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Oxyvanite

A valid IMA mineral species
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Formula:
V3+2V4+O5
Colour:
Black
Lustre:
Resinous
Hardness:
7 - 7½
Specific Gravity:
4.66 (Calculated)
Crystal System:
Monoclinic
Name:
For to composition, with oxygen and vanadium represented in its ideal formula.
Related to berdesinskiite


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Unique IdentifiersHide

Mindat ID:
39006
Long-form identifier:
mindat:1:1:39006:0
GUID
(UUID V4):
ea1449f5-0590-4e0d-a736-078280aacdf6

IMA Classification of OxyvaniteHide

IMA status:
Approved
Approval year:
2008
First published:
2009

Classification of OxyvaniteHide

Strunz-mindat (2023):
4.CB.30

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
Dana 8th ed.:
7.7.2.2

7 : MULTIPLE OXIDES
7 : AB2X5

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
OxyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OxyvaniteHide

Lustre:
Resinous
Colour:
Black
Streak:
Black
Hardness:
7 - 7½ on Mohs scale
Hardness:
VHN30=1180 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
none
Fracture:
Conchoidal
Density:
4.66(2) g/cm3 (Calculated)

Optical Data of OxyvaniteHide

Bireflectance:
None observed.
Reflectivity:
WavelengthR
440nm17.8%
460nm18.0%
480nm18.2%
500nm18.4%
520nm18.6%
540nm18.8%
560nm18.9%
580nm19.0%
600nm19.1%
620nm19.2%
640nm19.3%
660nm19.4%
680nm19.5%
700nm19.7%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 19.7%.
Colour in reflected light:
Pale cream.

Chemistry of OxyvaniteHide

Mindat Formula:
V3+2V4+O5
Elements listed:
O, V - search for minerals with similar chemistry

Crystallography of OxyvaniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 10.032(2) Å, b = 5.050(1) Å, c = 7.000(1) Å
β = 111.14(1)°
Ratio:
a:b:c = 1.987 : 1 : 1.386
Unit Cell V:
330.77 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0007328OxyvaniteArmbruster T, Galuskin E V, Reznitsky L Z, Sklyarov E V (2009) X-ray structural investigation of the oxyvanite (V3O5) - berdesinskiite (V2TiO5) series: V4+ substituting for octahedrally coordinated Ti4+ European Journal of Mineralogy 21 885-8912009Pereval marble quarry, Sludyanka complex, south of Lake Baikal, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.67 Å(60)
3.28 Å(100)
2.88 Å(100)
2.65 Å(100)
2.52 Å(60)
2.44 Å(100)
2.23 Å(60)
1.897 Å(80)
1.756 Å(60)
1.717 Å(100)
1.633 Å(100
1.522 Å(60)
1.485 Å(60)
1.446 Å(80)
1.379 Å(100)
Comments:
Slyudyanka, Lake Baikal area, Russia. Data from the type description. Note that the original data lists intensities on a five point scale; here they have been scaled to 100.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4

Type Occurrence of OxyvaniteHide

Type Locality:
ⓘ Slyudyanka, Lake Baikal area, Irkutsk Oblast, Russia
General Appearance of Type Material:
Anhedral grains, up to 0.1-0.15 mm in size.
Place of Conservation of Type Material:
The type material is deposited at the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow.
Geological Setting of Type Material:
Accessory mineral in Cr-V-bearing quartz-diopside metamorphic rocks.
Associated Minerals at Type Locality:
ZirconTremoliteTitaniteSchreyeriteScapolite
RutileQuartzPyriteOxy-vanadium-draviteNatalyite
KosmochlorKarelianiteIlmeniteGoldmaniteEskolaite
DraviteDiopsideCalciteBerdesinskiiteBaryte
Plagioclase

