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Uranospathite

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08033920015293659965709.jpg
Uranospathite

Le Boucheron, Davignac, Ussel, Corrèze, Nouvelle-Aquitaine, France
09825060014979072188320.jpg
Uranospathite

Don Benito, Badajoz, Extremadura, Spain
01208120014968122201094.jpg
Uranospathite, etc.

Markey Mine, Red Canyon, San Juan Co., Utah, USA
06340100015283901614184.jpg
Uranospathite

Le Boucheron, Davignac, Ussel, Corrèze, Nouvelle-Aquitaine, France
06094350014950554763417.jpg
Uranospathite

Don Benito, Badajoz, Extremadura, Spain
00567110014953370454758.jpg
Uranospathite, etc.

Markey Mine, Red Canyon, San Juan Co., Utah, USA
08033920015293659965709.jpg
Uranospathite

Le Boucheron, Davignac, Ussel, Corrèze, Nouvelle-Aquitaine, France
08823810014950620532155.jpg
Uranospathite

Don Benito, Badajoz, Extremadura, Spain
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About UranospathiteHide

Formula:
(Al,◻)(UO2)2(PO4)2F · 20(H2O,F)
Colour:
Yellow, light yellow-green, pale green
Hardness:
2 - 2½
Specific Gravity:
2.5
Crystal System:
Orthorhombic
Name:
In allusion to its composition, containing URANium plus Greek σπάθη for "SPATHe", sword or broad blade, alluding to its common habit.
Isostructural with:
Arsenuranospathite
The P analogue of arsenuranospathite. An uncommon secondary mineral occurring in the oxidized zones of uranium-bearing hydrothermal deposits.
Easily loses 10-12 H2O converting to sabugalite (Walenta, 1978).

Crystal structure details:

- corner-sharing UO6 square bipyramids
- PO4 tetrahedra
- the above form autunite-type [(UO2)(PO4)] sheet
- Al(H2O)6 octahedra are in the interlayer space
- 8 isolated water molecules in the interlayer
- hydrogen bonds link together the water molecules, Al octahedra and UAs-bearing sheets, forming a very complex bonding net
- F is supposed to replace some of the water molecules in the Al-bearing octahedra.


Classification of UranospathiteHide

IMA status:
Approved, 'Grandfathered' (first described prior to 1959)
Strunz 8th ed.:
7/E.04-10
Nickel-Strunz 10th (pending) ed.:
8.EB.25

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
Dana 8th ed.:
40.2a.22.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
Hey's CIM Ref.:
19.11.32

19 : Phosphates
11 : Phosphates of U

Physical Properties of UranospathiteHide

Transparency:
Translucent
Colour:
Yellow, light yellow-green, pale green
Hardness:
2 - 2½ on Mohs scale
Cleavage:
Perfect
On {001}, perfect; on {100} and {010}, good.
Density:
2.5 g/cm3 (Measured)    2.49 g/cm3 (Calculated)

Optical Data of UranospathiteHide

Type:
Biaxial (-)
RI values:
nα = 1.492 nβ = 1.510 nγ = 1.521
2V:
Measured: 69° , Calculated: 70°
Max Birefringence:
δ = 0.029
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v strong
Pleochroism:
Visible
Comments:
X = Pale yellow
Y = Z = Deep yellow
Comments:
anomalous

Chemical Properties of UranospathiteHide

Formula:
(Al,◻)(UO2)2(PO4)2F · 20(H2O,F)
IMA Formula:
(Al,◻)(UO2)2F(PO4)2 · 20H2O
Elements listed:
Al, F, H, O, P, U - search for minerals with similar chemistry

