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Betpakdalite Supergroup

A group of related mineral species

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Photos of Betpakdalite Supergroup (121)

Betpakdalite Supergroup Gallery Search Photos of Betpakdalite Supergroup

Edit Add Synonym Edit CIF structures Clear Cache

Betpakdalite-CaCa, etc.

Tsumeb Mine, Tsumeb, Oshikoto Region, Namibia

Mendozavilite-KCa

Punta de Su Seinargiu, Sarroch, Metropolitan City of Cagliari, Sardinia, Italy

Mendozavilite-NaCu

Chuquicamata Mine, Chuquicamata District, Calama, El Loa Province, Antofagasta, Chile

Betpakdalite-CaCa, etc.

Tsumeb Mine, Tsumeb, Oshikoto Region, Namibia

Mendozavilite-KCa

Punta de Su Seinargiu, Sarroch, Metropolitan City of Cagliari, Sardinia, Italy

Mendozavilite-NaCu

Chuquicamata Mine, Chuquicamata District, Calama, El Loa Province, Antofagasta, Chile

Betpakdalite-CaCa, etc.

Tsumeb Mine, Tsumeb, Oshikoto Region, Namibia

Mendozavilite-KCa

Punta de Su Seinargiu, Sarroch, Metropolitan City of Cagliari, Sardinia, Italy

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About Betpakdalite SupergroupHide

This page provides mineralogical data about Betpakdalite Supergroup.

Unique IdentifiersHide

Mindat ID:

46876

Long-form identifier:

mindat:1:1:46876:9

GUID
(UUID V4):

64ed8fbe-5cda-4e07-ae3b-cf921b4a20a8

IMA Classification of Betpakdalite SupergroupHide

IMA status notes:

IMA Approved Group Name

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005591	Betpakdalite-CaCa	Cooper M A, Hawthorne F C (1999) The crystal structure of betpakdalite, and a new chemical formula: {Mg(H2O)6}Ca2(H2O)13[Mo8As2Fe3O36(OH)](H2O)4 The Canadian Mineralogist 37 61-66		1999		0	293
0014792	Betpakdalite-CaCa	Schmetzer K, Nuber B, Tremmel G (1984) Betpakdalite from Tsumeb, Namibia: mineralogy, crystal chemistry and structure Neues Jahrbuch fur Mineralogie, Monatshefte 1984 393-403		1984	Tsumeb, Namibia	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Betpakdalite-CaCa'
loop_
_publ_author_name
'Cooper M A'
'Hawthorne F C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 37 
_journal_year 1999
_journal_page_first 61
_journal_page_last 66
_publ_section_title
;
 The crystal structure of betpakdalite, and a new chemical formula:
 {Mg(H2O)6}Ca2(H2O)13[Mo8As2Fe3O36(OH)](H2O)4
;
_database_code_amcsd 0005591
_chemical_formula_sum 'Mo8 As2 Fe3 Mg Ca2 O60 H47'
_cell_length_a 19.531
_cell_length_b 11.061
_cell_length_c 15.257
_cell_angle_alpha 90
_cell_angle_beta 131.57
_cell_angle_gamma 90
_cell_volume 2465.893
_exptl_crystal_density_diffrn      2.959
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Mo1   0.21480  -0.16070   0.19391   1.00000   0.00810
Mo2   0.37106   0.00000   0.19692   1.00000   0.00790
Mo3   0.37566   0.00000   0.42461   1.00000   0.01200
As  -0.13451   0.00000   0.05884   1.00000   0.00830
Fe1   0.75000   0.75000   0.00000   1.00000   0.01110
Fe2   0.00000   0.00000   0.00000   1.00000   0.01190
Mg   0.50000   0.00000   0.00000   1.00000   0.02240
Ca   0.15590  -0.17680   0.48800   0.50000   0.03300
O1   0.21260   0.00000   0.09260   1.00000   0.00940
O2   0.23750   0.00000   0.28520   1.00000   0.01150
O3   0.34230  -0.12490   0.10220   1.00000   0.01530
O4   0.35050  -0.11370   0.28690   1.00000   0.01350
O5   0.21840  -0.25460   0.10120   1.00000   0.01530
O6   0.09470  -0.12790   0.10070   1.00000   0.01540
O7   0.15130  -0.12430  -0.10560   1.00000   0.01730
O8   0.02850   0.00000  -0.10660   1.00000   0.01710
O9   0.37080  -0.12290   0.48890   1.00000   0.02330
O10   0.48730   0.00000   0.29260   0.50000   0.01760
O-H10   0.48730   0.00000   0.29260   0.50000   0.01760
O11   0.23460  -0.26080   0.29400   1.00000   0.01970
O12   0.50000   0.01400   0.50000   0.50000   0.01880
Wat1   0.46570  -0.13470   0.05860   1.00000   0.04830
Wat2   0.62940   0.00000   0.16500   1.00000   0.03970
Wat3  -0.20770   0.00000   0.22160   1.00000   0.04050
Wat4   0.12770  -0.05040   0.33900   0.50000   0.03680
Wat5  -0.10560  -0.03000   0.46440   0.50000   0.06980
Wat6  -0.29510  -0.04190   0.40390   0.50000   0.03190
Wat7  -0.23350  -0.20010   0.50280   0.50000   0.03850
Wat8   0.47980  -0.30680   0.35440   1.00000   0.12140
Wat9   0.05690  -0.23070   0.25970   0.50000   0.05370
Wat10   0.41700  -0.20000   0.70200   0.25000   0.04940
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Mo1 0.00990 0.00750 0.00860 0.00080 0.00690 0.00070
Mo2 76.00000 0.00820 0.00810 0.00000 0.00530 0.00000
Mo3 0.00960 0.01780 0.00830 0.00000 0.00580 0.00000
As 0.00830 0.00850 0.00840 0.00000 0.00570 0.00000
Fe1 0.01270 0.00940 0.01270 -0.00040 0.00900 0.00090
Fe2 0.01090 0.01420 0.01300 0.00000 0.00910 0.00000
Mg 0.01720 0.02700 0.02440 0.00000 0.01430 0.00000
Ca 0.03360 0.02610 0.03020 -0.00050 0.01720 0.01150
O1 0.01020 0.00880 0.00760 0.00000 0.00510 0.00000
O2 0.01110 0.01310 0.01160 0.00000 0.00810 0.00000
O3 0.01620 0.01330 0.01880 -0.00160 0.01250 -0.00350
O4 0.01330 0.01620 0.01320 0.00050 0.00980 0.00010
O5 0.02110 0.01310 0.01960 -0.00150 0.01680 -0.00220
O6 0.01400 0.01580 0.01670 0.00070 0.01030 0.00070
O7 0.02230 0.01420 0.01090 0.00610 0.00920 -0.00190
O8 0.00770 0.03350 0.01100 0.00000 0.00660 0.00000
O9 0.02330 0.02520 0.01550 -0.00260 0.01040 0.00230
O10 0.01240 0.02490 0.01340 0.00000 0.00760 0.00000
O-H10 0.01240 0.02490 0.01340 0.00000 0.00760 0.00000
O11 0.02550 0.01920 0.01700 0.00290 0.01510 0.00500
O12 0.00800 0.03140 0.01510 0.00000 0.00690 0.00000
Wat1 0.03700 0.06410 0.04620 -0.01990 0.02860 0.00020
Wat2 0.02300 0.05280 0.03350 0.00000 0.01460 0.00000
Wat3 0.05350 0.04000 0.04590 0.00000 0.04050 0.00000
Wat4 0.03180 0.06020 0.02400 0.00590 0.02080 0.01250
Wat5 0.07160 0.06760 0.05770 -0.01450 0.03760 0.00540
Wat6 0.03700 0.02790 0.03860 0.00320 0.02840 -0.00070
Wat7 0.06560 0.02510 0.04750 0.00840 0.04710 0.00100
Wat8 0.07380 0.06580 0.10780 0.01630 0.01100 -0.02240
Wat9 0.04460 0.04290 0.05580 -0.00130 0.02580 0.00110

