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Ferri-fluoro-leakeite

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About Ferri-fluoro-leakeiteHide

07424110014947736946756.jpg
Bernard Elgey Leake
Formula:
{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2
The Leakeite group minerals are sodium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu,
C(Al+Fe3++2Ti) > 1.5 apfu and
CLi > 0,5 apfu

Ferri-fluoro-leakeite is defined with
A position: Na dominant
C2+ position: Mg dominant
C3+ position: Fe dominant
W position: F dominant
Colour:
Black; mustard yellow to brownish yellow
Crystal System:
Monoclinic
Name:
Named in 1992 by Frank Christopher Hawthorne, Roberta Oberti, Luciano Ungaretti, and Joel Dennison Grice in honor of Scottish geologist Bernard Elgey Leake [1932-], University of Glasgow and who was chairman of the IMA subcommitte to revise amphibole nomenclature. The chenical suffix designates the chemical relationship in the series.
The mineral originally described as fluoroleakeite by Cámara et.al (2010) are now named ferri-fluoro-leakeite as the leakeite group was redefined in the 2012 amphibole nomenclature.

The name fluoro-leakeite is now used for the Na, Mg, Al and F dominant member of the group, which was originally named fluoro-aluminoleakeite by Roberti et.al(2009).


Classification of Ferri-fluoro-leakeiteHide

Approved
Approval Year:
2009
9.DE.05

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
66.4.16.3

66 : INOSILICATES Double-Width,Unbranched Chains,(W=2)
4 : Amphiboles - Na subgroup

Physical Properties of Ferri-fluoro-leakeiteHide

Colour:
Black; mustard yellow to brownish yellow
Streak:
Very pale grey to colourless

Chemical Properties of Ferri-fluoro-leakeiteHide

Formula:
{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2

The Leakeite group minerals are sodium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu,
C(Al+Fe3++2Ti) > 1.5 apfu and
CLi > 0,5 apfu

Ferri-fluoro-leakeite is defined with
A position: Na dominant
C2+ position: Mg dominant
C3+ position: Fe dominant
W position: F dominant
IMA Formula:
NaNa2(Mg2Fe3+2Li)Si8O22F2
Idealised Formula:
ANaBNa2<sup> C(Mg2Fe3+ 2 Li)TSi8O22WF2

Crystallography of Ferri-fluoro-leakeiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 9.8297(3) Å, b = 17.9257(6) Å, c = 5.2969(2) Å
β = 103.990(1)°
Ratio:
a:b:c = 0.548 : 1 : 0.295
Unit Cell V:
905.65 ų (Calculated from Unit Cell)
Morphology:
Elongated striated crystals.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.434 Å(40)
4.464 Å(30)
3.405 Å(30)
3.137 Å(20)
2.718 Å(100)
2.541 Å(20)
2.325 Å(15)
2.166 Å(20)

Type Occurrence of Ferri-fluoro-leakeiteHide

Synonyms of Ferri-fluoro-leakeiteHide

Relationship of Ferri-fluoro-leakeite to other SpeciesHide

Other Members of this group:
Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
Ferro-fluoro-leakeiteNaNa2(Fe2+2Al2Li)(Si8O22)F2
Ferro-leakeiteNaNa2(Fe2+2Al2Li)(Si8O22)(OH)2
Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
LeakeiteNaNa2(Mg2Al2Li)(Si8O22)(OH)2
Oxo-mangani-leakeiteNaNa2(Mn3+4Li)Si8O22O2Mon. 2/m : B2/m
Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
Potassic-leakeiteKNa2(Mg2Al2Li)(Si8O22)(OH)2
Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Ferri-fluoro-leakeite associated with AegirineNaFe3+Si2O6
2 photos of Ferri-fluoro-leakeite associated with CatapleiiteNa2Zr(Si3O9) · 2H2O