Crystallography of UranospathiteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pnn2
Cell Parameters:
a = 30.020(4) Å, b = 7.0084(9) Å, c = 7.0492(9) Å
Ratio:
a:b:c = 4.283 : 1 : 1.006
Unit Cell V:
1483.1 ų
Z:
2
Morphology:
Crystals platy, rectangular, flattened on {001}, striated parallel to the elongation [010], and exhibiting {100} and {010}, in fanlike groups.
Twinning:
On {110}, forming cruciform groupings.
Comment:
Pseudotetragonal (P42/n, a = 7.00, c = 30.02 A)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006021UranospathiteLocock A J, Kinman W S, Burns P C (2005) The structure and composition of uranospathite, Al1-xVacancyx[(UO2)(PO4)]2(H2O)20+3xF1-3x, x = 0 - 0.33, a non-centrosymmetric fluorine-bearing mineral of the autunite group, and of a related synthetic lower hydrate, Al0.67Vacancy0.33[(UO2)(PO4)]2(H2O)15.5 The Canadian Mineralogist 43 989-10032005Venachat, Haute-Vienne, France0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
15.22 Å(100)
7.60 Å(100)
4.93 Å(100)
3.50 Å(80)
4.48 Å(60)
2.21 Å(60)
4.08 Å(40)
Comments:
Basset mines material

Type Occurrence of UranospathiteHide

Type Locality:
ⓘ Wheal Basset, Basset Mines, Carnkie, Carn Brea, Cornwall, England, UK
Place of Conservation of Type Material:
Museum of Practical Geology, Ludlam collection: #L1941, now in The Natural History Museum, London, England.

Other Language Names for UranospathiteHide

Common AssociatesHide

BassetiteFe2+(UO2)2(PO4)2 · 10H2O

Related Minerals - Nickel-Strunz GroupingHide

8.EB.05AutuniteCa(UO2)2(PO4)2 · 10-12H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.EB.05HeinrichiteBa(UO2)2(AsO4)2 · 10H2OMon. 2/m
8.EB.05KahleriteFe(UO2)2(AsO4)2 · 12H2OTet. 4/m : P42/n
8.EB.05Nováčekite-IMg(UO2)2(AsO4)2 · 12H2OTric. 1 : P1
8.EB.05SaléeiteMg(UO2)2(PO4)2 · 10H2OMon. 2/m
8.EB.05TorberniteCu(UO2)2(PO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.EB.05UranocirciteBa(UO2)2(PO4)2 · 10H2OTet.
8.EB.05UranospiniteCa(UO2)(AsO4)2 · 10H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.05Xiangjiangite(Fe3+,Al)(UO2)4(PO4)2(SO4)2(OH) · 22H2OTet.
8.EB.05ZeuneriteCu(UO2)2(AsO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.EB.05MetarauchiteNi(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.05RauchiteNi(UO2)2(AsO4)2 · 10H2OTric. 1 : P1
8.EB.10BassetiteFe2+(UO2)2(PO4)2 · 10H2OMon. 2/m
8.EB.10LehneriteMn2+(UO2)2(PO4)2 · 8H2OMon.
8.EB.10Meta-autuniteCa(UO2)2(PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m)
8.EB.10MetasaléeiteMg(UO2)2(PO4)2 · 8H2O
8.EB.10Metauranocircite-IBa(UO2)2(PO4)2 · 7H2OMon. 2 : P21
8.EB.10MetauranospiniteCa(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
8.EB.10MetaheinrichiteBa(UO2)2(AsO4)2 · 8H2OTet. 4mm
8.EB.10MetakahleriteFe2+(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.10MetakirchheimeriteCo(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.10MetanováčekiteMg(UO2)2(AsO4)2 · 8H2OTet. 4/m : P4/n
8.EB.10MetatorberniteCu(UO2)2(PO4)2 · 8H2OTet. 4/m : P4/n
8.EB.10MetazeuneriteCu(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
8.EB.10PrzhevalskitePb2(UO2)3(PO4)2(OH)4 · 3H2OOrth.
8.EB.10Meta-lodèviteZn(UO2)2(AsO4)2 · 10H2O
8.EB.15AbernathyiteK(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
8.EB.15Chernikovite(H3O)2(UO2)2(PO4)2 · 6H2OTet.
8.EB.15Meta-ankoleiteK2(UO2)2(PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15NatrouranospiniteNa2(UO2)2(AsO4)2 · 5H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15Trögerite(H3O)(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15Uramphite(NH4)2(UO2)2(PO4)2 · 6H2OTet.
8.EB.15Uramarsite(NH4)(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
8.EB.20ThreadgolditeAl(UO2)2(PO4)2(OH) · 8H2OMon.
8.EB.20ChistyakovaiteAl(UO2)2(AsO4)2(F,OH) · 6.5H2OMon.
8.EB.25ArsenuranospathiteAl(UO2)2(AsO4)2F · 20H2OOrth. mm2 : Pnn2
8.EB.30Vochtenite(Fe2+,Mg)Fe3+(UO2)4(PO4)4(OH) · 12-13H2OMon.
8.EB.35CoconinoiteFe3+2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2OMon.
8.EB.40RanunculiteHAl(UO2)(PO4)(OH)3 · 4H2OMon.
8.EB.45TrianguliteAl3(UO2)4(PO4)4(OH)5 · 5H2OTric.
8.EB.50FurongiteAl13(UO2)7(PO4)13(OH)14 · 58H2OTric. 1 : P1
8.EB.55SabugaliteHAl(UO2)4(PO4)4 · 16H2OMon. 2/m : B2/m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

