/m
9.DE.15Vanadio-pargasiteNaCa2(Mg3+4V)(Al2Si6)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-taramiteNa(CaNa)(Fe2+3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
9.DE.20Ferro-ferri-barroisite☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe2+4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe2+3Fe3+2)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-richterite{Na}{CaNa}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.20Ferro-winchite ☐{CaNa}{Fe2+4Al}(Si8O22)(OH)2Mon.
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe2+4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Ferri-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)(OH)2Mon.
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
9.DE.20Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.20Winchite☐{CaNa}{Mg4Al}(Si8O22)(OH)2Mon. 2/m
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon. 2/m
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon.
9.DE.20Potassic-richterite{K}{CaNa}{Mg5}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferri-ghoseite☐[Mn2+Na][Mg4Fe3+]Si8O22(OH)2Mon. 2/m
9.DE.20Ferri-winchite☐[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.20Fluoro-katophoriteNa(CaNa)(Mg4Al)(AlSi7O22)F2Mon.
9.DE.20Ferri-fluoro-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)F2Mon. 2/m : B2/m
9.DE.25Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-eckermanniteNaNa2(Fe2+4Al)Si8O22(OH)2Mon.
9.DE.25Ferro-glaucophane◻[Na2][Fe2+3Al2]Si8O22(OH)2Mon.
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2Mon.
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.
9.DE.25Mangano-ferri-eckermannite{Na}{Na2}{Mn2+4Fe3+}Si8O22(OH)2Mon.
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Riebeckite◻[Na2][Fe2+3Fe3+2]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn2+2Mn3+3)(Si8O22)O2Mon.
9.DE.25Clino-ferro-ferri-holmquistite◻{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2Mon.
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
9.DE.25Mangani-dellaventuraite{Na}{Na2}{MgMn3+2LiTi4+}Si8O22O2Mon. 2/m : B2/m
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangani-obertiiteNa(Na2)(Mg3Mn3+Ti)(Si8O22)O2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]Mon. 2/m : B2/m
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe2+3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m
9.DE.25Ferri-obertiiteNa(Na2)(Mg3Fe3+Ti)(Si8O22)O2Mon. 2/m : B2/m

Fluorescence of Ferro-ferri-nybøiteHide

Non-fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferro-ferri-nybøiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.
Lussier, A.J., Hawthorne, F.C., Abdu, Y., Ball, N.A., Tait, K.T., Back, M.E., Steede, A.H., Taylor, R., MacDonald, A.M. (2013) Ferro-ferri-nybøite, IMA 2013-072. CNMNC Newsletter No. 18, December 2013, page 3251; Mineralogical Magazine: 77: 3249-3258.
Lussier, A.J., Hawthorne, F.C., Abdu, Y.A., Ball, N.A., Tait, K.T., Back, M.E., Steede, A.H., Taylor, R., McDonald, A.M. (2014) Ferro-ferri-nybøite, NaNa2(Fe2+3Fe3+2)Si8O22(OH)2, a new clinoamphibole from Mont Saint-Hilaire, Québec, Canada: Description and crystal structure. Canadian Mineralogist: 52: 1019-1026.
Lussier, A.J., Hawthorne, F.C., Abdu, Y.A., Ball, N.A., Tait, K.T., Back, M.E., Steede, A.H., Taylor, R., McDonald, A.M. (2017): Ferro-Ferri-Nybøite From Mont Saint-Hilaire, Québec, Canada: Correction. Canadian Mineralogist: 55: 515-516.

Internet Links for Ferro-ferri-nybøiteHide

Localities for Ferro-ferri-nybøiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Lussier, A.J., Hawthorne, F.C., Abdu, Y., Ball, N.A., Tait, K.T., Back, M.E., Steede, A.H., Taylor, R. and MacDonald, A.M. (2013) Ferro-ferri-nybøite, IMA 2013-072. CNMNC Newsletter No. 18, December 2013, page 3251; Mineralogical Magazine, 77, 3249 -3258.; Lussier, A.J., Hawthorne, F.C., Abdu, Y.A., Ball, N.A., Tait, K.T., Back, M.E., Steede, A.H., Taylor, R., McDonald, A.M. (2014): Ferro-ferri-nybøite, NaNa2(Fe2+3Fe3+2)Si8O22(OH)2, a new clinoamphibole from Mont Saint-Hilaire, Québec, Canada: Description and crystal structure. Canadian Mineralogist, 52, 1019-1026.
North Korea
 
  • Kangwon Province
    • Pyonggang County
Pavel M. Kartashov data
Norway
 
  • Vestfold
    • Larvik
      • Hedrum
        • Lysebo
Piilonen, P.C., McDonald, A.M., Poirier, G., Rowe, R. & Larsen, A.O. (2014): Mafic minerals of the alkaline pegmatites in the Larvik plutonic complex, Oslo rift, southern Norway. Canadian Mineralogist 51: 735-770
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
Konopleva, N.G., Ivanyuk, G.Y., Pakhomovsky, Y.A., Yakovenchuk, V.N., Men’shikov, Y.P., and Korchak, Y.A. (2008): Geology of Ore Deposits 50(8), 720-731.
      • Kukisvumchorr Mt
Konopleva, N.G., Ivanyuk, G.Y., Pakhomovsky, Y.A., Yakovenchuk, V.N., Men’shikov, Y.P., and Korchak, Y.A. (2008): Geology of Ore Deposits 50(8), 720-731.
Konopleva, N.G., Ivanyuk, G.Y., Pakhomovsky, Y.A., Yakovenchuk, V.N., Men’shikov, Y.P., and Korchak, Y.A. (2008): Geology of Ore Deposits 50(8), 720-731.
 
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