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Wakabayashilite

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About WakabayashiliteHide

08639380014947871448295.jpg
Dr. Yaichiro Wakabayashi
Formula:
[(As,Sb)6S9][As4S5]
Colour:
Lemon-yellow to orange-yellow
Lustre:
Resinous
Hardness:
Specific Gravity:
3.98
Crystal System:
Orthorhombic
Name:
Named after Yaichiro Wakabayashi (30 August 1874, Kanazawa, Ishikawa Prefecture, Japan - 1943, Tokyo, Japan), mineralogist, Mitsubishi Mining Company (Japan). The mineral was discovered in his collection.


This page provides mineralogical data about Wakabayashilite.


Classification of WakabayashiliteHide

Approved
Approval Year:
1969
First Published:
1970
2.FA.40

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
F : Sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O
A : With As, (Sb), S
2.11.4.1

2 : SULFIDES
11 : AmBnXp, with (m+n):p = 2:3
3.7.12

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
7 : Sulphides etc. of V, As, Sb and Bi

Physical Properties of WakabayashiliteHide

Resinous
Transparency:
Translucent
Comment:
Silky as fibers, resinous as single crystals
Colour:
Lemon-yellow to orange-yellow
Streak:
Orange-yellow
Hardness:
1½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
Density:
3.98 g/cm3 (Measured)    4.06 g/cm3 (Calculated)

Chemical Properties of WakabayashiliteHide

Formula:
[(As,Sb)6S9][As4S5]
IMA Formula:
(As,Sb)6As4S14

Crystallography of WakabayashiliteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pna21
Cell Parameters:
a = 25.262 Å, b = 14.563 Å, c = 6.492 Å
Ratio:
a:b:c = 1.735 : 1 : 0.446
Unit Cell V:
2388.4 ų
Z:
4
Twinning:
Reticular merohedry

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.28 Å(100)
3.488 Å(80)
4.78 Å(70)
3.239 Å(40)
3.078 Å(40)
2.423 Å(40)
1.590 Å(40)

Type Occurrence of WakabayashiliteHide

General Appearance of Type Material:
Felt-like aggregates of fibers.
Place of Conservation of Type Material:
National Science Museum, Tokyo, Japan, MA5635.
National Museum of Natural History, Washington, D.C., USA, C252, 98012, 94600.
Associated Minerals at Type Locality:

Synonyms of WakabayashiliteHide

Other Language Names for WakabayashiliteHide

Common AssociatesHide

OrpimentAs2S3
RealgarAs4S4
Associated Minerals Based on Photo Data:
10 photos of Wakabayashilite associated with RealgarAs4S4
6 photos of Wakabayashilite associated with SmithiteAgAsS2
5 photos of Wakabayashilite associated with CalciteCaCO3
5 photos of Wakabayashilite associated with StibniteSb2S3
4 photos of Wakabayashilite associated with ChabournéiteTl4Pb2(Sb,As)20S34
3 photos of Wakabayashilite associated with Twinnite Pb0.8Tl0.1Sb1.3As0.8S4
3 photos of Wakabayashilite associated with OrpimentAs2S3
3 photos of Wakabayashilite associated with SarabauiteCaSb3+10S6O10
1 photo of Wakabayashilite associated with PierrotiteTl2(Sb,As)10S16
1 photo of Wakabayashilite associated with GetchelliteAsSbS3

Related Minerals - Nickel-Strunz GroupingHide

2.FA.AnorpimentAs2S3Tric. 1 : P1
2.FA.BonazziiteAs4S4Mon. 2/m : B2/b
2.FA.05DuranusiteAs4SOrth. mmm (2/m 2/m 2/m) : Pmna
2.FA.10DimorphiteAs4S3Orth. mmm (2/m 2/m 2/m) : Pnma
2.FA.15bPararealgarAs4S4Mon. 2/m : P21/b
2.FA.15aRealgarAs4S4Mon. 2/m
2.FA.15dUM1970-18-S:AsAs4S4Mon. 2/m : B2/b
2.FA.20AlacrániteAs8S9Mon. 2/m : P2/b
2.FA.25UzoniteAs4S5Mon.
2.FA.30LaphamiteAs2Se3Mon. 2/m
2.FA.30OrpimentAs2S3Mon. 2/m
2.FA.35GetchelliteAsSbS3Mon. 2/m : P21/b

