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Arsenuranospathite

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About ArsenuranospathiteHide

Formula:
Al(UO2)2(AsO4)2F · 20H2O
Colour:
Pale yellow
Hardness:
2
Crystal System:
Orthorhombic
Name:
Named in allusion to its composition as the ARSENate analog of uranospathite.
Isostructural with:
Partially dehydrates readily in air (Walenta, 1978) to form Unnamed (Partially dehydrated Arsenuranospathite), which contains only 10 water molecules per formula unit.

Chemically related to chistyakovaite.

Crystal structure details:

- corner-sharing UO6 square bipyramids
- (As,P)O4 tetrahedra
- the above form autunite-type [(UO2)((As,P)O4)] sheet
- Al(H2O)6 octahedra are in the interlayer space
- 8 isolated water molecules in the interlayer
- hydrogen bonds link together the water molecules, Al octahedra and UAs-bearing sheets, forming a very complex bonding net
- F likely replaces some of the water molecules of the Al-bearing octahedra.


Classification of ArsenuranospathiteHide

Approved, 'Grandfathered' (first described prior to 1959)
8.EB.25

8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
40.2a.23.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
20.7.14

20 : Arsenates (also arsenates with phosphate, but without other anions)
7 : Arsenates of U

Physical Properties of ArsenuranospathiteHide

Colour:
Pale yellow
Hardness:

Optical Data of ArsenuranospathiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.542 nε = 1.538
Max Birefringence:
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemical Properties of ArsenuranospathiteHide

Formula:
Al(UO2)2(AsO4)2F · 20H2O
Common Impurities:
P

Crystallography of ArsenuranospathiteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pnn2
Cell Parameters:
a = 29.9262(7) Å, b = 7.1323(1) Å, c = 7.1864(1) Å
Ratio:
a:b:c = 4.196 : 1 : 1.008
Unit Cell V:
1533.9 ų
Z:
2

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
14.62 Å(100)
7.62 Å(100)
3.49 Å(90)
5.03 Å(80)
3.59 Å(50)
3.24 Å(40)
2.25 Å(30)
Comments:
Menzenschwand material

Type Occurrence of ArsenuranospathiteHide

Other Language Names for ArsenuranospathiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Arsenuranospathite associated with Betpakdalite-CaCa[Ca2(H2O)17Ca(H2O)6][Mo6+8As5+2Fe3+3O36(OH)]
1 photo of Arsenuranospathite associated with MetatorberniteCu(UO2)2(PO4)2 · 8H2O

