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Pertlikite

A valid IMA mineral species

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Photos of Pertlikite (18)

Pertlikite Gallery Search Photos of Pertlikite

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Pertlikite

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Pertlikite, etc.

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Pertlikite

Alcaparrosa Mine, Sierra Gorda, Antofagasta Province, Antofagasta, Chile

Pertlikite

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Pertlikite, etc.

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Pertlikite

Alcaparrosa Mine, Sierra Gorda, Antofagasta Province, Antofagasta, Chile

Pertlikite

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Pertlikite, etc.

Grotta dell'Allume, Faraglione Nico, Faraglioni di Levante, Porto Levante, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

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About PertlikiteHide

Formula:

K₂(Fe²⁺,Mg)₂Mg₄Fe³⁺₂Al(SO₄)₁₂ · 18H₂O

Colour:

Dark olive green to black

Specific Gravity:

2.59

Crystal System:

Tetragonal

Member of:

Voltaite Group

Name:

In honour of Franz Pertlik (b. 1943), Professor of Mineralogy and Crystallography, University of Vienna, Austria, in recognition of his extensive work on the crystal chemistry of minerals.

Type Locality:

ⓘ Zagh Mine, Hajjiabad, Hajjiabad County, Hormozgan Province, Iran

Voltaite Group. Chemically related to magnesiovoltaite. One of a few ferrous-ferric sulfate minerals, by bílinite, copiapite, römerite (purely Fe minerals), metavoltine, and voltaite.

Tetragonal-pseudocubic due to ordering of Fe and Mg.

An apparently cubic (a = 27.220 Å) pertlikite-related mineral with the formula [K_0.73(NH₄)_0.27]₂(Mg,Al,Fe)₆²⁺(Fe_0.93Al_0.07)₂³⁺Al(SO₄)₁₂·18H₂O and unknown Fe(II):Fe(III) ratio was described by Witzke et al. (2015).

Unique IdentifiersHide

Mindat ID:

36064

Long-form identifier:

mindat:1:1:36064:3

GUID
(UUID V4):

c71c6d62-e9b2-4899-85ab-1c5f43e99834

IMA Classification of PertlikiteHide

IMA status:

Approved

IMA Formula:

K₂(Fe²⁺,Mg)₂(Mg,Fe³⁺)₄Fe³⁺₂Al(SO₄)₁₂ · 18H₂O

Approval year:

2005

First published:

2008

Classification of PertlikiteHide

Strunz-mindat (2024):

7.CC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H₂O
C : With medium-sized and large cations

Dana 8th ed.:

29.9.1.3

29 : HYDRATED ACID AND NORMAL SULFATES
9 : Miscellaneous

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol	Source	Reference
Plk	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Prt	The Canadian Mineralogist (2019)	The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of PertlikiteHide

Colour:

Dark olive green to black

Streak:

Grayish green

Cleavage:

None Observed

Fracture:

Conchoidal

Density:

2.59(3) g/cm³ (Measured) 2.56(1) g/cm³ (Calculated)

Optical Data of PertlikiteHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.590(2) n_ε = 1.586(2)

Birefringence:

Very low

Max Birefringence:

δ = 0.004

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Moderate

Chemistry of PertlikiteHide

Mindat Formula:

K₂(Fe²⁺,Mg)₂Mg₄Fe³⁺₂Al(SO₄)₁₂ · 18H₂O

Elements listed:

Al, Fe, H, K, Mg, O, S - search for minerals with similar chemistry

Crystallography of PertlikiteHide

Crystal System:

Tetragonal

Class (H-M):

4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal

Space Group:

I4₁/acd

Cell Parameters:

a = 19.2080 Å, c = 27.2158 Å

Ratio:

a:c = 1 : 1.417

Unit Cell V:

10,041.19 Å³ (Calculated from Unit Cell)

Comment:

