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Asimowite

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About AsimowiteHide

02771540015774889211203.jpg
Paul D. Asimow
Formula:
Fe2+4O(Si2O7)
although this formula would be typically written as β-Fe2+2SiO4 to emphasize its polymorphic relationship to fayalite, asimowite, like Mg-dominant wadsleyite, is actually a sorosilicate and not a member of the olivine group.
Crystal System:
Orthorhombic
Name:
Named in honor of Paul D. Asimow (b. 1969), professor of Geology and Geochemistry at the California Institute of Technology, for "his research in igneous and computational petrology and mineral physics and for exploring the behavior of materials under shock conditions."
Polymorph of:
Isostructural with:
The Fe2+ analogue of wadsleyite


Classification of AsimowiteHide

Approved
Approval year:
2018
First published:
2019
9.BE.X

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination

Chemical Properties of AsimowiteHide

Formula:
Fe2+4O(Si2O7)

although this formula would be typically written as β-Fe2+2SiO4 to emphasize its polymorphic relationship to fayalite, asimowite, like Mg-dominant wadsleyite, is actually a sorosilicate and not a member of the olivine group.
IMA Formula:
Fe2SiO4

Crystallography of AsimowiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Imma
Setting:
Imma
Cell Parameters:
a = 5.7485(4) Å, b = 11.5761(9) Å, c = 8.3630(7) Å
Ratio:
a:b:c = 0.497 : 1 : 0.722
Unit Cell V:
556.52 ų
Z:
8

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.708 Å(50)
2.650 Å(70)
2.506 Å(40)
2.471 Å(100)
2.220 Å(40)
2.088 Å(50)
2.036 Å(90)
1.460 Å(90)

Type Occurrence of AsimowiteHide

Place of Conservation of Type Material:
Collections of the Museo di Storia Naturale, Università di Firenze, Via La Pira 4, I-50121, Firenze, Italy, catalogue number 3238/I (holotype), and the Goethe University Frankfurt, Germany (cotype).
Associated Minerals at Type Locality:
Reference:
Bindi, L., Brenker, F.E., Nestola, F., Koch, T.E., Prior, D.J., Lilly, K., Krot, A.N., Bizzarro, M., Xie, X. (2019) Discovery of asimowite, the Fe-analog of wadsleyite, in shock-melted silicate droplets of the Suizhou L6 and the Quebrada Chimborazo 001 CB3.0 chondrites. American Mineralogist: 104(5): 775-778.