Relationship of Betpakdalite Supergroup to other SpeciesHide

Group Members:

Betpakdalite Group
Betpakdalite-CaCa	[Ca₂(H₂O)₁₇Ca(H₂O)₆][Mo⁶⁺₈As⁵⁺₂Fe³⁺₃O₃₆(OH)]	Mon. 2/m : B2/m
Betpakdalite-CaMg	[Ca₂(H₂O)₁₇Mg(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₆(OH)]	Mon. 2/m : B2/m
Betpakdalite-FeFe	[Fe³⁺₂ (H₂O)₁₅(OH)₂Fe³⁺(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₇]	Mon. 2/m : B2/m
Betpakdalite-NaCa	[Na₂(H₂O)₁₇Ca(H₂O)₆][Mo⁶⁺₈As⁵⁺₂Fe³⁺₃O₃₄(OH)₃]	Mon. 2/m : B2/m
Betpakdalite-NaNa	[Na₂(H₂O)₁₆Na(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₃(OH)₄]	Mon. 2/m : B2/m
Mendozavilite Group
Melkovite	[Ca₂(H₂O)₁₅Ca(H₂O)₆][Mo₈P₂Fe³⁺₃O₃₆(OH)]	Mon. 2/m : B2/m
Mendozavilite-KCa	[K₂(H₂O)₁₅Ca(H₂O)₆][Mo₈P₂Fe³⁺₃O₃₄(OH)₃]	Mon. 2/m : B2/m
Mendozavilite-NaCu	[Na₂(H₂O)₁₅Cu(H₂O)₆][Mo₈P₂Fe³⁺₃O₃₄(OH)₃]	Mon. 2/m : B2/m
Mendozavilite-NaFe	[Na₂(H₂O)₁₅Fe³⁺(H₂O)₆][Mo₈P₂Fe³⁺₃O₃₅(OH)₂]	Mon. 2/m : B2/m
Obradovicite Group
Obradovicite-KCu	[K₂(H₂O)₁₇Cu(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₄(OH)₃]	Orth. mmm (2/m 2/m 2/m) : Pmna
Obradovicite-NaCu	Na₂(H₂O)₁₇Cu(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₄(OH)₃]	Orth. mmm (2/m 2/m 2/m) : Pmna
Obradovicite-NaNa	[Na₂(H₂O)₁₆Na(H₂O)₆][Mo₈As₂Fe³⁺₃O₃₃(OH)₄]	Orth.

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Betpakdalite SupergroupHide

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References for Betpakdalite SupergroupHide

Reference List:

Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09

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