Hydroxynatropyrochlore
A valid IMA mineral species
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Formula:
(Na,Ca,Ce)2Nb2O6(OH)
Colour:
Pale-brown
Lustre:
Adamantine, Greasy
Hardness:
5
Specific Gravity:
4.60
Crystal System:
Isometric
Member of:
Name:
Named according to the International Mineralogical Association recommended nomenclature for pyrochlore supergroup minerals, to indicate hydroxyl and sodium content.
This page provides mineralogical data about Hydroxynatropyrochlore.
Unique Identifiers
Mindat ID:
52584
Long-form identifier:
mindat:1:1:52584:2
GUID
(UUID V4):
(UUID V4):
09e346b4-2808-42fa-8d54-d06afea37ff2
IMA Classification of Hydroxynatropyrochlore
Approved
Approval year:
2017
First published:
2019
Classification of Hydroxynatropyrochlore
4.DH.15
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Hnpcl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Hydroxynatropyrochlore
Adamantine, Greasy
Transparency:
Transparent, Translucent
Colour:
Pale-brown
Streak:
White
Hardness:
5 on Mohs scale
Cleavage:
Distinct/Good
'Average' on {111}
'Average' on {111}
Parting:
None observed
Fracture:
Conchoidal
Density:
4.60(5) g/cm3 (Measured) 4.77 g/cm3 (Calculated)
Comment:
Measured using float-sink method in Clerici solution
Optical Data of Hydroxynatropyrochlore
Chemistry of Hydroxynatropyrochlore
Mindat Formula:
(Na,Ca,Ce)2Nb2O6(OH)
Crystallography of Hydroxynatropyrochlore
Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Fd3m
Setting:
Fd3m
Cell Parameters:
a = 10.3276(5) Å
Unit Cell V:
1101.5 ų
Z:
8
Morphology:
Cubes and truncated octahedrons
Twinning:
None observed
Comment:
a above from single crystal; a=10.3211(3) from powder diffraction
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.96 Å | (47) |
3.110 Å | (30) |
2.580 Å | (100) |
2.368 Å | (19) |
1.987 Å | (6) |
1.826 Å | (25) |
1.746 Å | (3) |
1.556 Å | (14) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks | |
36 : Carbonatites, kimberlites, and related igneous rocks |
Type Occurrence of Hydroxynatropyrochlore
General Appearance of Type Material:
Zonal cubic or cubo-octahedral crystals (up to 0.5 mm in diameter) with irregularly shaped relics of amorphous U-Ta-rich hydroxykenopyrochlore inside.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Mineralogical Museum, Saint-Petersburg State University, University Emb. 7/9, St. Petersburg 199034, Russia, catalogue number 1/19679
Associated Minerals at Type Locality:
Reference:
Ivanyuk, G.Y., Yakovenchuk, V.N., Panikorovskii, T.L., Konoplyova, N., Pakhomovsky, Y.A., Bazai, A.V., Bocharov, V.N., Krivovichev, S.V. (2019) Hydroxynatropyrochlore, (Na,Сa,Ce)2Nb2O6(OH), a new member of the pyrochlore group from the Kovdor phoscorite–carbonatite pipe, Kola Peninsula, Russia. Mineralogical Magazine: 83(1): 107-113.
Synonyms of Hydroxynatropyrochlore
Relationship of Hydroxynatropyrochlore to other Species
Member of:
Other Members of this group:
Cesiokenopyrochlore | ◻Nb2(O,OH)6(Cs,◻) | Iso. m3m (4/m 3 2/m) : Fd3m |