Related Minerals - Nickel-Strunz GroupingHide

9.DE.Clino-suenoite□{Mn2+2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Cummingtonite☐{Mg2}{Mg5}(Si8O22)(OH)2Mon.
9.DE.05Clino-holmquistite Root Name☐{Li2}{Z2+3Z3+2}(Si8O22)(OH,F,Cl)2Mon.
9.DE.05Grunerite☐{Fe2+2}{Fe2+5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Permanganogrunerite☐{Mn2+2}{Mn2+5}(Si8O22)(OH)2Mon.
9.DE.10Actinolite☐{Ca2}{Mg4.5-2.5Fe0.5-2.5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe3+2}(Al2Si6O22)(OH)2Mon.
9.DE.10Ferro-actinolite☐{Ca2}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.10Ferro-hornblende☐{Ca2}{Fe2+4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Ferro-tschermakite☐{Ca2}{Fe2+3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10Joesmithite{Pb}{Ca2}{Mg3Fe3+2}(Be2Si6O22)(OH)2Mon.
9.DE.10Magnesio-hornblende☐{Ca2}{Mg4Al}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tschermakite☐(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2Mon.
9.DE.10Fluoro-cannilloite{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2Mon.
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Fluoro-tremolite☐{Ca2}{Mg5}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Ferro-ferri-hornblende☐Ca2(Fe2+4Fe3+)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Edenite{Na}{Ca2}{Mg5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-edenite{Na}{Ca2}{Fe2+5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe2+3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Ferro-pargasite{Na}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Kaersutite{Na}{Ca2}{Mg3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Si5Al3O22)(OH)2Mon.
9.DE.15Fluoro-edenite{Na}{Ca2}{Mg5}(AlSi7O22)(F,OH)2Mon. 2/m : P2/m
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe2+3Fe3+2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe2+3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Magnesio-fluoro-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Fluoro-pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe2+5}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsite{K}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-pargasite{K}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Ferri-kaersutiteNaCa2(Mg3Fe3+Ti)(Al2Si6O22)O2Mon. 2/m : B2/m
9.DE.15Vanadio-pargasiteNaCa2(Mg3+4V)(Al2Si6)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-taramiteNa(CaNa)(Fe2+3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
9.DE.20Ferro-ferri-barroisite☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe2+4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe2+3Fe3+2)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-richterite{Na}{CaNa}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.20Ferro-winchite ☐{CaNa}{Fe2+4Al}(Si8O22)(OH)2Mon.
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe2+4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Ferri-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)(OH)2Mon.
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
9.DE.20Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.20Winchite☐{CaNa}{Mg4Al}(Si8O22)(OH)2Mon. 2/m
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon. 2/m
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon.
9.DE.20Potassic-richterite{K}{CaNa}{Mg5}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferri-ghoseite☐[Mn2+Na][Mg4Fe3+]Si8O22(OH)2Mon. 2/m
9.DE.20Ferri-winchite☐[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.20Fluoro-katophoriteNa(CaNa)(Mg4Al)(AlSi7O22)F2Mon.
9.DE.20Ferri-fluoro-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)F2Mon. 2/m : B2/m
9.DE.25Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-eckermanniteNaNa2(Fe2+4Al)Si8O22(OH)2Mon.
9.DE.25Ferro-glaucophane◻[Na2][Fe2+3Al2]Si8O22(OH)2Mon.
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2Mon.
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.
9.DE.25Mangano-ferri-eckermannite{Na}{Na2}{Mn2+4Fe3+}Si8O22(OH)2Mon.
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Riebeckite◻[Na2][Fe2+3Fe3+2]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn2+2Mn3+3)(Si8O22)O2Mon.
9.DE.25Ferro-ferri-nybøiteNaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Clino-ferro-ferri-holmquistite◻{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2Mon.
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
9.DE.25Mangani-dellaventuraite{Na}{Na2}{MgMn3+2LiTi4+}Si8O22O2Mon. 2/m : B2/m
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangani-obertiiteNa(Na2)(Mg3Mn3+Ti)(Si8O22)O2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]Mon. 2/m : B2/m
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe2+3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m
9.DE.25Ferri-obertiiteNa(Na2)(Mg3Fe3+Ti)(Si8O22)O2Mon. 2/m : B2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferri-fluoro-leakeiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Cámara, F., Hawthorne, F.C., Ball, N.A., Bekenova, G., Stepanov, A.V., Kotel’nikov, P.E. (2010) Fluoroleakeite, NaNa2(Mg2Fe3+2Li)Si8O22F2, a new mineral of the amphibole group from the Verkhnee Espe deposit, Akjailyautas Mountains, Eastern Kazakhstan District, Kazakhstan: description and crystal structure. Mineralogical Magazine: 74: 521-528.
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.
Oberti, R., Boiocchi, M., Hawthorne, F.C., Kristiansen, R. (2014) Ferri-fluoro-leakeite: a second occurrence at Bratthagen (Norway), with new data on Zn partitioning and the oxo component in Na amphiboles. Mineralogical Magazine: 78: 861-869.

Internet Links for Ferri-fluoro-leakeiteHide

Localities for Ferri-fluoro-leakeiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Catamarca Province
    • Belén Department
Fernando Colombo, Raúl Lirai,María Sol O´Leary y Colombo C. G. Tassinari (2010): Los diques comendíticos de Papachacra (Catamarca): magmatismo peralcalino en sierras Pampeanas orientales. Rev. Asoc. Geol. Argent. 66 (1-2). Buenos Aires ene./mar. 2010.
Kazakhstan (TL)
 
  • East Kazakhstan
    • Tarbagatai Range
      • Akzhaylyautas Mts (Akzhailyautas Mts; Akjaylautas Mts; Akzhalautas Mts)
Cámara, F., Hawthorne, F.C., Ball, N.A., Bekenova, G., Stepanov, A.V., Kotel’nikov, P.E. (2010): Fluoroleakeite, NaNa2(Mg2Fe3+2Li)Si8O22F2, a new mineral of the amphibole group from the Verkhnee Espe deposit, Akjailyautas Mountains, Eastern Kazakhstan District, Kazakhstan: description and crystal structure. Mineralogical Magazine, 74, 521-528.
Norway
 
  • Vestfold
    • Larvik
      • Hedrum
        • Lågendalen
Kristiansen, R. (2013): Surkhobitt fra Bratthagen i Lågendalen. Norsk Bergverksmuseum Skrifter. 50, 89-92;Oberti, R., Boiocchi, M., Hawthorne, F.C., Kristiansen, R. (2014): Ferri-fluoro-leakeite: a second occurrence at Bratthagen (Norway), with new data on Zn partitioning and the oxo component in Na amphiboles. Mineralogical Magazine, 78, 861-869.
Sweden
 
  • Jönköping County
    • Jönköping
      • Gränna
Gunnar Färber
 
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