19.11.1LermontoviteU(PO4)(OH) · H2OOrth. mmm (2/m 2/m 2/m) : Ccca
19.11.2MetavanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 2H2OOrth. mmm (2/m 2/m 2/m) : Fddd
19.11.3VanmeersscheiteU6+(UO2)3(PO4)2(OH)6 · 4H2OOrth.
19.11.4Chernikovite(H3O)2(UO2)2(PO4)2 · 6H2OTet.
19.11.5VyacheslaviteU(PO4)(OH)Orth. mmm (2/m 2/m 2/m) : Cmca
19.11.6MetanatroautuniteNa(UO2)(PO4)(H2O)3Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
19.11.7YingjiangiteK2Ca(UO2)7(PO4)4(OH)6 · 6H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
19.11.8Meta-ankoleiteK2(UO2)2(PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
19.11.9Uramphite(NH4)2(UO2)2(PO4)2 · 6H2OTet.
19.11.10TorberniteCu(UO2)2(PO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
19.11.11MetatorberniteCu(UO2)2(PO4)2 · 8H2OTet. 4/m : P4/n
19.11.12SaléeiteMg(UO2)2(PO4)2 · 10H2OMon. 2/m
19.11.13Ningyoite(U,Ca,Ce)2(PO4)2 · 1-2H2OOrth.
19.11.14Meta-autuniteCa(UO2)2(PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m)
19.11.15AutuniteCa(UO2)2(PO4)2 · 10-12H2OOrth. mmm (2/m 2/m 2/m) : Pnma
19.11.16Pseudo-autunite(H3O)4Ca2(UO2)2(PO4)4 · 5H2OOrth.
19.11.17PhurcaliteCa2(UO2)3(PO4)2O2 · 7H2OOrth.
19.11.18PhosphuranyliteKCa(H3O)3(UO2)7(PO4)4O4 · 8H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
19.11.19UlrichiteCaCu(UO2)(PO4)2 · 4H2OMon.
19.11.20BergeniteCa2Ba4(UO2)9(PO4)6O6 · 16H2OMon. 2/m : P21/b
19.11.21Metauranocircite-IBa(UO2)2(PO4)2 · 7H2OMon. 2 : P21
19.11.22UranocirciteBa(UO2)2(PO4)2 · 10H2OTet.
19.11.23RanunculiteHAl(UO2)(PO4)(OH)3 · 4H2OMon.
19.11.24TrianguliteAl3(UO2)4(PO4)4(OH)5 · 5H2OTric.
19.11.25MunditeAl(UO2)3(PO4)2(OH)3 · 5.5H2OOrth.
19.11.26UpaliteAl(UO2)3(PO4)2O(OH) · 7H2OMon.
19.11.27FurongiteAl13(UO2)7(PO4)13(OH)14 · 58H2OTric. 1 : P1
19.11.28ThreadgolditeAl(UO2)2(PO4)2(OH) · 8H2OMon.
19.11.29PhuralumiteAl2[(UO2)3(PO4)2O(OH)](OH)3(H2O)9Mon. 2/m
19.11.30MoreauiteAl3(UO2)(PO4)3(OH)2 · 13H2OMon. 2/m : P21/b
19.11.31SabugaliteHAl(UO2)4(PO4)4 · 16H2OMon. 2/m : B2/m
19.11.33AlthupiteAlTh(UO2)7(PO4)4(OH)5O2 · 15H2OTric. 1 : P1
19.11.34Françoisite-(Nd)(Nd,Ce,Sm)(UO2)3(PO4)2O(OH) · 6H2OMon.
19.11.35KivuiteTh(UO2)4(PO3OH)2(OH)8 · 7H2O
19.11.36ParsonsitePb2(UO2)(PO4)2Tric. 1 : P1
19.11.37DewindtiteH2Pb3(UO2)2(PO4)4O4 · 12H2OOrth. mmm (2/m 2/m 2/m) : Cmma
19.11.38DumontitePb2(UO2)3O2(PO4)2 · 5H2OMon. 2/m : P21/m
19.11.39PrzhevalskitePb2(UO2)3(PO4)2(OH)4 · 3H2OOrth.
19.11.40LehneriteMn2+(UO2)2(PO4)2 · 8H2OMon.
19.11.41BassetiteFe2+(UO2)2(PO4)2 · 10H2OMon. 2/m
19.11.42Vochtenite(Fe2+,Mg)Fe3+(UO2)4(PO4)4(OH) · 12-13H2OMon.

