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Toyohaite

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About ToyohaiteHide

Formula:
Ag1+(Fe2+0.5Sn4+1.5)S4
Colour:
Gray-brown
Lustre:
Metallic
Hardness:
4
Crystal System:
Tetragonal
Name:
Named after its discovery locality, Toyoha Mine, Sapporo, Hokkaido, Japan.
Isostructural with:
The Ag analogue of rhodostannite.


Classification of ToyohaiteHide

Approved
Notes:
Redefined by the IMA
Approval Year:
1989
Approval History:
Redefined by IMA as Ag1+(Fe2+0.5Sn4+1.5)S4 Bosi et al. 2018)
2/C.06-160
2.DA.10

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4
2.10.3.2

2 : SULFIDES
10 : AmBnXp, with (m+n):p = 3:4

Physical Properties of ToyohaiteHide

Metallic
Transparency:
Opaque
Colour:
Gray-brown
Hardness:

Chemical Properties of ToyohaiteHide

Formula:
Ag1+(Fe2+0.5Sn4+1.5)S4
Common Impurities:
Cu,Zn,Cd

Crystallography of ToyohaiteHide

Crystal System:
Tetragonal

Type Occurrence of ToyohaiteHide

Place of Conservation of Type Material:
Geology Museum (Geological Survey of Japan)

Synonyms of ToyohaiteHide

Other Language Names for ToyohaiteHide

Relationship of Toyohaite to other SpeciesHide

Other Members of this group:
CarrolliteCu(Co,Ni)2S4Iso. m3m (4/m 3 2/m) : Fd3m
Cuproiridsite(Cu,Fe)Ir2S4Iso. m3m (4/m 3 2/m) : Fd3m
CuprokalininiteCuCr2S4Iso. m3m (4/m 3 2/m) : Fd3m
FletcheriteCu(Ni,Co)2S4Iso. m3m (4/m 3 2/m) : Fd3m
Florensovite(Cu,Zn)Cr1.5Sb0.5S4
MalaniteCu1+(Ir3+Pt4+)S4Iso.
RhodostanniteCu1+(Fe2+0.5Sn4+1.5)S4Tet. 4/m : I41/a

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Toyohaite associated with FranckeiteFe2+(Pb,Sn2+)6Sn4+2Sb2S14
2 photos of Toyohaite associated with PirquitasiteAg2ZnSnS4
2 photos of Toyohaite associated with Hocartite-Pirquitasite Series
1 photo of Toyohaite associated with SphaleriteZnS

Related Minerals - Nickel-Strunz GroupingHide

2.DA.05BornhardtiteCo2+Co3+2Se4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05CarrolliteCu(Co,Ni)2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05Cuproiridsite(Cu,Fe)Ir2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05Cuprorhodsite(Cu1+0.5Fe3+0.5)Rh3+2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05DaubréeliteFe2+Cr3+2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05FletcheriteCu(Ni,Co)2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05Florensovite(Cu,Zn)Cr1.5Sb0.5S4
2.DA.05GreigiteFe2+Fe3+2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05InditeFeIn2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05KalininiteZnCr2S4
2.DA.05LinnaeiteCo2+Co3+2S4Iso.
2.DA.05MalaniteCu1+(Ir3+Pt4+)S4Iso.
2.DA.05PolydymiteNi2+Ni3+2S4Iso.
2.DA.05SiegeniteCoNi2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05TrüstedtiteNi3Se4Iso.
2.DA.05TyrrelliteCu(Co3+,Ni3+)2Se4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05ViolariteFe2+Ni3+2S4Iso.
2.DA.05XingzhongitePb2+Ir3+2S4Iso.
2.DA.05Ferrorhodsite(Fe,Cu)(Rh,Ir,Pt)2S4Iso.
2.DA.05CadmoinditeCdIn2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.05CuprokalininiteCuCr2S4Iso. m3m (4/m 3 2/m) : Fd3m
2.DA.10RhodostanniteCu1+(Fe2+0.5Sn4+1.5)S4Tet. 4/m : I41/a
2.DA.15BrezinaiteCr3S4Mon. 2/m
2.DA.15Heideite(Fe,Cr)1.15(Ti,Fe)2S4Mon. 2/m
2.DA.20InaglyiteCu3Pb(Ir,Pt)8S16Hex.
2.DA.20KonderiteCu3Pb(Rh,Pt,Ir)8S16Hex. 6/m : P6/m
2.DA.25Kingstonite(Rh,Ir,Pt)3S4Mon. 2/m : B2/m

Related Minerals - Dana Grouping (8th Ed.)Hide

2.10.3.1RhodostanniteCu1+(Fe2+0.5Sn4+1.5)S4Tet. 4/m : I41/a

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for ToyohaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Mineralogical Journal, Japan (1991): 15(5): 222-232.
American Mineralogist (1992): 77: 1117.
New Minerals (1997), New Minerals 1990-1994.
Bosi, F., Biagioni, C. & Pasero, M.(2019) Nomenclature and classification of the spinel supergroup. European Journal of Mineralogy. 31:183-192

Internet Links for ToyohaiteHide

Localities for ToyohaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Jujuy Province
    • Rinconada Department
Milka K. de Brodtkorb (2002) Las Especies Minerales de la Republica Argentina. Vol. 1 (elements, sulphides and sulphosalts). (Asociacion Mineralogica Argentina)
Brodtkorb, "Las Especies Minerales de la Republica Argentina" (2002); DE BRODTKORB, Milka K. Precious metaltellurides and other Te-bearing minerals in different paragenesis of Argentina: A review. Rev. Asoc. Geol. Argent. [online]. 2009, vol.64, n.3, pp. 365-372.
Rob Lavinsky specimen; Amer.Min.(2000) 85, 1066-1075
Japan (TL)
 
  • Hokkaidō
    • Sapporo
      • Minami-ku
Min. Jour. (Japan): 15:222-232.; Eijun Ohta (1991) Polymetallic Mineralization at the Toyoha Mine, Hokkaido, Japan. Mining Geology 41:279-295
 
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