Fluorcalciopyrochlore | (Ca,Na)2(Nb, Ti)2O6F | Iso. |
Fluorhydropyrochlore | A possible new species (See discussion in Atencio et al. | |
Fluorkenopyrochlore | (◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F | |
Fluornatropyrochlore | (Na,Pb,Ca,REE,U)2Nb2O6F | Iso. m3m (4/m 3 2/m) |
Fluorplumbopyrochlore | (Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6F | Iso. |
Fluorstrontiopyrochlore | (Sr,◻)2Nb2(O,OH)6F | |
Hydrokenopyrochlore | (◻,x)2Nb2O6(H2O,Cs) | Iso. m3m (4/m 3 2/m) : Fd3m |
Hydropyrochlore | (H2O,◻)2Nb2(O,OH)6(H2O) | Iso. m3m (4/m 3 2/m) : Fd3m |
Hydroxycalciopyrochlore | (Ca,Na,U,◻)2(Nb,Ti)2O6(OH) | Iso. m3m (4/m 3 2/m) : Fd3m |
Hydroxykenopyrochlore | (◻,Ce,Ba)2(Nb,Ti)2O6(OH,F) | Iso. m3m (4/m 3 2/m) : Fd3m |
Hydroxymanganopyrochlore | (Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) | Iso. m3 (2/m 3) |
Hydroxyplumbopyrochlore | (Pb1.5◻0.5)Nb2O6(OH) | Iso. m3m (4/m 3 2/m) : Fd3m |
Kenoplumbopyrochlore | (Pb,◻)Nb2O6(◻,O) | |
Oxycalciopyrochlore | Ca2Nb2O6O | Iso. m3m (4/m 3 2/m) : Fd3m |
Oxynatropyrochlore | (Na,Ca,U)2Nb2O6(O,OH) | |
Oxyplumbopyrochlore | Pb2Nb2O6O | |
Oxyyttropyrochlore-(Y) | (Y,◻)2Nb2O6O | |
Unnamed (Sb-analogue of Hydroxymanganopyrochlor) | (Mn,Ca,Y)2(Sb,Ti)2O6(OH) |
Related Minerals - Strunz-mindat Grouping
4.DH. | Fluornatropyrochlore | (Na,Pb,Ca,REE,U)2Nb2O6F |
4.DH. | Roméite Group | A2(Sb5+)2O6Z |
4.DH. | Hydroxykenomicrolite | (◻,Na,Sb3+)2Ta2O6(OH) |
4.DH. | Fluornatroroméite | (Na,Ca)2Sb2(O,OH)6F |
4.DH. | Oxyplumboroméite | Pb2Sb2O6O |
4.DH. | Cesiokenopyrochlore | ◻Nb2(O,OH)6(Cs,◻) |
4.DH. | Oxyyttrobetafite-(Y) | Y2Ti2O6O |
4.DH.05 | Brannerite | UTi2O6 |
4.DH.05 | Orthobrannerite | U4+U6+Ti4O12(OH)2 |
4.DH.05 | Thorutite | (Th,U,Ca)Ti2(O,OH)6 |
4.DH.10 | Kassite | CaTi2O4(OH)2 |
4.DH.10 | Lucasite-(Ce) | CeTi2(O,OH)6 |
4.DH.15 va | Alumotungstite | ◻2W2O6(H2O) |
4.DH.15 | Bismutomicrolite (of Hogarth 1977) | |
4.DH.15 | Hydroplumboelsmoreite | (Pb,◻)(W,Fe3+)2O6 · H2O |
4.DH.15 | Hydropyrochlore | (H2O,◻)2Nb2(O,OH)6(H2O) |
4.DH.15 | Plumbomicrolite (of Hogarth 1977) | |
4.DH.15 | Stibiomicrolite (of Groat et al.) | |
4.DH.15 | Strontiopyrochlore (of Hogarth 1977) | A2Nb2(O,OH)6Z |
4.DH.15 | Fluornatromicrolite | (Na1.5Bi0.5)Ta2O6F |
4.DH.15 | Bismutopyrochlore (of Chukanov et al.) | (Bi,Ca,U,Pb)2-xNb2(O,OH)6(OH) |
4.DH.15 | Hydrokenoelsmoreite | ◻2W2O6(H2O) |
4.DH.15 | Fluorcalciomicrolite | (Ca,Na)2(Ta,Nb)2O6F |
4.DH.15 | Oxycalciobetafite | Ca2(Ti,Nb)2O6O |
4.DH.15 va | Yttromicrolite (of Hogarth) | (Ca,Y3+,U,Na)2-x(Ta,Nb,Ti,Fe3+)2O7 |
4.DH.15 | Oxynatropyrochlore | (Na,Ca,U)2Nb2O6(O,OH) |
4.DH.15 | Hydroxycalciopyrochlore | (Ca,Na,U,◻)2(Nb,Ti)2O6(OH) |
4.DH.15 | Fluorcalciopyrochlore | (Ca,Na)2(Nb, Ti)2O6F |
4.DH.15 | Oxycalciopyrochlore | Ca2Nb2O6O |
4.DH.15 | Fluorstrontiopyrochlore | (Sr,◻)2Nb2(O,OH)6F |
4.DH.15 | Oxyplumbopyrochlore | Pb2Nb2O6O |
4.DH.15 | Kenoplumbopyrochlore | (Pb,◻)Nb2O6(◻,O) |