Other InformationHide

IR Spectrum:
Yellowish green (UV).
Notes:
Radioactive. Readily dehydrates to Sabugalite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for UranospathiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Hallimond (1915) Mineralogical Magazine: 17: 221-230.
Palache, C., Berman, H., & Frondel, C. (1951) The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 990.
Walenta, K. (1978) Uranospathite and arsenuranospathite. Mineralogical Magazine, 42, 117–128.
American Mineralogist (1979) 64: 465.
Locock, A.J., Kinman, W.S. & Burns, P.C. (2005) The structure and composition of uranospathite, Al1–x◻x[(UO2)(PO4)]2(H2O)20+3xF1–3x, 0 < x < 0.33, a non-centrosymmetric fluorine-bearing mineral of the autunite group, and of a related synthetic lower hydrate, Al0.67◻0.33[(UO2)(PO4)]2(H2O)15. Canadian Mineralogist 43: 989-1003.
Anthony, J.W., Bideaux, R.A., Bladh, K.W. and Nichols, M.C., Eds. Handbook of Mineralogy, Mineralogical Society of America, Chantilly, VA 20151-1110, USA. http://www.handbookofmineralogy.org/ (2016)
Theye, T., Walenta, K., Markl, G. (2016): The chemical composition of uranospathite, arsenuranospathite, and associated minerals revisited: the peculiarity of fluorine incorporation in autunite group minerals. Neues Jahrbuch für Mineralogie - Abhandlungen: Journal of Mineralogy and Geochemistry 193, 59-68.