Synonyms of OxyvaniteHide

Related Minerals - Strunz-mindat GroupingHide

4.CB.SassiteTi3+2Ti4+O5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.Ferrohögbomite-2N2S[(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2Hex. 6mm : P63mc
4.CB.Magnesiohögbomite-6N12SMg5Al11TiO23(OH)Trig. 3m (3 2/m) : R3m
4.CB.GriffiniteAl2TiO5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.Zhenruite(MoO3)2 · H2OMon. 2/m : P21/m
4.CB.Pengite(Pb8Sb3+3)Σ11Sb5+9O35Trig. 3m (3 2/m) : R3m
4.CB.VirgilluethiteMoO3 · H2OMon. 2/m : P21/b
4.CB.05BrizziiteNaSb5+O3Trig. 3 : R3
4.CB.05CorundumAl2O3Trig. 3m (3 2/m) : R3c
4.CB.05Ecandrewsite(Zn,Fe2+,Mn2+)TiO3Trig. 3 : R3
4.CB.05EskolaiteCr2O3Trig. 3m (3 2/m) : R3c
4.CB.05GeikieliteMgTiO3Trig. 3 : R3
4.CB.05HematiteFe2O3Trig. 3m (3 2/m) : R3c
4.CB.05IlmeniteFe2+TiO3Trig. 3 : R3
4.CB.05KarelianiteV3+2O3Trig. 3m (3 2/m) : R3c
4.CB.05MelanostibiteMn2+2Fe3+Sb5+O6Trig. 3 : R3
4.CB.05PyrophaniteMn2+TiO3Trig. 3 : R3
4.CB.05Akimotoite(Mg,Fe2+)SiO3Trig. 3 : R3
4.CB.05AuroantimonateAuSbO3
4.CB.05UM1998-11-O-AuHSbAu+2Sb3+O2(OH)
4.CB.05TistariteTi3+2O3Trig. 3m (3 2/m) : R3c
4.CB.05Unnamed (Fe-Cr Oxide)FeCrO3Trig. 3 : R3
4.CB.05Hemleyite(Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3Trig. 3 : R3
4.CB.10AvicenniteTl2O3Iso. m3 (2/m 3) : Ia3
4.CB.10Bixbyite-(Mn)Mn3+2O3Iso. m3 (2/m 3) : Ia3
4.CB.10Bixbyite-(Fe)(Fe,Mn)2O3Iso.
4.CB.15Armalcolite(Mg,Fe2+)Ti2O5Orth. mmm (2/m 2/m 2/m)
4.CB.15PseudobrookiteFe2TiO5Orth. mmm (2/m 2/m 2/m)
4.CB.15FerropseudobrookiteFe2+Ti2O5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.20Zincohögbomite-2N2S[(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2Hex. 6mm : P63mc
4.CB.20Zincohögbomite-2N6S[(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2Hex. 6mm : P63mc
4.CB.20Magnesiohögbomite-6N6S[(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6Trig. 3m (3 2/m) : R3m
4.CB.20Magnesiohögbomite-2N3S[(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2Trig. 3m (3 2/m) : P3 1m
4.CB.20Magnesiohögbomite-2N2S[(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2Hex. 6mm : P63mc
4.CB.20Ferrohögbomite-6N12S[(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6Trig. 3m (3 2/m) : R3m
4.CB.20Magnesiohögbomite-2N4S(Mg8.43Fe2+1.57)sum=10Al22Ti4+2O46(OH)2Hex. 6mm : P63mc
4.CB.20Magnesiobeltrandoite-2N3S(Mg6Al2)(Al18Fe3+2)O38(OH)2 Trig. 3m : P3m1
4.CB.20Zincovelesite-6N6SZn3(Fe3+,Mn3+,Al,Ti)8O15(OH)Trig. 3m (3 2/m) : P3m1
4.CB.25PseudorutileFe2Ti3O9Hex. 6 2 2 : P63 2 2
4.CB.25KleberiteFeTi6O11(OH)5Mon. 2/m : P21/b
4.CB.30BerdesinskiiteV3+2TiO5Mon.
4.CB.30KaitianiteTi3+2Ti4+O5Mon. 2/m : B2/b
4.CB.35Olkhonskite(Cr,V)2Ti3O9Mon.
4.CB.35SchreyeriteV3+2Ti3O9Mon. 2/m : B2/b
4.CB.35MachiiteAl2Ti3O9Mon. 2/m : B2/b
4.CB.35Vestaite(Ti4+Fe2+)Ti4+3O9Mon. 2/m : B2/b
4.CB.40KamiokiteFe2Mo3O8Hex. 6mm : P63mc
4.CB.40NolaniteV3+8Fe3+2O14(OH)2Hex. 6mm : P63mc
4.CB.40RinmaniteZn2Sb2Mg2Fe4O14(OH)2Hex. 6 : P63
4.CB.40IseiteMn2Mo3O8Hex. 6mm : P63mc
4.CB.40MajindeiteMg2Mo3O8Hex. 6mm : P63mc
4.CB.45ClaudetiteAs2O3Mon. 2/m
4.CB.45StibioclaudetiteAsSbO3Mon. 2/m : P21/m
4.CB.50ArsenoliteAs2O3Iso. m3m (4/m 3 2/m) : Fd3m
4.CB.50SenarmontiteSb2O3Iso. m3m (4/m 3 2/m) : Fd3m
4.CB.55ValentiniteSb2O3Orth. mmm (2/m 2/m 2/m) : Pccn
4.CB.60BismiteBi2O3Mon. 2/m : P21/b
4.CB.65SphaerobismoiteBi2O3Tet.
4.CB.70SilléniteBi12SiO20Iso. 2 3 : I2 3
4.CB.75KyzylkumiteV3+Ti2O5(OH)Mon. 2/m : P21/b
4.CB.80TietaiyangiteFe3+4Fe2+TiO9Hex.
4.CB.85LiuiteFeTiO3Orth. mmm (2/m 2/m 2/m) : Pnma
4.CB.90LuogufengiteFe2O3Orth. mm2 : Pna21
4.CB.95WangdaodeiteFeTiO3Trig. 3m : R3c