Synonyms of AsimowiteHide

Related Minerals - Nickel-Strunz GroupingHide

9.BE.BetalomonosoviteNa64Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF)Tric. 1 : P1
9.BE.BobshannoniteNa2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2Tric.
9.BE.Calciomurmanite(Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4Tric. 1 : P1
9.BE.Batievaite-(Y)Y2Ca2Ti(Si2O7)2(OH)2(H2O)4Tric. 1 : P1
9.BE.Delhuyarite-(Ce)Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2Mon. 2/m : B2/m
9.BE.02WadsleyiteMg4O(Si2O7)Orth.
9.BE.05HennomartiniteSrMn3+2(Si2O7)(OH)2 · H2OOrth.
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05NoelbensoniteBaMn3+2(Si2O7)(OH)2 · H2OOrth. mm2
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2OOrth.
9.BE.07IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)Orth. mmm (2/m 2/m 2/m)
9.BE.07ManganilvaiteCaFe2+Fe3+Mn2+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.10SuoluniteCa2(H2Si2O7) · H2OOrth.
9.BE.12JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
9.BE.15FresnoiteBa2Ti(Si2O7)OTet. 4mm : P4bm
9.BE.17BaghdaditeCa6Zr2(Si2O7)2O4Mon. 2/m : P21/b
9.BE.17BurpaliteNa2CaZr(Si2O7)F2Mon.
9.BE.17CuspidineCa4(Si2O7)(F,OH)2Mon. 2/m : P21/b
9.BE.17HiortdahliteNa2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3Tric. 1 : P1
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
9.BE.17Låvenite(Na,Ca)2(Mn2+,Fe2+)(Zr,Ti)(Si2O7)(O,OH,F)2Mon. 2/m : P21/b
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2Mon.
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OFMon. 2/m : P21/b
9.BE.17WöhleriteNaCa2(Zr,Nb)(Si2O7)(O,OH,F)2Mon. 2 : P21
9.BE.17Hiortdahlite INa4Ca8Zr2(Nb,Mn,Ti,Fe,Mg,Al)2(Si2O7)4O3F5Tric. 1 : P1
9.BE.20Mosandrite-(Ce)(Ca3REE)[(H2O)2Ca0.50.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Ce)NbNa3Ca3(Ce,REE )(Si2O7)2OF3Mon.
9.BE.22GötzeniteNaCa6Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22Hainite-(Y)Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22RosenbuschiteNa6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
9.BE.22KochiteNa3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4Orth. mmm (2/m 2/m 2/m) : Pnnm
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
9.BE.25EricssoniteBaMn2+2Fe3+(Si2O7)O(OH)Mon. 2/m : B2/m
9.BE.25Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon.
9.BE.25Ericssonite-2OBaMn2+2Fe3+(Si2O7)O(OH)Orth.
9.BE.25SeidozeriteNa4MnZr2Ti(Si2O7)2O2F2Mon.
9.BE.25NabalamprophylliteNa3(Ba,Na)2Ti3(Si2O7)2O2(OH,F)2Mon. 2/m
9.BE.25GrenmariteNa4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25EmmerichiteBa2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25Fluorbarytolamprophyllite(Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2OTric.
9.BE.30EpistoliteNa2(Nb,Ti)2(Si2O7)O2 · nH2OTric.
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric. 1 : P1
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
9.BE.40InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4Tric. 1 : P1
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
9.BE.45QuadruphiteNa14Ca2Ti4(Si2O7)2(PO4)2O2FTric.
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
9.BE.50BornemaniteNa6BaTi2Nb(Si2O7)2(PO4)O2(OH)F Tric. 1 : P1
9.BE.50ShkatulkaliteNa5(Nb1-xTix)2(Ti1-yMn2+y)[Si2O7]2O2(OH)2 · nH2OMon. 2/m : P2/m
9.BE.55BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
9.BE.55HejtmaniteBa2Mn2+4Ti2(Si2O7)2O2(OH)2F2Tric. 1
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2OMon. 2/m
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon.
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
9.BE.67JinshajiangiteBaNaFe2+4Ti2(Si2O7)2O2(OH)2FTric. 1 : P1
9.BE.67PerraultiteBaNaMn2+4Ti2(Si2O7)2O2(OH)2FMon. 2/m : B2/m
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2OAmor.
9.BE.70Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon.
9.BE.70Chevkinite-(Ce)(Ce,La,Ca,Th)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe,Mn2+,Mg)Fe3+2(Ti,Fe3+)2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70UM2008-53-SiO:SrTiZrSr4ZrTi4(Si2O7)2O8Orth. mmm (2/m 2/m 2/m) : Pbca
9.BE.70Hezuolinite(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3Tric.
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12Hex.
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2Hex.
9.BE.80KentrolitePb2Mn3+2(Si2O7)O2Orth. mmm (2/m 2/m 2/m) : Pbcm
9.BE.80MelanotekitePb2Fe3+2(Si2O7)O2Orth. 2 2 2 : C2 2 21
9.BE.82TilleyiteCa5(Si2O7)(CO3)2Mon.
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon.
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30Trig. 3 : P31
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)Mon. 2/m : P21/b
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m
9.BE.95BatisiviteBaV3+8Ti6(Si2O7)O22Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for AsimowiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Bindi, L., Brenker, F.E., Nestola, F., Koch, T.E., Prior, D.J., Lilly, K., Krot A.N., Bizzarro, M. and Xie, X. (2018) Asimowite, IMA 2018-102. CNMNC Newsletter No. 46, December 2018, page xxxx; Mineralogical Magazine, 82, xxxx–xxxx.
Bindi, L., Brenker, F.E., Nestola, F., Koch, T.E., Prior, D.J., Lilly, K., Krot, A.N., Bizzarro, M., Xie, X. (2019) Discovery of asimowite, the Fe-analog of wadsleyite, in shock-melted silicate droplets of the Suizhou L6 and the Quebrada Chimborazo 001 CB3.0 chondrites. American Mineralogist: 104(5): 775-778.

Internet Links for AsimowiteHide

Localities for AsimowiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
China (TL)
 
  • Hubei
    • Suizhou
      • Zengdu District (Cengdou District)
        • Xihe
Bindi, L., Brenker, F.E., Nestola, F., Koch, T.E., Prior, D.J., Lilly, K., Krot, A.N., Bizzarro, M., Xie, X. (2019) Discovery of asimowite, the Fe-analog of wadsleyite, in shock-melted silicate droplets of the Suizhou L6 and the Quebrada Chimborazo 001 CB3.0 chondrites. American Mineralogist: 104(5): 775-778.
 
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