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Tongbaite

A valid IMA mineral species
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Formula:
Cr3C2
Colour:
Brownish yellow
Lustre:
Metallic
Hardness:
Specific Gravity:
6.64 (Calculated)
Crystal System:
Orthorhombic
Name:
Named after its discovery locality, Liu village, Tongbai, Henan Province, China.
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Unique IdentifiersHide

Mindat ID:
3994
Long-form identifier:
mindat:1:1:3994:5
GUID
(UUID V4):
bae3de71-9fde-4f9e-865a-4a5080f30635

Classification of TongbaiteHide

Approved
Approval year:
1982
First published:
1983
1.BA.15

1 : ELEMENTS (Metals and intermetallic alloys; metalloids and nonmetals; carbides, silicides, nitrides, phosphides)
B : Metallic Carbides, Silicides, Nitrides, Phosphides and Hydrides
A : Carbides
Dana 7th ed.:
1.1.26.1
1.1.17.1

1 : NATIVE ELEMENTS AND ALLOYS
1 : Metals, other than the Platinum Group
2.4

2 : Carbides, Nitrides, Silicides and Phosphides

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
TgbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TongbaiteHide

Metallic
Transparency:
Opaque
Colour:
Brownish yellow
Streak:
Dark gray
Hardness:
8½ on Mohs scale
Hardness:
VHN100=1885 kg/mm2 - Vickers
Tenacity:
Brittle
Density:
6.64 g/cm3 (Calculated)

Optical Data of TongbaiteHide

Type:
Biaxial
Anisotropism:
Strong; purplish yellow to yellow-orange.
Bireflectance:
Distinct
Reflectivity:
WavelengthR1R2
405nm46.54%49.10%
436nm48.50%51.28%
480nm51.14%53.86%
526nm53.72%55.94%
546nm54.68%56.89%
578nm57.07%57.51%
589nm57.38%57.82%
622nm58.72%57.68%
644nm60.33%59.02%
656nm61.50%59.97%
664nm61.56%59.97%
700nm61.35%59.20%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 61.56%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Pale violet
Pleochroism:
Visible

Chemical Properties of TongbaiteHide

Formula:
Cr3C2

Crystallography of TongbaiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 5.57(5) Å, b = 11.47(8) Å, c = 2.816(8) Å
Ratio:
a:b:c = 0.486 : 1 : 0.246
Unit Cell V:
179.91 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0011913TongbaiteRundqvist S, Runnsjo G (1969) Crystal structure refinement of Cr3C2 Acta Chemica Scandinavica 23 1191-11991969synthetic0293
0011914TongbaiteRundqvist S, Runnsjo G (1969) Crystal structure refinement of Cr3C2 Acta Chemica Scandinavica 23 1191-11991969synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.30 Å(100)
2.23 Å(80)
1.193 Å(70)
1.70 Å(40)
1.164 Å(40)
1.94 Å(30)
1.86 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks

Type Occurrence of TongbaiteHide

General Appearance of Type Material:
Prismatic, pseudohexagonal crystals, to 0.3 mm.
Place of Conservation of Type Material:
National Museum for Geology, Beijing, China, M09332 (type).
Geological Setting of Type Material:
Ultramafic rocks
Associated Minerals at Type Locality:
Reference:
Tian Peixue, Fang Qingsong, Chen Keqiao, and Peng Zhizhong (1983): A study on tongbaite - A new mineral. Acta Mineralogica Sinica 3(4), 241-245

Synonyms of TongbaiteHide

Other Language Names for TongbaiteHide

German:Tongbait
Simplified Chinese:桐柏矿
Spanish:Tongbaita

Related Minerals - Strunz-mindat GroupingHide

1.BA.05CoheniteFe3COrth. mmm (2/m 2/m 2/m)
1.BA.10Haxonite(Fe,Ni)23C6Iso. m3m (4/m 3 2/m) : Fm3m
1.BA.10Isovite(Cr,Fe)23C6Iso. m3m (4/m 3 2/m) : Fm3m
1.BA.20Khamrabaevite(Ti,V,Fe)CIso. m3m (4/m 3 2/m) : Fm3m
1.BA.20Niobocarbide(Nb,Ta)CIso. m3m (4/m 3 2/m) : Fm3m
1.BA.20TantalcarbideTaCIso. m3m (4/m 3 2/m) : Fm3m
1.BA.25QusongiteWCHex. 6 m2 : P6m2
1.BA.30YarlongiteCr4Fe4NiC4Hex. 6mm : P63mc
1.BA.35EdscottiteFe5C2Mon. 2/m : B2/b

Other InformationHide

Magnetism:
Non-Magnetic
Notes:
Not soluble in HCl, H2SO4 or HNO3. It is weakly attacked by aqua regia.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for TongbaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Rundqvist, S., Runnsjö, G. (1969) Crystal structure refinement of Cr3C2. Acta Chemica Scandinavica: 23: 1191-1199.
Peixue, Tian; Qingsong, Fang; Keqiao, Chen; Zhizhong, Peng (1983) A study on tongbaite - a new mineral. Acta Mineralogica Sinica: 3: 241-245. (in Chinese with English abstract)
Dunn, P.J., Chao, G.Y., Fleischer, M., Ferraiolo, J.A., Langley, R.H., Pabst, A., Zilczer, J.A. (1985) New mineral names. American Mineralogist, 70, 214-221 (218).
Chen Keqiao, Tian Peixue, Shi Nicheng, and Peng Zhizhong (1983): A study on tongbaite, Cr3C2 - A new mineral. Ziran Zazhi: 6: 478-479.
Dai, Ming-quan; Shi, Ni-cheng; Ma, Zhe-sheng; Xiong, Ming; Bai, Wen-ji; Fang, Qing-song; Yan, Bing-gang; Yang, Jing-sui (2004): Crystal structure determination of tongbaite. Acta Mineralogica Sinica: 24(1): 1-6. (in Chinese with English abstract)

Internet Links for TongbaiteHide

Localities for TongbaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China (TL)
 
  • Henan
    • Nanyang
      • Tongbai County
Tian Peixue, Fang Qingsong, Chen Keqiao, and Peng Zhizhong (1983): Acta Mineralogica Sinica 3(4), 241-245.
http://www.encyclopedia.com/doc/1G1-130213802.html
Russia
 
  • Sverdlovsk Oblast
    • Nizhnyaya Tura
Generalov M.E., Naumov V.A., Mokhov A.V., Trubkin N.V. (1998) Isovite (Cr,Fe)23C6 - a new mineral from the gold-platinum -bearing placiers of the Urals, - Zapiski VMO, 127(5), pp. 26-37 (in Russian).
 
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