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Willemseite

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About WillemseiteHide

Formula:
Ni3Si4O10(OH)2
Colour:
Light green
Lustre:
Waxy, Greasy
Crystal System:
Monoclinic
Name:
Named after Johannes Willemse (1909-1967), Professor of Geology, University of Pretoria (South Africa).
Ni end-member of the Pyrophyllite-Talc Group.


Classification of WillemseiteHide

Approved
9.EC.05

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.1.4

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
14.26.4

14 : Silicates not Containing Aluminum
26 : Silicates of Ni

Physical Properties of WillemseiteHide

Waxy, Greasy
Transparency:
Translucent
Colour:
Light green

Optical Data of WillemseiteHide

Type:
Biaxial (-)
RI values:
nα = 1.600 nβ = 1.652 nγ = 1.655
2V:
Measured: 27° , Calculated: 26°
Max Birefringence:
δ = 0.055
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v weak

Chemical Properties of WillemseiteHide

Formula:
Ni3Si4O10(OH)2
Common Impurities:
Al,Fe,Co,Ca,H2O

Crystallography of WillemseiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 5.31 Å, b = 9.14 Å, c = 18.99 Å
β = 99.97°
Ratio:
a:b:c = 0.581 : 1 : 2.078
Unit Cell V:
907.73 ų (Calculated from Unit Cell)

Type Occurrence of WillemseiteHide

Synonyms of WillemseiteHide

Other Language Names for WillemseiteHide

Relationship of Willemseite to other SpeciesHide

Other Members of this group:
FerripyrophylliteFe3+Si2O5(OH)Mon.
MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
PyrophylliteAl2Si4O10(OH)2Tric. 1
TalcMg3Si4O10(OH)2Tric. 1 : P1

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Willemseite associated with Falcondoite(Ni,Mg)4Si6O15(OH)2 · 6H2O
2 photos of Willemseite associated with TrevoriteNi2+Fe3+2O4
1 photo of Willemseite associated with PecoraiteNi3(Si2O5)(OH)4

Related Minerals - Nickel-Strunz GroupingHide

9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.9.EC.VoloshiniteRb(LiAl1.51.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon.
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon.
9.EC.15CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon.
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon.
9.EC.15AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2Mon.
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2Mon.
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon.
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2Mon.
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon.
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon.
9.EC.20ShirokshiniteKNaMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(AlSi3O10)(F,OH)2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon.
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteLiCaAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon.
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon.
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)4((Si,Al)4O10)2(OH,F)4 · nH2OMon.
9.EC.45ZincsiliteZn3(Si4O10)(OH)2 · 4H2OMon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8Mon.
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(Al2Li)Al2(AlSi3O10)(OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon.
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon.
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon.
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Related Minerals - Dana Grouping (8th Ed.)Hide

71.2.1.1PyrophylliteAl2Si4O10(OH)2Tric. 1
71.2.1.2FerripyrophylliteFe3+Si2O5(OH)Mon.
71.2.1.3TalcMg3Si4O10(OH)2Tric. 1 : P1
71.2.1.5MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

14.26.1Liebenbergite(Ni,Mg)2SiO4Orth.
14.26.2PecoraiteNi3(Si2O5)(OH)4Mon.
14.26.3Népouite(Ni,Mg)3(Si2O5)(OH)4Orth.
14.26.5Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
14.26.6Falcondoite(Ni,Mg)4Si6O15(OH)2 · 6H2OOrth.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for WillemseiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Nat. Inst. Met. (S.A.) Res. Rep. (1968): 352: 1-14.
American Mineralogist (1969): 54: 1740.
American Mineralogist (1970): 55: 31-42.
Villanova-de-Benavent, C., Tredoux, M., Aiglsperger, T., Proenza, J. (2014): Ni-Mg-phyllosilicates from Bon Accord, Barberton, South Africa: new data on willemseite and nimite. 21st General Meeting of the IMA (IMA2014), Gauteng, South Africa, September 1-5; Abstract Volume, 212.