Pseudocubic.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0006190	Pertlikite	Ertl A, Dyar M D, Hughes J M, Brandstatter F, Gunter M E, Prem M, Peterson R C (2008) Pertlikite, a new tetragonal Mg-rich member of the voltaite group from Madeni Zakh, Iran The Canadian Mineralogist 46 661-669		2008	Madeni Zakh, Iran	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Pertlikite'
loop_
_publ_author_name
'Ertl A'
'Dyar M D'
'Hughes J M'
'Brandstatter F'
'Gunter M E'
'Prem M'
'Peterson R C'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 46 
_journal_year 2008
_journal_page_first 661
_journal_page_last 669
_publ_section_title
;
 Pertlikite, a new tetragonal Mg-rich member of the voltaite group from Madeni Zakh, Iran
;
_database_code_amcsd 0006190
_chemical_compound_source 'Madeni Zakh, Iran'
_chemical_formula_sum 'S12 Fe4.47 Mg3.53 Al K2 O66.252 H36.504'
_cell_length_a 19.2080
_cell_length_b 19.2080
_cell_length_c 27.2158
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 10041.194
_exptl_crystal_density_diffrn      2.543
_symmetry_space_group_name_H-M 'I 41/a c d'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '1/4-y,3/4-x,3/4+z'
  '3/4-y,1/4-x,1/4+z'
  '1/4+y,3/4+x,3/4-z'
  '3/4+y,1/4+x,1/4-z'
  '1/4+y,3/4-x,1/4-z'
  '3/4+y,1/4-x,3/4-z'
  '1/4-y,3/4+x,1/4+z'
  '3/4-y,1/4+x,3/4+z'
  '1/2+x,-y,z'
  '+x,1/2-y,1/2+z'
  '1/2-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2+x,y,1/2-z'
  '+x,1/2+y,-z'
  '1/2-x,-y,1/2+z'
  '-x,1/2-y,+z'
  '1/4+y,1/4+x,1/4+z'
  '3/4+y,3/4+x,3/4+z'
  '1/4-y,1/4-x,1/4-z'
  '3/4-y,3/4-x,3/4-z'
  '1/4-y,1/4+x,3/4-z'
  '3/4-y,3/4+x,1/4-z'
  '1/4+y,1/4-x,3/4+z'
  '3/4+y,3/4-x,1/4+z'
  '-x,y,1/2+z'
  '1/2-x,1/2+y,+z'
  'x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
S1   0.96172   0.01319   0.88167   1.00000   0.01256
S2   0.85585   0.09319   0.01219   1.00000   0.01247
S3   0.10633   0.13065   0.97439   1.00000   0.01271
Fe1   0.00000   0.00000   0.00000   1.00000   0.01297
Fe2   0.79421   0.00000   0.75000   0.71900   0.01341
Mg2   0.79421   0.00000   0.75000   0.28100   0.01341
Mg3   0.85252   0.14740   0.89717   0.74200   0.01346
Fe3   0.85252   0.14739   0.89717   0.25800   0.01346
Al   0.00000   0.25000   0.12500   1.00000   0.01185
K   0.00007   0.00000   0.75000   1.00000   0.03164
O1   0.94004  -0.05104   0.85726   1.00000   0.02930
O2   0.00530   0.05430   0.84827   1.00000   0.02340
O3   0.89868   0.05176   0.89558   1.00000   0.02300
O4   0.00262  -0.00378   0.92639   1.00000   0.01930
O5   0.85269   0.13891   0.05494   1.00000   0.02900
O6   0.82315   0.12712   0.96982   1.00000   0.02290
O7   0.81894   0.02821   0.02480   1.00000   0.02330
O8   0.92949   0.07699   0.00033   1.00000   0.01900
O9   0.08850   0.19804   0.99582   1.00000   0.02980
O10   0.08053   0.12894   0.92374   1.00000   0.02390
O11   0.18249   0.12144   0.97558   1.00000   0.02450
O12   0.07354   0.07388   0.00326   1.00000   0.01920
O13   0.94033   0.19736   0.92101   1.00000   0.02470
H13A   0.97440   0.17770   0.92080   1.00000   0.06500
H13B   0.93160   0.22570   0.94130   1.00000   0.07300
O14   0.79926   0.04325   0.68084   1.00000   0.02520
H14A   0.83890   0.04670   0.67160   1.00000   0.07900
H14B   0.76830   0.06880   0.67440   1.00000   0.10600
O15   0.75947   0.10238   0.87849   1.00000   0.02480
H15A   0.72750   0.11200   0.89660   1.00000   0.06400
H15B   0.75200   0.09600   0.85050   1.00000   0.10300
Wat1  -0.01370   0.19270   0.17896   0.22500   0.01980
Wat2  -0.01900   0.15850   0.10342   0.22200   0.02100
Wat3  -0.07590   0.28200   0.08946   0.23600   0.02270
Wat4   0.05790   0.26390   0.17991   0.22100   0.02160
Wat5   0.08980   0.26850   0.10361   0.23300   0.02130
Wat6  -0.03320   0.32690   0.08894   0.22800   0.02180
Wat7   0.00000   0.25000   0.19460   0.12900   0.02300
Wat8  -0.06970   0.31970   0.12500   0.13400   0.02400
Wat9   0.06940   0.31940   0.12500   0.13300   0.02300

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
5.543 Å	(28)
3.396 Å	(100)
3.136 Å	(21)
3.038 Å	(39)
2.848 Å	(31)
2.534 Å	(21)
2.078 Å	(29)
1.601 Å	(21)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
Stage 10b: Anthropogenic minerals	<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of PertlikiteHide

Type Locality:

ⓘ Zagh Mine, Hajjiabad, Hajjiabad County, Hormozgan Province, Iran

General Appearance of Type Material:

Single crystals up to 1 cm.