Related Minerals - Nickel-Strunz GroupingHide

8.EB.05AutuniteCa(UO2)2(PO4)2 · 11H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.EB.05HeinrichiteBa(UO2)2(AsO4)2 · 10H2OMon. 2/m
8.EB.05KahleriteFe(UO2)2(AsO4)2 · 12H2OTet. 4/m : P42/n
8.EB.05Nováčekite-IMg(UO2)2(AsO4)2 · 12H2OTric. 1 : P1
8.EB.05SaléeiteMg(UO2)2(PO4)2 · 10H2OMon. 2/m : P21/b
8.EB.05TorberniteCu(UO2)2(PO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.EB.05UranocirciteBa(UO2)2(PO4)2 · 10H2OTet.
8.EB.05UranospiniteCa(UO2)(AsO4)2 · 10H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.05Xiangjiangite(Fe3+,Al)(UO2)4(PO4)2(SO4)2(OH) · 22H2OTet.
8.EB.05ZeuneriteCu(UO2)2(AsO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.EB.05MetarauchiteNi(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.05RauchiteNi(UO2)2(AsO4)2 · 10H2OTric. 1 : P1
8.EB.10BassetiteFe2+(UO2)2(PO4)2 · 10H2OMon. 2/m
8.EB.10LehneriteMn2+(UO2)2(PO4)2 · 8H2OMon.
8.EB.10Meta-autuniteCa(UO2)2(PO4)2 · 6-8H2OTet. 4/mmm (4/m 2/m 2/m)
8.EB.10MetasaléeiteMg(UO2)2(PO4)2 · 8H2O
8.EB.10Metauranocircite-IBa(UO2)2(PO4)2 · 7H2OMon. 2 : P21
8.EB.10MetauranospiniteCa(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
8.EB.10MetaheinrichiteBa(UO2)2(AsO4)2 · 8H2OTet. 4mm
8.EB.10MetakahleriteFe2+(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.10MetakirchheimeriteCo(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
8.EB.10MetanováčekiteMg(UO2)2(AsO4)2 · 8H2OTet. 4/m : P4/n
8.EB.10MetatorberniteCu(UO2)2(PO4)2 · 8H2OTet. 4/m : P4/n
8.EB.10MetazeuneriteCu(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
8.EB.10PrzhevalskitePb2(UO2)3(PO4)2(OH)4 · 3H2OOrth.
8.EB.10Meta-lodèviteZn(UO2)2(AsO4)2 · 10H2O
8.EB.15AbernathyiteK(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
8.EB.15Chernikovite(H3O)2(UO2)2(PO4)2 · 6H2OTet.
8.EB.15Meta-ankoleiteK2(UO2)2(PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15Natrouranospinite(Na2,Ca)(UO2)2(AsO4)2 · 5H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15Trögerite(H3O)(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
8.EB.15Uramphite(NH4)2(UO2)2(PO4)2 · 6H2OTet.
8.EB.15Uramarsite(NH4,H3O)2(UO2)2(AsO4,PO4)2 · 6H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
8.EB.20ThreadgolditeAl(UO2)2(PO4)2(OH) · 8H2OMon.
8.EB.20ChistyakovaiteAl(UO2)2(AsO4)2(F,OH) · 6.5H2OMon.
8.EB.25Uranospathite(Al,☐)(UO2)2(PO4)2F · 20(H2O,F)Orth. mm2 : Pnn2
8.EB.30Vochtenite(Fe2+,Mg)Fe3+(UO2)4(PO4)4(OH) · 12-13H2OMon.
8.EB.35CoconinoiteFe3+2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2OMon.
8.EB.40RanunculiteHAl(UO2)(PO4)(OH)3 · 4H2OMon.
8.EB.45TrianguliteAl3(UO2)4(PO4)4(OH)5 · 5H2OTric.
8.EB.50FurongiteAl13(UO2)7(PO4)13(OH)14 · 58H2OTric. 1 : P1
8.EB.55SabugaliteHAl(UO2)4(PO4)4 · 16H2OMon. 2/m : B2/m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

20.7.1Trögerite(H3O)(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
20.7.2Natrouranospinite(Na2,Ca)(UO2)2(AsO4)2 · 5H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
20.7.3AbernathyiteK(UO2)(AsO4) · 3H2OTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
20.7.4MetazeuneriteCu(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
20.7.5ZeuneriteCu(UO2)2(AsO4)2 · 12H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
20.7.6MetanováčekiteMg(UO2)2(AsO4)2 · 8H2OTet. 4/m : P4/n
20.7.7Nováčekite-IMg(UO2)2(AsO4)2 · 12H2OTric. 1 : P1
20.7.8ArsenuranyliteCa(UO2)4(AsO4)2(OH)4 · 6H2OOrth.
20.7.9MetauranospiniteCa(UO2)2(AsO4)2 · 8H2OTet. 4/m : P42/n
20.7.10UranospiniteCa(UO2)(AsO4)2 · 10H2OTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
20.7.11MetaheinrichiteBa(UO2)2(AsO4)2 · 8H2OTet. 4mm
20.7.12HeinrichiteBa(UO2)2(AsO4)2 · 10H2OMon. 2/m
20.7.13MetalodèviteZn(UO2)2(AsO4)2 · 10H2OTet.
20.7.15HallimonditePb2(UO2)(AsO4)2 · nH2O, 0 <= n <= 0.5Tric. 1 : P1
20.7.16HügelitePb2(UO2)3(AsO4)2O2 · 5H2OMon.
20.7.17AsselbornitePb(BiO)3(UO2)4(AsO4)2(OH)7·4H2OIso.
20.7.18MetakahleriteFe2+(UO2)2(AsO4)2 · 8H2OTric. 1 : P1
20.7.19KahleriteFe(UO2)2(AsO4)2 · 12H2OTet. 4/m : P42/n
20.7.20MetakirchheimeriteCo(UO2)2(AsO4)2 · 8H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for ArsenuranospathiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Walenta, K. (1978): Uranospathite and arsenuranospathite. Mineral. Mag., 42, 117-128. [Abs. in American Mineralogist: 64: 465]
Chukanov, N.V., Möckel, S., Sidorenko, G.A., Zaitsev, V.A. (2009): Arsenuranospathite, Al(UO2)2(AsO4)2F·20H2O: Formula revision and relationships with allied uranyl arsenates and phosphates. Neues Jahrbuch für Mineralogie - Abhandlungen 185, 305-312.
Dal Bo, F., Hatert, F., Baijot, M., Philippo, S. (2015): Crystal structure of arsenuranospathite from Rabejac, Lodève, France. European Journal of Mineralogy: 27, 589-597.
Anthony, J.W., Bideaux, R.A., Bladh, K.W. and Nichols, M.C., Eds. Handbook of Mineralogy, Mineralogical Society of America, Chantilly, VA 20151-1110, USA. http://www.handbookofmineralogy.org/ (2016)
Theye, T., Walenta, K., Markl, G. (2016): The chemical composition of uranospathite, arsenuranospathite, and associated minerals revisited: the peculiarity of fluorine incorporation in autunite group minerals. Neues Jahrbuch für Mineralogie - Abhandlungen: Journal of Mineralogy and Geochemistry 193, 59-68.