Internet Links for WillemseiteHide

Localities for WillemseiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Queensland
    • Rockhampton Region
      • Marlborough
Eggleton, R.A., Fitzgerald, J., and Foster, L., 2011. Chrysoprase from Gumigil, Queensland. Australian Journal of Earth Science. 58, 767-776.
Dominican Republic
 
  • La Vega Province
    • Bonao
Villanova-de-Benavent, C., Proenza, J. A., Galí, S., Nieto, F., García-Casco, A., Roqué-Rosell, J., ... & Lewis, J. F. (2014). Mineralogy of Niphyllosilicates in the Falcondo Nilaterite deposit (Dominican Republic): A multiscale approach. In Proceedings ot the twenty first meeting of the International Mineralogical Association IMA (Vol. 298).
  • Monseñor Nouel Province
    • Bonao
M.E. Ciriotti (Steffen Moeckel analysis) 06/09/2007
France
 
  • New Caledonia
    • Northern Province
      • Houaïlou Commune
Berger, V.I., Singer, D.A., Bliss, J.D., and Moring, B.C., 2011, Ni-Co laterite deposits of the world; database and grade and tonnage models: U.S. Geological Survey Open-File Report 2011-1058.
      • Poya North Commune
Berger, V.I., Singer, D.A., Bliss, J.D., and Moring, B.C., 2011, Ni-Co laterite deposits of the world; database and grade and tonnage models: U.S. Geological Survey Open-File Report 2011-1058.
    • Southern Province
      • Yaté Commune
Wells, M.A., Ramanaidou, E.R., Verral, M., and Tessarolo, C., (2009) Mineralogy and crystal chemistry of “garnierites” in the Goro lateritic nickel deposit, New Caledonia. European Journal of Mineralogy, 21, p.467-483
Germany
 
  • Saxony
    • Vogtlandkreis
      • Limbach
Tröger, S. (2012): Der Steinbruch Reimersgrün im Sächsischen Vogtland. Lapis 37 (10), 32-39.
      • Plauen
        • Jocketa-Neuensalz District
          • Röttis
Andreas Gerstenberg collection
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion mining district
          • Km 3
            • Km 3 mines
Möckel, S. (2000): Strashimirit und 11 weitere Neubestimmungen aus Lavrion (GR). Lapis 25 (7-8), 74.
Indonesia
 
  • Central Sulawesi Province
    • Petasia
Wei Fu, Yongzhang Zhou, Yuanrong Chen, Yunhu Hu, Nanchun Chen, Hujie Niu, Zhiwei Zhang, and Xiaolong Li (2010): Earth Science Frontiers 17(2), 127-139
Romania
 
  • Harghita
    • Ditrău (Ditró)
      • Jolotca (Orotva)
Hirtopanu, P., Bermanec, V., Udubasa, G., & Melgarejo, J. C. (2000). Monazite and Allanite from the Ditrau Alkaline Massif, East Carpathians, Romania. Anuarul Institutului Geologic al Romaniei, 72, 41.
South Africa (TL)
 
  • Mpumalanga
    • Ehlanzeni District
      • Barberton
Nat.Inst.Met.(S.A.)Res.Rep.(1968) 352, 1-14; Am Min 55 (1970), 31; O'Driscoll, B., Clay, P. L., Cawthorn, R. G., Lenaz, D., Adetunji, J., & Kronz, A. (2014). Trevorite: Ni-rich spinel formed by metasomatism and desulfurization processes at Bon Accord, South Africa?. Mineralogical Magazine, 78(1), 145-163.; Zaccarini, F., Tredoux, M., Miller, D. E., Garuti, G., Aiglsperger, T., & Proenza, J. A. (2014). The occurrence of platinum-group element and gold minerals in the Bon Accord Ni-oxide body, South Africa. American Mineralogist, 99(8-9), 1774-1782.
  • North West
    • Dr Ruth Segomotsi Mompati District
      • Vryburg
www.lpi.usra.edu/meetings/impacts97/pdf/6055.pdf.; Andreoli, M. A., Maier, W. D., McDonald, I., Barnes, S. J., Roelofse, F., Cloete, M. C., ... & Hart, R. J. (2008). Siderophile minerals in the melt Sheet of the Morokweng impact crater, South Africa: similarities and differences with the Sudbury deposits. In Large Meteorite Impacts and Planetary Evolution IV (Vol. 1423).
Switzerland
 
  • Valais
    • Anniviers
      • Ayer
Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
      • Vissoie
Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
USA
 
  • Montana
    • Beaverhead Co.
      • Ruby Range
Gobla, M.J. (2012) Montana mineral locality index. Rocks & Minerals, 87, #3, 208-240.
 
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