Place of Conservation of Type Material:

Institute for Mineralogy and Crystallography, University of Vienna, Austria (7813).
National Museum of Natural History, Washington, D.C., USA (NMNH174370).
Museum of Natural History, Harvard University, Cambridge, Massachusetts, USA, (135547).

Geological Setting of Type Material:

Pyrite-bearing trachytic eruptive rock. It probably formed after the decomposition of pyrite.

Associated Minerals at Type Locality:

Synonyms of PertlikiteHide

IMA2005-055

Relationship of Pertlikite to other SpeciesHide

Member of:

Voltaite Group

Other Members of this group:

Ammoniomagnesiovoltaite	(NH₄)₂Mg²⁺₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
Ammoniovoltaite	(NH₄)₂Fe²⁺₅Fe³⁺₃Al(SO₄)₁₂(H₂O)₁₈	Iso. m3m (4/m 3 2/m) : Fd3c
Magnesiovoltaite	K₂Mg₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
Voltaite	K₂Fe²⁺₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
Zincovoltaite	K₂Zn₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c

Common AssociatesHide

Associated Minerals Based on Photo Data:

3 photos of Pertlikite associated with Coquimbite	AlFe₃(SO₄)₆(H₂O)₁₂ · 6H₂O
2 photos of Pertlikite associated with Alcaparrosaite	K₃Ti⁴⁺Fe³⁺(SO₄)₄O(H₂O)₂
1 photo of Pertlikite associated with Tamarugite	NaAl(SO₄)₂ · 6H₂O
1 photo of Pertlikite associated with Krausite	KFe(SO₄)₂ · H₂O

Related Minerals - Strunz-mindat Grouping Hide

7.CC.	Cobaltoblödite	Na₂Co(SO₄)₂ · 4H₂O	Mon. 2/m : P2₁/b
7.CC.	Andychristyite	PbCu²⁺Te⁶⁺O₅(H₂O)	Tric. 1 : P1
7.CC.	Ammoniovoltaite	(NH₄)₂Fe²⁺₅Fe³⁺₃Al(SO₄)₁₂(H₂O)₁₈	Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.05	Krausite	KFe(SO₄)₂ · H₂O	Mon. 2/m : P2₁/m
7.CC.10	Tamarugite	NaAl(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.15	Kalinite	KAl(SO₄)₂ · 11H₂O	Mon. 2/m : B2/b
7.CC.15	Mendozite	NaAl(SO₄)₂ · 11H₂O	Mon. 2/m : B2/b
7.CC.20	Lonecreekite	(NH₄)Fe³⁺(SO₄)₂ · 12H₂O	Iso. m3 (2/m 3) : Pa3
7.CC.20	Alum-(K)	KAl(SO₄)₂ · 12H₂O	Iso. m3 (2/m 3) : Pa3
7.CC.20	Alum-(Na)	NaAl(SO₄)₂ · 12H₂O	Iso. m3 (2/m 3) : Pa3
7.CC.20	Tschermigite	(NH₄)Al(SO₄)₂ · 12H₂O	Iso. m3 (2/m 3) : Pa3
7.CC.20	Lanmuchangite	Tl⁺Al(SO₄)₂ · 12H₂O	Iso. m3 (2/m 3) : Pa3
7.CC.25	Voltaite	K₂Fe²⁺₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.25	Zincovoltaite	K₂Zn₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.25	Ammoniomagnesiovoltaite	(NH₄)₂Mg²⁺₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.25	Magnesiovoltaite	K₂Mg₅Fe³⁺₃Al(SO₄)₁₂ · 18H₂O	Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.30	Kröhnkite	Na₂Cu(SO₄)₂ · 2H₂O	Mon. 2/m : P2₁/b
7.CC.35	Ferrinatrite	Na₃Fe(SO₄)₃ · 3H₂O	Trig. 3 : P3
7.CC.40	Goldichite	KFe(SO₄)₂ · 4H₂O	Mon. 2/m : P2₁/b
7.CC.45	Löweite	Na₁₂Mg₇(SO₄)₁₃ · 15H₂O	Trig. 3 : R3
7.CC.50	Blödite	Na₂Mg(SO₄)₂ · 4H₂O	Mon. 2/m : P2₁/b
7.CC.50	Nickelblödite	Na₂(Ni,Mg)(SO₄)₂ · 4H₂O	Mon. 2/m : P2₁/b
7.CC.50	Changoite	Na₂Zn(SO₄)₂ · 4H₂O	Mon. 2/m : P2₁/b
7.CC.55	Leonite	K₂Mg(SO₄)₂ · 4H₂O	Mon. 2/m : B2/m
7.CC.55	Mereiterite	K₂Fe(SO₄)₂ · 4H₂O	Mon. 2/m : B2/m
7.CC.60	Boussingaultite	(NH₄)₂Mg(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.60	Cyanochroite	K₂Cu(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.60	Mohrite	(NH₄)₂Fe(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.60	Nickelboussingaultite	(NH₄)₂Ni(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.60	Picromerite	K₂Mg(SO₄)₂ · 6H₂O	Mon. 2/m : P2/b
7.CC.60	Nickelpicromerite	K₂Ni(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.60	Katerinopoulosite	(NH₄)₂Zn(SO₄)₂ · 6H₂O	Mon. 2/m : P2₁/b
7.CC.65	Polyhalite	K₂Ca₂Mg(SO₄)₄ · 2H₂O	Tric. 1
7.CC.70	Leightonite	K₂Ca₂Cu(SO₄)₄ · 2H₂O	Mon. 2/m : B2/b
7.CC.75	Amarillite	NaFe(SO₄)₂ · 6H₂O	Mon. 2/m : B2/b
7.CC.80	Konyaite	Na₂Mg(SO₄)₂ · 5H₂O	Mon. 2/m : P2₁/b
7.CC.85	Wattevilleite	Na₂Ca(SO₄)₂ · 4H₂O (?)	Orth.
7.CC.85	Xocolatlite	Ca₂Mn⁴⁺₂(Te⁶⁺O₆)₂ · H₂O	Mon. 2/m : P2/m
7.CC.90	Eckhardite	(Ca,Pb)Cu²⁺Te⁶⁺O₅(H₂O)	Mon. 2/m

