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Falottaite

A valid IMA mineral species
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About FalottaiteHide

Formula:
MnC2O4 · 3H2O
Colour:
Colorless
Lustre:
Vitreous
Hardness:
Specific Gravity:
1.924 (Calculated)
Crystal System:
Orthorhombic
Name:
Named for the type locality, Falotta mine, Switzerland.
Dehydrates slowly (over several months) under ambient conditions to form the dihydrate lindbergite (Gröbner & Nikoleizig, 2009; Graeser & Gabriel, 2016). The originally colourless and transparent crystals turn white and opaque during the dehydration process. Stability studies of synthetic Mn oxalates indicate a dehydration temperature of about 30°C (Huizing et al., 1977).

Can also be created by fungi (A. niger) grown with hausmannite.

Known as a synthetic compound.


Unique IdentifiersHide

Mindat ID:
43915
Long-form identifier:
mindat:1:1:43915:6
GUID
(UUID V4):
e7c60b11-9882-4c1a-84e7-a7be69ea5912

IMA Classification of FalottaiteHide

Classification of FalottaiteHide

10.AB.X

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
B : Oxalates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
FltIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FalottaiteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
2½ on Mohs scale
Cleavage:
None Observed
Density:
1.924 g/cm3 (Calculated)

Optical Data of FalottaiteHide

Type:
Biaxial
RI values:
nα = 1.460 nγ = 1.560
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Max Birefringence:
δ = 0.100
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Non-pleochroic

Chemistry of FalottaiteHide

Mindat Formula:
MnC2O4 · 3H2O

Crystallography of FalottaiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:
a = 10.527(5) Å, b = 6.626(2) Å, c = 9.783(6) Å
Ratio:
a:b:c = 1.589 : 1 : 1.476
Unit Cell V:
682.4 ų
Z:
4
Morphology:
Elongated along c and flattened on b with main forms {010}, {100}, and {101} modified by minor {210} and {10.1.10}.
Twinning:
Common, unknown law.
Comment:
Space Group: Pcaa.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.630 Å(100)
6.630 Å(60)
3.801 Å(90)
3.153 Å(80)
2.959 Å(60)
2.697 Å(60)
2.622 Å(70)
2.122 Å(60)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47e : [Vanadates, chromates, manganates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4

Type Occurrence of FalottaiteHide

General Appearance of Type Material:
Well formed colorless ship-like crystals up to 1 × 0.5 mm, on quartz crystals.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Natural History Museum Basel, Basel, Switzerland, specimen number S69
Geological Setting of Type Material:
Alpine metamorphism of manganese ores. Then, presumably reaction of humus and oxalic acids (from plants) with those manganese minerals.
Reference:
Graeser, G., Gabriel, W. (2016) Falottait (MnC2O4)·3H2O) - ein neues Oxalat-Mineral aus den Schweizer Alpen. Schweizer Strahler: 50(3): 20-27.

Synonyms of FalottaiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Falottaite associated with LindbergiteMn2+(C2O4) · 2H2O

Related Minerals - Strunz-mindat GroupingHide

10.AB.Deveroite-(Ce)Ce2(C2O4)3 · 10H2OMon. 2/m : P21/b
10.AB.Uroxite [(UO2)2(C2O4)(OH)2(H2O)2] · H2OMon. 2/m : P21/b
10.AB.AndreybulakhiteNi(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.EdwindavisiteCu(C2O4)(NH3)Orth. mmm (2/m 2/m 2/m) : Pbca
10.AB.05HumboldtineFe2+(C2O4) · 2H2OMon. 2/m
10.AB.05LindbergiteMn2+(C2O4) · 2H2OMon. 2/m
10.AB.05KatsarositeZn(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.10GlushinskiteMg(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.15MoolooiteCu(C2O4) · nH2OOrth.
10.AB.20StepanoviteNaMgFe3+(C2O4)3 · 8-9H2OTrig. 3m : P3c1
10.AB.25MinguzziteK3Fe3+(C2O4)3 · 3H2OMon. 2/m : P21/b
10.AB.30WheatleyiteNa2Cu(C2O4)2 · 2H2OTric. 1 : P1
10.AB.35ZhemchuzhnikoviteNaMgAl(C2O4)3 · 8H2OTrig. 3m : P3c1
10.AB.40WeddelliteCa(C2O4) · (2.5-x)H2OTet. 4/m : I4/m
10.AB.45WhewelliteCa(C2O4) · H2OMon. 2/m : P21/b
10.AB.47FiemmeiteCu2(C2O4)(OH)2 · 2H2OMon. 2/m : P21/b
10.AB.50CaoxiteCa(C2O4) · 3H2OTric. 1 : P1
10.AB.50MiddlebackiteCu2C2O4(OH)2Mon. 2/m : P21/b
10.AB.52Metauroxite(UO2)2(C2O4)(OH)2(H2O)2Tric. 1 : P1
10.AB.55Oxammite(NH4)2(C2O4) · H2OOrth. 2 2 2 : P21 21 2
10.AB.60NatroxalateNa2(C2O4)Mon. 2/m : P21/b
10.AB.60Phoxite(NH4)2Mg2(C2O4)(PO3OH)2(H2O)4Mon. 2/m : P21/b
10.AB.60Carboferriphoxite[(NH4)K(H2CO3)][Fe3+(HPO4)(H2PO4)(C2O4)]Tric.
10.AB.60Ferriphoxite[(NH4)2K(H2O)][Fe3+(HPO4)2(C2O4)]Mon. 2/m : P21/b
10.AB.65Coskrenite-(Ce)(Ce,Nd,La)2(C2O4)(SO4)2 · 12H2OTric.
10.AB.70Levinsonite-(Y)(Y,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m
10.AB.75Zugshunstite-(Ce)(Ce,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m : B2/b
10.AB.80NovgorodovaiteCa2(C2O4)Cl2 · 2H2OMon. 2/m

Fluorescence of FalottaiteHide

Other InformationHide

Special Storage/
Display Requirements:
Without protection, crystals become milky white and opaque in a few months, dehydrating into lindbergite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FalottaiteHide

References for FalottaiteHide

Reference List:

Localities for FalottaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany
 
  • Lower Saxony
    • Goslar District
      • Clausthal-Zellerfeld
        • Zellerfeld veins
Gröbner et al. (2009)
Italy
 
  • Aosta Valley
    • Nus
      • Saint-Barthélemy
Franco Luca Bonino et al. (2023)
Switzerland (TL)
 
  • Grisons
    • Albula Region
      • Surses
        • Tinizong (Tinzen)
Atencio et al. (2004) +3 other references
 
矿物 and/or 产地  
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