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Destinezite

A valid IMA mineral species - grandfathered
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About DestineziteHide

06229040014947283039313.jpg
Pierre Destinez
Formula:
Fe3+2(PO4)(SO4)(OH) · 6H2O
Colour:
Yellow, brownish yellow, brown, reddish brown, greenish yellow, pale green, pale yellow; pale yellow to yellowish brown in transmitted light
Lustre:
Dull, Earthy
Hardness:
3 - 4
Specific Gravity:
2.2
Crystal System:
Triclinic
Name:
Named by H. Forir and A. Jorissen in 1880 in honor of Mr. Pierre Destinez [died 7 April 1911 in Liège], a laboratory assistant at the University of Liège, Liège, Belgium. Destinez was a member of the Société Géologique de Belgique as early as 1886 and published a number of articles on paleontological subjects as late as 1904.
Sanjuanite-Destinezite Group.

Destinezite was redefined (IMA Code 00-E) as triclinic Fe2(PO4)(SO4)(OH)·6H2O, the crystalline counterpart of the amorphous diadochite.

Structurally related to arangasite.


Unique IdentifiersHide

Mindat ID:
5222
Long-form identifier:
mindat:1:1:5222:7
GUID
(UUID V4):
314de84b-d75c-48e9-a405-9a408704d4c9

IMA Classification of DestineziteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA status notes:
Redefined by the IMA
Approval year:
2002
First published:
1880
Approval history:
Redefined (IMA Code 00-E).

Classification of DestineziteHide

8.DB.05

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
DtzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DestineziteHide

Dull, Earthy
Colour:
Yellow, brownish yellow, brown, reddish brown, greenish yellow, pale green, pale yellow; pale yellow to yellowish brown in transmitted light
Hardness:
3 - 4 on Mohs scale
Fracture:
Conchoidal
Density:
2.2 g/cm3 (Measured)    2.33 g/cm3 (Calculated)

Optical Data of DestineziteHide

Type:
Biaxial (+)
RI values:
nα = 1.615 nβ = 1.625 nγ = 1.665
2V:
Measured: 55° , Calculated: 56°
Birefringence:
0.050
Max Birefringence:
δ = 0.050
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r

Chemistry of DestineziteHide

Mindat Formula:
Fe3+2(PO4)(SO4)(OH) · 6H2O

Crystallography of DestineziteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 9.584 Å, b = 9.748 Å, c = 7.338 Å
α = 93.07°, β = 95.78°, γ = 105.32°
Ratio:
a:b:c = 0.983 : 1 : 0.753
Unit Cell V:
655.53 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Rarely microcrystalline comprised of six-sided platy crystals.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012239DestinezitePeacor D R, Rouse R C, Coskren T D, Essene E J (1999) Destinezite ("diadochite"), Fe2(PO4)(SO4)(OH)*6(H2O): its crystal structure and role as a soil mineral at Alum Cave Bluff,Tennessee Clays and Clay Minerals 47 1-111999Alum Cave Bluff, Tennessee, USA0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.77 Å(90)
8.27 Å(80)
4.28 Å(100)
4.08 Å(70)
3.93 Å(100)
3.21 Å(40)
2.94 Å(80)

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of DestineziteHide

Place of Conservation of Type Material:
No designated type material.

Other Language Names for DestineziteHide

German:Destinezit
Spanish:Destinezita

Relationship of Destinezite to other SpeciesHide

Other Members of this group:
SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2

Common AssociatesHide

Associated Minerals Based on Photo Data:
7 photos of Destinezite associated with CopiapiteFe2+Fe3+4(SO4)6(OH)2 · 20H2O
6 photos of Destinezite associated with GypsumCaSO4 · 2H2O
4 photos of Destinezite associated with SideronatriteNa2Fe(SO4)2(OH) · 3H2O
2 photos of Destinezite associated with MetasideronatriteNa2Fe(SO4)2(OH) · H2O
1 photo of Destinezite associated with SeleniteCaSO4 · 2H2O
1 photo of Destinezite associated with KröhnkiteNa2Cu(SO4)2 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