Fluorescence of PertlikiteHide

In UV light:

Not fluorescent.

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PertlikiteHide

mindat.org URL:

https://www.mindat.org/min-36064.html
Please feel free to link to this page.

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External Links:

Look for Pertlikite on Webmineral

Look for Pertlikite on Wikipedia

Look for Pertlikite on Mineralien Atlas

Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for PertlikiteHide

Reference List:

Ertl, A.; Dyar, M.D.; Hughes, J.M.; Brandstätter, F.; Gunter, M.E.; Prem, M.; Peterson, R.C. (2008): Pertlikite, a new tetragonal Mg-rich member of the voltaite group from Madeni Zakh, Iran. The Canadian Mineralogist, 46, 661-669.

Majzlan, J., Schlicht, H., Wierzbicka-Wieczorek, M., Giester, G., Pöllmann, H., Brömme, B., Doyle, S., Buth, G., Bender Koch, C. (2013): A contribution to the crystal chemistry of the voltaite group: solid solutions, Mössbauer and infrared spectra, and anomalous anisotropy. Mineralogy and Petrology, 107, 221-233.

Witzke, T., de Wit, F., Kolitsch, U., Blaß, G. (2015) Mineralogy of the Burning Anna I Coal Mine Dump, Alsdorf, Germany. In Coal and Peat Fires: A Global Perspective- Case Studies – Coal Fires Vol. 3. Elsevier. p.203-240. doi:10.1016/C2010-0-68844-4

(2023) Pertlikite. Handbook of Mineralogy. Mineralogical Society of America

Localities for PertlikiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Chile
Antofagasta Antofagasta Province Sierra Gorda ⓘ Alcaparrosa Mine	Samples analysed by Tony Kampf (LAC Museum) +5 other references

Costa Rica
Alajuela Province Sarchí Canton ⓘ Poás Volcano	Rodríguez et al. (2017)

Hungary
Baranya County Pécs District ⓘ Pécs-Vasas	Collectors: Gábor Koller & Dávid ...

Iran (TL)
Hormozgan Province Hajjiabad County Hajjiabad ⓘ Zagh Mine (TL)	Ertl +6 other references

Italy
Campania Naples Pozzuoli ⓘ Antiniana (Scarfoglio) ?	Russo et al. (2017)
ⓘ Pisciarelli di Agnano ?	Russo et al. (2017)
Sicily Metropolitan City of Messina Eolie Islands (Aeolian Islands) Lipari Vulcano Island Porto Levante Faraglioni di Levante Faraglione Nico ⓘ Grotta dell'Allume	Campostrini I. et al - Vulcano: ein ...

Poland
Silesian Voivodeship Wodzisław County Radlin ⓘ Marcel mine heap ?	Cu +2 other references

Pertlikite

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