Other InformationHide

Notes:
Insoluble in HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for OxyvaniteHide

References for OxyvaniteHide

Reference List:
Armbruster, T., Galuskin, E.V., Reznitsky, L.Z., Sklyarov, E.V. (2009) X-ray structural investigation of the oxyvanite (V3O5) - berdesinskiite (V2TiO5) series: V4+ substituting for octahedrally coordinated Ti4+. European Journal of Mineralogy, 21, 885-891.
Reznitsky, L.Z., Sklyarov, E.V., Armbruster, T., Ushchapovskaya, Z.F., Galuskin, E.V., Polekhovsky, Y.S., Barash, I.G. (2009) The new mineral oxyvanite V3O5 and the oxyvanite-berdesinskiite V2TiO5 isomorphic join in metamorphic rocks of Sludyanka complex (South Baikal region) (abstract). Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva, 138(3), 70-81.
Di Cecco, Veronica E., Tait, Kimberly T., Spooner, Edward T.C., Scherba, Craig (2018) The Vanadium-bearing Oxide Minerals of the Green Giant Vanadium-graphite Deposit, Southwest Madagascar. The Canadian Mineralogist, 56 (3). 247-257 doi:10.3749/canmin.1700068

Localities for OxyvaniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Liguria
    • Genoa
      • Ne
Balestra C. (2014): Sistematica ligure 2014. Prie, 10, 35-37.
Madagascar
 
  • Atsimo-Andrefana
    • Ampanihy District
      • Fotadrevo
        • Green Giant Vanadium Property
Di Cecco, Veronica E., Tait, Kimberly T., Spooner, Edward T.C., Scherba, Craig (2018) The Vanadium-bearing Oxide Minerals of the Green Giant Vanadium-graphite Deposit, Southwest Madagascar. The Canadian Mineralogist, 56 (3). 247-257 doi:10.3749/canmin.1700068
Di Cecco, Veronica E., Tait, Kimberly T., Spooner, Edward T.C., Scherba, Craig (2018) The Vanadium-bearing Oxide Minerals of the Green Giant Vanadium-graphite Deposit, Southwest Madagascar. The Canadian Mineralogist, 56 (3). 247-257 doi:10.3749/canmin.1700068
Russia (TL)
 
  • Irkutsk Oblast
    • Lake Baikal area
European J. Mineralogy 21,885(2009)
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