Internet Links for ArsenuranospathiteHide

Localities for ArsenuranospathiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
Lapis 2002(7/8), 63-65
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Razès
Le Règne Minéral, Hors Série IV, 1998
      • Saint-Sylvestre
Le Règne Minéral, Hors Série IV, 1998
  • Occitanie
    • Hérault
      • Le Puech
[Le Règne Minéral 1997, 13, p.5-18]; Bariand, P., Bachet, B., Brassy, C., Medenbach, O., Deliens, M., Vautier, R., & Piret, P. (1993) A New Uranium Mineral from the Talmessi Mine, Iran, and Rabejac, France. Mineralogical Record: 24: 463-467; Dal Bo, F., Hatert, F., Baijot, M., & Philippo, S. (2015). Crystal structure of arsenuranospathite from Rabejac, Lodève, France. European Journal of Mineralogy, 27(4), 589-597.; Dal Bo, F., Hatert, F., & Philippo, S. (2018). Supergene Uranyl Mineralization of the Rabejac Deposit, Lodève, France. Minerals, 8(9), 414.
Germany
 
  • Baden-Württemberg
    • Freiburg
      • Breisgau-Hochschwarzwald
        • Bollschweil
          • St Ulrich
Lapis 21(12), 43 (1996)
      • Ortenaukreis
        • Haslach im Kinzigtal
          • Schnellingen
Blaß, G. & Graf, H.W. (2000): Neufunde von bekannten Fundorten im Schwarzwald. Mineralien-Welt, 11 (4), 57-60.
      • Rottweil
        • Schenkenzell
Unnamed (Partially dehydrated Arsenuranospathite)
            • Böckelsbach valley
K. Walenta: "Die Mineralien des Schwarzwaldes", Weise (Munich), 1992; Mineralogical Magazine(1978) 42, 117-128
            • Burgfelsen
No reference listed
            • Heubach Valley
No reference listed
      • Waldshut
        • St Blasien
          • Menzenschwand
Walenta: "Die Mineralien des Schwarzwaldes", Weise (Munich), 1992
  • Rhineland-Palatinate
    • Birkenfeld
      • Ellweiler
Aufschluss 69/(7+8), Lapis 79/(7+8)
Italy
 
  • Piedmont
    • Cuneo Province
      • Bagnolo Piemonte
Marello, B., Bittarello, E., Marengo, A., Bertan, M., Cianchi, L., Ciriotti, M.E. (2018) Arsenuranospatite di Montoso: primo ritrovamento in Italia. Micro, 16, 2-2018, 70-85.
Kazakhstan
 
  • Almaty Region
    • Alakol
P.M. Kartashov data
Switzerland
 
  • Valais
    • Le Trient Valley
      • Salvan
        • Les Marécottes
USA
 
  • Utah
    • San Juan Co.
      • Red Canyon
Kampf, A.R., Plášil, J., Kasatkin, A.V., Marty, J., and Čejka, J. (2018) Markeyite, a new calcium uranyl carbonate mineral from the Markey mine, San Juan County, Utah, USA. Mineralogical Magazine, 82, 1089-1100.
 
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