Internet Links for UranospathiteHide

Localities for UranospathiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • South Australia
    • Olary Province
      • Radium Hill area
China
 
  • Jiangxi
    • Jiujiang
      • Xiushui Co.
        • Xiushui Uranium ore field
Dahlkamp, F.J., Ed. (2009): Uranium Deposits of the World. Springer (Berlin, Heidelberg), pp. 31-156
Dahlkamp, F.J., Ed. (2009): Uranium Deposits of the World. Springer (Berlin, Heidelberg), pp. 31-156
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
Lapis 2002(7/8), 63-65
Pauliš P., Kopecký S., Černý P. 2007: Uranové minerály České Republiky a jejich naleziště. 1. část. (Kutna Hora, issue 1)
Ecuador
 
  • Loja Province
Manrique, J., Guaman, G., & Guartan, J. (2018). Geochemical Prospecting Study of the Vanadium-Uranium Mineralization of Puyango, Ecuador (No. IAEA-CN--261).
France
 
  • Nouvelle-Aquitaine
    • Corrèze
      • Ussel
        • Davignac
Patrice Queneau Collection
    • Creuse
      • Guéret
        • Guéret
    • Haute-Vienne
      • Bellac
        • Compreignac
Le Règne Minéral, Hors Série IV, 1998
        • Razès
Le Règne Minéral, Hors Série IV, 1998
      • Limoges
        • Saint-Sylvestre
Le Règne Minéral, Hors Série IV, 1998
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Waldshut
        • St Blasien
          • Menzenschwand
Walenta: "Die Mineralien des Schwarzwaldes", Weise (Munich), 1992
  • Saxony
    • Erzgebirgskreis
      • Annaberg-Buchholz
        • Kleinrückerswalde
Möhn, G., Stolze, S. & Desor, J. (11/2020) SEM-EDS confirmed
      • Schneeberg
        • Neustädtel
          • Weißer Hirsch Mine (shaft 3)
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 967.
Italy
 
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Montescheno
Rivista Mineralogica Italiana, 23 (1), 42-49
North Macedonia
 
  • Probistip Municipality
    • Kratovo-Zletovo ore district
Radusinovic, D. (1974). Zletovska Reka uranium deposit. In IAEA Symposium on the formation of uranium ore deposits. Athens, Greece (pp. 593-601).
Romania
 
  • Suceava
    • Suceava district
Hîrtopanu P., Udubaşa G., Scott P., Hârtopanu I. (2004) Uranium sulphide mineralisation in the Bistriţa Mts., East Carpathians, Romania. Romanian Journal of Mineral Deposits 81:108-111
South Africa
 
  • Western Cape
    • Central Karoo District Municipality
      • Beaufort West
Cairncross, B., Dixon, R. (1995) Cairncross, B., Dixon, R. (1995) Minerals of South Africa. Geological Society of South Africa, PO Box 44283, Linden 2104, South Africa.
Spain
 
  • Extremadura
    • Badajoz
Grupo Mineralogista de Madrid(1994) Don Benito, uranio en la pizarra. Bocamina, Vol.0, p 39. (in Spanish)
      • La Haba
https://www.foro-minerales.com/forum/viewtopic.php?p=141369#141369
https://www.foro-minerales.com/forum/viewtopic.php?p=141369#141369
    • Cáceres
      • Tejeda de Tiétar
http://www.foro-minerales.com/forum/viewtopic.php?t=6707
Switzerland
 
  • Valais
    • Saint-Maurice
      • Salvan
        • Les Marécottes
          • La Creusaz
- Meisser, N. (2012): La minéralogie de l'uranium dans le massif des Aiguilles Rouges. Matér. Géol. Suisse, Sér. géotech. 96, 183 p.
UK (TL)
 
  • England
    • Cornwall
      • Carn Brea
        • Carnkie
          • Basset Mines
[Embrey & Symes, 1987, 45 - "Minerals of Cornwall and Devon"]
USA
 
  • Utah
    • San Juan Co.
      • Paradox Valley
        • Paradox Valley Mining District
UGMS Bull 117 Minerals and Mineral Localities of Utah
      • Red Canyon
Travis Olds collection; Kampf, A.R., Plášil, J., Kasatkin, A.V., Marty, J., and Čejka, J. (2018) Markeyite, a new calcium uranyl carbonate mineral from the Markey mine, San Juan County, Utah, USA. Mineralogical Magazine, 82, 1089-1100.
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矿物 and/or 产地  
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