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

3.7.1PatróniteVS4Mon.
3.7.2DuranusiteAs4SOrth. mmm (2/m 2/m 2/m) : Pmna
3.7.3DimorphiteAs4S3Orth. mmm (2/m 2/m 2/m) : Pnma
3.7.4RealgarAs4S4Mon. 2/m
3.7.5PararealgarAs4S4Mon. 2/m : P21/b
3.7.6AlacrániteAs8S9Mon. 2/m : P2/b
3.7.7UzoniteAs4S5Mon.
3.7.8OrpimentAs2S3Mon. 2/m
3.7.9JeromiteAmor.
3.7.10LaphamiteAs2Se3Mon. 2/m
3.7.11GetchelliteAsSbS3Mon. 2/m : P21/b
3.7.13PääkköneniteSb2AsS2Mon. 2/m : B2/m
3.7.14StibniteSb2S3Orth. mmm (2/m 2/m 2/m)
3.7.15MetastibniteSb2S3Amor.
3.7.16TellurantimonySb2Te3Trig.
3.7.17BismuthiniteBi2S3Orth. mmm (2/m 2/m 2/m)
3.7.18NevskiteBi(Se,S)Trig.
3.7.19GuanajuatiteBi2Se3Orth. mmm (2/m 2/m 2/m) : Pnma
3.7.21IkunoliteBi4(S,Se)3Trig.
3.7.22LaitakariteBi4Se2STrig. 3m : R3m
3.7.23PoubaitePbBi2(Se,Te,S)4Trig.
3.7.24TellurobismuthiteBi2Te3Trig.
3.7.25SoučekitePbCuBi(S,Se)3Orth.
3.7.26TsumoiteBiTeTrig. 3m (3 2/m) : P3 1m
3.7.27PilseniteBi4Te3Trig. 3m (3 2/m) : R3m
3.7.28HedleyiteBi7Te3Trig. 3m (3 2/m) : R3m
3.7.29TetradymiteBi2Te2STrig. 3m (3 2/m) : R3m
3.7.30JoséiteBi4TeS2Trig. 3m (3 2/m) : R3m
3.7.31Joséite-BBi4Te2STrig. 3m (3 2/m) : R3m
3.7.32IngoditeBi2TeSTrig.
3.7.33SulphotsumoiteBi3Te2STrig.
3.7.34KawazuliteBi2Te2SeTrig.
3.7.36SkippeniteBi2TeSe2Trig.
3.7.37KochkaritePbBi4Te7Trig.
3.7.38RucklidgeitePbBi2Te4Trig.
3.7.39AleksitePbBi2Te2S2Trig.
3.7.40JunoiteCu2Pb3Bi8(S,Se)16Mon. 2/m : B2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for WakabayashiliteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Kato, A., Sakurai, K., Ohsumi, K. (1970) Wakabayashilite (As,Sb)11S18. in Introduction to Japanese Minerals, Geological Survey of Japan: 39: 92-93.
Fleischer, M. (1972) New mineral names. American Mineralogist: 57: 1311-1317.
Scott, J.D., Nowacki, W. (1975) New data on wakabayashilite. The Canadian Mineralogist: 13: 418-419.
Bonazzi, P., Lampronti, G.I., Bindi, L., Zandari, S. (2005) Wakabayashilite, [(As,Sb)6S9][As4S5]: crystal structure, pseudosymmetry, twinning, and revised chemical formula. American Mineralogist: 90: 1108-1114.
Bonazzi, P., Bindi, L. (2008) A crystallographic review of arsenic sulfides: Effects of chemical variations and changes induced by exposure to light. Zeitschrift für Kristallographie: 223: 132-147.
Bindi, L., Bonazzi, P., Zoppi, M., Spry, P.G. (2014) Chemical variability in wakabayashilite: a real feature or an analytical artifact? Mineralogical Magazine: 78: 693-702.

