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Pertlikite

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About PertlikiteHide

Formula:
K2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2O
Crystal System:
Tetragonal
Member of:
Name:
In honour of Franz Pertlik (b. 1943), Professor of Mineralogy and Crystallography, University of Vienna, Austria, in recognition of his extensive work on the crystal chemistry of minerals.
Voltaite Group. Chemically related to magnesiovoltaite. One of a few ferrous-ferric sulfate minerals, by bílinite, copiapite, römerite (purely Fe minerals), metavoltine, and voltaite.

Tetragonal-pseudocubic due to ordering of Fe and Mg.

An apparently cubic (a = 27.220 Å) pertlikite-related mineral with the formula [K0.73(NH4)0.27]2(Mg,Al,Fe)62+(Fe0.93Al0.07)23+Al(SO4)12·18H2O and unknown Fe(II):Fe(III) ratio was described by Witzke et al. (2015).


Classification of PertlikiteHide

Approved
Approval Year:
2005
7.CC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.9.1.3

29 : HYDRATED ACID AND NORMAL SULFATES
9 : Miscellaneous

Chemical Properties of PertlikiteHide

Formula:
K2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2O
IMA Formula:
K2(Fe2+,Mg)2(Mg,Fe3+)4Fe3+2Al(SO4)12 · 18H2O

Crystallography of PertlikiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
I41/acd
Cell Parameters:
a = 19.2080 Å, c = 27.2158 Å
Ratio:
a:c = 1 : 1.417
Unit Cell V:
10,041.19 ų (Calculated from Unit Cell)
Comment:
Pseudocubic.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.543 Å(28)
3.396 Å(100)
3.136 Å(21)
3.038 Å(39)
2.848 Å(31)
2.534 Å(21)
2.078 Å(29)
1.601 Å(21)

Type Occurrence of PertlikiteHide

Synonyms of PertlikiteHide

Relationship of Pertlikite to other SpeciesHide

Member of:
Other Members of this group:
Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m (4/m 3 2/m) : Fd3c
MagnesiovoltaiteK2Mg5Fe3+3Al(SO4)12·18H2OIso. m3m (4/m 3 2/m) : Fd3c
VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Pertlikite associated with CoquimbiteAlFe3(SO4)6(H2O)12·6H2O
1 photo of Pertlikite associated with TamarugiteNaAl(SO4)2 · 6H2O

Related Minerals - Nickel-Strunz GroupingHide

7.CC.CobaltoblöditeNa2Co(SO4)2•4H2OMon. 2/m : P21/b
7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m
7.CC.15KaliniteKAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.15MendoziteNaAl(SO4)2 · 11H2OMon. 2/m
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso.
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2O
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.35FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig.
7.CC.50BlöditeNa2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.50NickelblöditeNa2(Ni,Mg)(SO4)2 · 4H2O
7.CC.50ChangoiteNa2Zn(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.55LeoniteK2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.55MereiteriteK2Fe(SO4)2 · 4H2OMon.
7.CC.60Boussingaultite(NH4)2Mg(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60CyanochroiteK2Cu(SO4)2 · 6H2OMon. 2/m
7.CC.60Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Nickelboussingaultite(NH4)2Ni(SO4)2 · 6H2O
7.CC.60PicromeriteK2Mg(SO4)2 · 6H2OMon. 2/m
7.CC.65PolyhaliteK2Ca2Mg(SO4)4 · 2H2OTric. 1
7.CC.70LeightoniteK2Ca2Cu(SO4)4 · 2H2OTric.
7.CC.75AmarilliteNaFe(SO4)2 · 6H2OMon. 2/m : B2/b
7.CC.80KonyaiteNa2Mg(SO4)2 · 5H2OMon. 2/m : P21/b
7.CC.85WattevilleiteNa2Ca(SO4)2 · 4H2O (?)Orth.

Related Minerals - Dana Grouping (8th Ed.)Hide

29.9.1.1VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
29.9.1.2ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
29.9.1.4Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for PertlikiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Ertl, A.; Dyar, M.D.; Hughes, J.M.; Brandstätter, F.; Gunter, M.E.; Prem, M.; Peterson, R.C. (2008): Pertlikite, a new tetragonal Mg-rich member of the voltaite group from Madeni Zakh, Iran. Canadian Mineralogist, 46, 661-669.
Majzlan, J., Schlicht, H., Wierzbicka-Wieczorek, M., Giester, G., Pöllmann, H., Brömme, B., Doyle, S., Buth, G., Bender Koch, C. (2013): A contribution to the crystal chemistry of the voltaite group: solid solutions, Mössbauer and infrared spectra, and anomalous anisotropy. Mineralogy and Petrology, 107, 221-233.
Witzke, T., de Wit, F., Kolitsch, U. and Blaß, G. (2015): Mineralogy of the Burning Anna I Coal Mine Dump, Alsdorf, Germany. Chapter 7, pp. 203-240, in: Stracher, G. B., Prakash, A. and Sokol, E. V.: Coal and Peat Fires: A Global Perspective, Volume 3: Case Studies - Coal Fires, Elsevier, 786 pp.

Internet Links for PertlikiteHide

Localities for PertlikiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • El Loa Province
      • Calama
        • Cerritos Bayos
Samples analysed by Tony Kampf (LAC Museum) and Dr. Jochen Schluter (Hamburg University), Germany.; Kampf, A.R.; Mills, S.J.; Housley, R.M.; Williams, P.A.; Dini, M. (2012): Alcaparrosaite, K3Ti4+Fe3+(SO4)4O(H2O)2, a new hydrophobic Ti4+ sulfate from Alcaparrosa, Chile. Mineralogical Magazine 76, 851-861.
Costa Rica
 
  • Alajuela Province
Rodríguez, A., & van Bergen, M. J. (2017). Superficial alteration mineralogy in active volcanic systems: An example of Poás volcano, Costa Rica. Journal of Volcanology and Geothermal Research, 346, 54-80.
Hungary
 
  • Baranya County
    • Pécs
Collectors: Gábor Koller & Dávid Szabó, EDS: Zsolt Bendő, XRD: Sándor Szakáll
Iran (TL)
 
  • Hormozgan Province
    • Bandar-Abbas County
      • Bandar Abbas (Bandar-e Abbas)
        • Haji Abad town
Ertl, A.; Dyar, M.D.; Hughes, J.M.; Brandstätter, F.; Gunter, M.E.; Prem, M.; Peterson, R.C. (2008): Pertlikite, a new tetragonal Mg-rich member of the voltaite group from Madeni Zakh, Iran. Canadian Mineralogist, 46, 661-669.
Italy
 
  • Campania
    • Naples
      • Pozzuoli
- Russo, M., Campostrini, I., Demartin, F. (2017): I minerali di origine fumarolica dei Campi Flegrei: Solfatara di Pozzuoli (Napoli) e dintorni. Micro, 15, 122-192.
- Russo, M., Campostrini, I., Demartin, F. (2017): I minerali di origine fumarolica dei Campi Flegrei: Solfatara di Pozzuoli (Napoli) e dintorni. Micro, 15, 122-192.
  • Sicily
    • Messina Province
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
            • Porto Levante
              • Faraglioni di Levante (Grotte dei Faraglioni; Grotte del Faraglione; "Grotte de Faraglione")
                • Faraglione Nico (Faraglione Piccolo; Faragghiune Nicu)
Campostrini I. et al - Vulcano: ein aussergewohnlicher Fundpunkt von neuen und seltenen Mineralien - MineralienWelt 2010 - nr.3 - p.40-57
 
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