4.DH.15 | Oxyyttropyrochlore-(Y) | (Y,◻)2Nb2O6O |
4.DH.15 | Fluorkenopyrochlore | (◻,Sr,Ce,Ca,Na)2(Nb,Ti)2O6F |
4.DH.15 | Oxyuranobetafite | (U,Ca,◻)2(Ti,Nb)2O6O |
4.DH.15 | Oxycalciomicrolite | Ca2Ta2O6O |
4.DH.15 | Oxystannomicrolite | Sn2Ta2O6O |
4.DH.15 | Kenoplumbomicrolite | (Pb,◻)2Ta2O6(◻,OH,O) |
4.DH.15 | Oxystibiomicrolite | (Sb3+,Ca)2Ta2O6O |
4.DH.15 | Hydromicrolite | (H2O,◻)2Ta2(O,OH)6(H2O) |
4.DH.15 | Hydrokenomicrolite | (◻,H2O)2Ta2(O,OH)6(H2O) |
4.DH.15 | Hydroxymanganopyrochlore | (Mn2+,Th,Na,Ca,REE)2(Nb,Ti)2O6(OH) |
4.DH.15 | Hydroxycalciomicrolite | Ca1.5Ta2O6(OH) |
4.DH.15 | Fluorplumbopyrochlore | (Pb,Y,Th,U,Na,Ca)2-x(Nb,Ti)2O6F |
4.DH.15 | Hydroxyplumbopyrochlore | (Pb1.5◻0.5)Nb2O6(OH) |
4.DH.15 | Oxynatromicrolite | (Na,Ca,U)2(Ta,Nb)2O6(O,F) |
4.DH.15 | Fluorhydropyrochlore | |
4.DH.15 | Hydroxykenoelsmoreite | (◻,Pb)2(W,Fe3+,Al)2(O,OH)6(OH) |
4.DH.15 | Hydrokenopyrochlore | (◻,x)2Nb2O6(H2O,Cs) |
4.DH.15 | Hydroxykenopyrochlore | (◻,Ce,Ba)2(Nb,Ti)2O6(OH,F) |
4.DH.15 | Hydroxynatromicrolite | (Na,Bi3+,◻)2Ta2O6(OH) |
4.DH.15 | Unnamed (Sb-analogue of Hydroxymanganopyrochlor) | (Mn,Ca,Y)2(Sb,Ti)2O6(OH) |
4.DH.15 | Oxybismutomicrolite | (Bi1.33◻0.67)Σ2Ta2O6O |
4.DH.20 | Bindheimite | Pb2Sb2O6O |
4.DH.20 | Hydroxycalcioroméite | (Ca,Sb3+)2(Sb5+,Ti)2O6(OH) |
4.DH.20 | Monimolite | Pb2Sb5+2O7 |
4.DH.20 | Cuproroméite | Cu2Sb2(O,OH)7 |
4.DH.20 | Stetefeldtite | Ag2Sb2(O,OH)7 |
4.DH.20 | Stibiconite | Sb3+Sb5+2O6(OH) |
4.DH.20 | Fluorcalcioroméite | (Ca,Na,◻)2Sb5+2(O,OH)6F |
4.DH.20 | Oxycalcioroméite | Ca2Sb2O6O |
4.DH.20 | Hydroxyferroroméite | (Fe2+1.5◻0.5)Sb5+2O6(OH) |
4.DH.25 | Rosiaite | PbSb5+2O6 |
4.DH.30 | Zirconolite | CaZrTi2O7 |
4.DH.30 | Laachite | (Ca,Mn)2Zr2Nb2TiFeO14 |
4.DH.30 | Nöggerathite-(Ce) | (Ce,Ca)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 |
4.DH.30 | Stefanweissite | (Ca,REE)2Zr2(Nb,Ti)(Ti,Nb)2Fe2+O14 |
4.DH.35 | Liandratite | U(Nb,Ta)2O8 |
4.DH.35 | Petscheckite | UFe(Nb,Ta)2O8 |
4.DH.40 | Ingersonite | Ca3Mn2+Sb5+4O14 |
4.DH.45 | Pittongite | Na0.22(W,Fe3+)(O,OH)3 · 0.44H2O |
4.DH.50 | Tazzoliite | Ba4-xNaxTi2Nb3SiO17[PO2(OH)2]x(OH)(1-2x) |
Other Information
Notes:
Slowly dissolves in hot HCl
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Hydroxynatropyrochlore
mindat.org URL:
https://www.mindat.org/min-52584.html
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References for Hydroxynatropyrochlore
Reference List:
Atencio, D., Andrade, M. B., Christy, A. G., Giere, R., Kartashov, P. M. (2010) The pyrochlore supergroup of minerals: nomenclature. The Canadian Mineralogist, 48 (3) 673-698 doi:10.3749/canmin.48.3.673
Localities for Hydroxynatropyrochlore
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Canada | |
| Horváth et al. (2019) |
Portugal | |
| Pedro Alves collection and analytical ... |
Russia | |
| Makagonov et al. (2017) |
| Ivanyuk et al. (2018) |
Ivanyuk et al. (2018) +1 other reference |
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