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Borisenkoite

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About BorisenkoiteHide

Formula:
Cu3[(V,As)O4]2
Colour:
Red-brown, golden-brown or brown
Lustre:
Adamantine, Greasy
Hardness:
Specific Gravity:
4.69 (Calculated)
Crystal System:
Monoclinic
Name:
Named in honor of Leonid Fedorovich Borisenko (1922–2000), Russian geochemist, mineralogist, and geologist.
The V analogue of lammerite-β. Most likely polymorphous with mcbirneyite and pseudolyonsite (to be confirmed).




Classification of BorisenkoiteHide

Approved
Approval Year:
2016
First Published:
2020
8.AB.

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
B : With medium-sized cations

Physical Properties of BorisenkoiteHide

Adamantine, Greasy
Transparency:
Translucent
Colour:
Red-brown, golden-brown or brown
Streak:
Yellowish-brown
Hardness:
4½ on Mohs scale
Hardness:
VHN20=234 - 379 kg/mm2 - Vickers
Comment:
Mohs hardness calculated
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Irregular/Uneven
Density:
4.69 g/cm3 (Calculated)

Optical Data of BorisenkoiteHide

Type:
Anisotropic
Anisotropism:
Weak
Bireflectance:
Very weak
Reflectivity:
400nmR1=16.8%R2=15.8%
420nmR1=16.1%R2=15.2%
440nmR1=15.7%R2=14.7%
460nmR1=15.2%R2=14.3%
470nmR1=15.1%R2=14.1%
480nmR1=14.9%R2=14.0%
500nmR1=14.6%R2=13.7%
520nmR1=14.4%R2=13.5%
540nmR1=14.2%R2=13.3%
546nmR1=14.1%R2=13.3%
560nmR1=13.9%R2=13.1%
580nmR1=13.8%R2=12.9%
589nmR1=13.7%R2=12.8%
600nmR1=13.6%R2=12.7%
620nmR1=13.4%R2=12.5%
640nmR1=13.3%R2=12.4%
650nmR1=13.2%R2=12.3%
660nmR1=13.1%R2=12.3%
680nmR1=13.0%R2=12.1%
700nmR1=12.8%R2=11.9%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 16.8%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Brownish-grey
Internal Reflections:
Strong, deep red-brown
Pleochroism:
Not Visible

Chemical Properties of BorisenkoiteHide

Formula:
Cu3[(V,As)O4]2

Crystallography of BorisenkoiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 6.3797(6) Å, b = 8.6052(1) Å, c = 11.348(1) Å
β = 91.985(8)°
Ratio:
a:b:c = 0.741 : 1 : 1.319
Unit Cell V:
622.62 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.309 Å(48)
3.424 Å(40)
2.994 Å(48)
2.917 Å(50)
2.868 Å(72)
2.830 Å(100)
2.782 Å(54)
2.568 Å(38)

Geological EnvironmentHide

Paragenetic Mode(s):
•  Fumarolic

Type Occurrence of BorisenkoiteHide

General Appearance of Type Material:
Prismatic crystals (up to 0.04 × 0.04 × 0.10 mm3) usually combined in clusters up to 0.4 mm and as rims up to 0.05 mm in width around lammerite.
Place of Conservation of Type Material:
collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia (registration
number 4824/1)
Geological Setting of Type Material:
Fumarole
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals: 47: 17.

Synonyms of BorisenkoiteHide

Related Minerals - Nickel-Strunz GroupingHide

8.AB.05FarringtoniteMg3(PO4)2Mon. 2/m
8.AB.10FerrisickleriteLi1-x(Fe3+xFe2+1-x)PO4Orth.
8.AB.10Heterosite(Fe3+,Mn3+)PO4Orth. mmm (2/m 2/m 2/m) : Pmna
8.AB.10LithiophiliteLiMn2+PO4Orth. mmm (2/m 2/m 2/m) : Pmna
8.AB.10NatrophiliteNaMn2+PO4Orth. mmm (2/m 2/m 2/m) : Pmna
8.AB.10PurpuriteMn3+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AB.10SickleriteLi1-x(Mn3+xMn2+1-x)PO4Orth.
8.AB.10SimferiteLi(Mg,Fe3+,Mn3+)2(PO4)2Orth.
8.AB.10TriphyliteLiFe2+PO4Orth. mmm (2/m 2/m 2/m) : Pmna
8.AB.10KarenwebberiteNaFe2+PO4Orth. mmm (2/m 2/m 2/m) : Pnma
8.AB.15Sarcopside(Fe2+,Mn2+,Mg)3(PO4)2Mon. 2/m : P21/b
8.AB.15Chopinite(Mg,Fe2+)3(PO4)2Mon. 2/m : P21/b
8.AB.20BeusiteMn2+Mn2+2 (PO4)2Mon.
8.AB.20GraftoniteFe2+Fe2+2(PO4)2Mon. 2/m : P21/b
8.AB.25XanthiositeNi3(AsO4)2Mon. 2/m : P21/b
8.AB.30LammeriteCu3(AsO4)2Mon.
8.AB.30Lammerite-βCu3(AsO4)2Mon. 2/m : P21/b
8.AB.35McbirneyiteCu3(VO4)2Tric. 1 : P1
8.AB.35StranskiiteZn2Cu(AsO4)2Tric. 1 : P1
8.AB.35PseudolyonsiteCu3(VO4)2Mon. 2/m : P21/b
8.AB.40LyonsiteCu3Fe4(VO4)6Orth.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for BorisenkoiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Y. (2016) Borisenkoite, IMA 2015-113. CNMNC Newsletter No. 30, April 2016, page 411. Mineralogical Magazine: 80: 407–413
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals: 47: 17.

Internet Links for BorisenkoiteHide

Localities for BorisenkoiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kamchatka Krai
    • Tolbachik volcano
      • Great Fissure eruption (Main Fracture)
        • Northern Breakthrough (North Breach)
          • Second scoria cone
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals: 47: 17.
 
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