8.DB.ArangasiteAl2F(PO4)(SO4) · 9H2O Mon. 2/m : P2/b
8.DB.Camaronesite[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2OTrig. 3 2 : R3 2
8.DB.HösliteFe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2OMon. 2/m : P21/b
8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 6H2OAmor.
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.07WilhelmgümbeliteZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2OOrth. mmm (2/m 2/m 2/m)
8.DB.07Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
8.DB.07WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm (2/m 2/m 2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.20SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric. 1 : P1
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric. 1 : P1
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.40BukovskýiteFe3+2(AsO4)(SO4)(OH) · 9H2OTric. 1 : P1
8.DB.40FlurliteZn3Mn2+Fe3+(PO4)3(OH)2 · 9H2OMon. 2/m : P21/m
8.DB.40ManganflurliteZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2OMon. 2/m : P21/m
8.DB.42BohuslaviteFe3+4(PO4)3(SO4)(OH) · nH2OTric. 1 : P1
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2
8.DB.47LapeyreiteCu3O[AsO3(OH)]2 · 0.75H2OMon. 2/m : B2/m
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.50RossiantoniteAl3(PO4)(SO4)2(OH)2(H2O)14Tric. 1 : P1
8.DB.52ArctowskiteAl9(PO4)8(OH)3 · 27H2OOrth.
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Other InformationHide

Notes:
Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DestineziteHide

References for DestineziteHide

Reference List:

Localities for DestineziteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Styria
    • Leoben District
      • Trofaiach
        • Rötzgraben
Brandstätter et al. (2008)
Belgium
 
  • Wallonia
    • Hainaut
      • Bernissart
        • Blaton
Van Tassel (1956) +7 other references
    • Liège
      • Amay
Hatert et al. (2002)
      • Dalhem
Hatert et al. (2002)
Hatert et al. (2002)
      • Héron
        • Couthuin
Hatert et al. (2002)
      • Liège
Hatert et al. (2002)
Jorissen (1880) +2 other references
Cesàro (1885) +4 other references
Mélon et al. (1976)
    • Namur
      • Anhée
Van Tassel (1985) +1 other reference
      • Namur
Blondieau (2012)
Dewalque (1880) +1 other reference
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Mejillones
        • Mejillones peninsula
Some of the Sulphates has been ...
SEM-EDS by Igor V. Pekov
    • El Loa Province
      • San Pedro de Atacama
Francisco Velasco et al. (2020)
Czech Republic
 
  • Central Bohemian Region
    • Beroun District
Vtělenský J. (1959)
  • Pardubice Region
    • Pardubice District
Prachař +6 other references
  • Prague
    • Hloubětín
Chlupáč (1988)
Germany
 
  • Thuringia
    • Greiz District
      • Kauern
T. Witzke & F. Rüger: Lapis 1998 (7/8)
    • Saalfeld-Rudolstadt District
      • Saalfeld
        • Garnsdorf
F. Rüger (1)
Hungary
 
  • Heves County
    • Parádfürdő
collector: János Nyúl
Italy
 
  • Tuscany
    • Lucca Province
      • Stazzema
        • Pontestazzemese
Orlandi P. et al. (Italien) +1 other reference
        • Sant'Anna di Stazzema
Mauro (2020)
Japan
 
  • Yamaguchi Prefecture
    • Abu District
      • Abu town
Matsubara et al. (1999)
Russia
 
  • Orenburg Oblast
    • Mednogorsk District
      • Sakmara Zone
German (1956)
Slovakia
 
  • Bratislava Region
    • Pezinok District
      • Pezinok
Spain
 
  • Catalonia
    • Barcelona
      • Baix Llobregat
        • Cervelló
Joan Rosell (2022)
    • Tarragona
      • Priorat
        • La Vilella Alta
Joan Abella i Creus (Joanabellacreus@gmail.com)
USA (TL)
 
  • Tennessee
    • Sevier County
Peacor et al. (1999) +3 other references
 
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