Internet Links for WakabayashiliteHide

Localities for WakabayashiliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Chile
 
  • Atacama
    • Chañaral Province
      • Diego de Almagro
Econ Geol (1991) 86:1287-1300
China
 
  • Guangxi
    • Hechi
      • Jinchengjiang District
        • Beixiang - Furongchang ore field
Baogui Zhang (1985): Acta Mineralogica Sinica 5(3), 270-274
  • Guizhou
    • Qiannan
      • Huishui County
Xianxiao Xiong (2000): Acta Geologica Sinica (English Edition) 74(3), 618-622
    • Qianxinan
      • Ceheng County
Xianxiao Xiong (2000): Acta Geologica Sinica (English Edition) 74(3), 618-622
  • Yunnan
    • Chuxiong
      • Nanhua County
Xianxiao Xiong (2000): Acta Geologica Sinica (English Edition) 74(3), 618-622
France
 
  • Provence-Alpes-Côte d'Azur
    • Hautes-Alpes
      • La Chapelle-en-Valgaudemar (La Chapelle-en-Valgaudémar)
Am Min 90:1108-1114; Johan, Z. & Mantienne, J. (2000): Thallium-rich mineralization at Jas Roux, Hautes-Alpes, France: a complex epithermal, sediment-hosted, ore-forming system. J. Czech Geol. Soc. 45, 63-77.
Georgia
 
  • Racha-Lechkhumi and Kvemo Svaneti
    • Mestia-Racha District
Am Min 90:1108-1114
Japan (TL)
 
  • Gunma Prefecture
Introd.Japan.Min.,Geol.Surv.Japan (1970) 92-93; Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 1, 1990; 松原聰, & 宮脇律郎. (2005). 群馬県西ノ牧鉱山産パラ鶏冠石とアラクラン石. Bulletin of the National Science Museum. Series C, Geology & paleontology, 31, 1-6.
Kyrgyzstan
 
  • Batken Region
[Lapis 11:11-24]; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow; Bindi, L., Pratesi, G., Muniz-Miranda, M., Zoppi, M., Chelazzi, L., Lepore, G. O., & Menchetti, S. (2015). From ancient pigments to modern optoelectronic applications of arsenic sulfides: bonazziite, the natural analogue of β-As4S4 from Khaidarkan deposit, Kyrgyzstan. Mineralogical Magazine, 79(1), 121-131.
  • Osh Region
[Lapis 1993:11 p11-24]
Malaysia
 
  • Sarawak
    • Kuching Division
      • Bau
Rolf Luetcke collection (ex- Richard Gillespie collection)
Russia
 
  • Sakha Republic (Yakutia)
    • Ust-Yansky District
Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 1, 1990
  • Sverdlovsk Oblast
    • Serovsky District
      • Turinsk-Auerbakovsk ore field
        • Turya river
          • Tur'insk
Mikhail Tsyganko
USA
 
  • Nevada
    • Humboldt Co.
      • Osgood Mountains
        • Potosi Mining District
          • Adam Peak
NBMG Spec. Pub. 31 Minerals of Nevada
    • Mineral Co.
      • Rawhide Mining District
NBMG Spec. Pub. 31 Minerals of Nevada
    • Nye Co.
      • Toquima Range
        • Manhattan Mining District
          • Manhattan
            • Black Mammoth Hill
NBMG Spec Pub 31 Minerals of Nevada
Mineralogical Record 16:86
 
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