Rinkite-(Ce)
A valid IMA mineral species
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About Rinkite-(Ce)
Formula:
(Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2
Colour:
Yellowish-brown, yellow; brown
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
3.18 - 3.44
Crystal System:
Monoclinic
Member of:
Name:
Named as rinkite by Lorenzen (1884) for a mineral found in material collected by K.J.V. Steenstrup in the years 1874, 1876 and 1877 at Kangerdluarssuk area, Ilímaussaq complex, Greenland. The exact locality is not known. The name is in honor of Henrik Johannes Rink (26 August 1819 Copenhagen, Denmark - 15 December 1893 Christiania, Norway), at the time Director of the Royal Greenland Board of Trade.
Name was changed by IMA in 2016 from rinkite to rinkite-(Ce) (IMA 16-A). See Sokolova and Cámara 2017.
Name was changed by IMA in 2016 from rinkite to rinkite-(Ce) (IMA 16-A). See Sokolova and Cámara 2017.
See also Mosandrite-(Ce).
The crystal structure of rinkite was established by Galli and Alberti (1971). Some authors (Fleischer 1958, 1987; Sokolova & Cámara, 2008, etc.) have argued that rinkite is identical with mosandrite. However, reinvestigation of mosandrite by Bellezza et al. (2009) showed that mosandrite differs from rinkite in chemical composition, with low Ca, Na and F contents and a high amount of H2O.
The crystal structure of rinkite was established by Galli and Alberti (1971). Some authors (Fleischer 1958, 1987; Sokolova & Cámara, 2008, etc.) have argued that rinkite is identical with mosandrite. However, reinvestigation of mosandrite by Bellezza et al. (2009) showed that mosandrite differs from rinkite in chemical composition, with low Ca, Na and F contents and a high amount of H2O.
Visit gemdat.org for gemological information about Rinkite-(Ce).
Unique Identifiers
Mindat ID:
3422
Long-form identifier:
mindat:1:1:3422:3
GUID
(UUID V4):
(UUID V4):
459a28cb-c39c-470d-8bc5-582cd468b521
IMA Classification of Rinkite-(Ce)
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
(Ca3REE)Na(NaCa)Ti(Si2O7)2(OF)F2
Approval year:
2009
Approval history:
Redefined 2009, special procedure
2016: Name changed from rinkite to rinkite-(Ce) (IMA 16-A).
2016: Name changed from rinkite to rinkite-(Ce) (IMA 16-A).
Classification of Rinkite-(Ce)
9.00.20
9 : SILICATES (Germanates)
0 :
0 :
9 : SILICATES (Germanates)
0 :
0 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Rin-Ce | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Rinkite-(Ce)
Vitreous
Colour:
Yellowish-brown, yellow; brown
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Distinct on {100}.
Distinct on {100}.
Fracture:
Irregular/Uneven, Conchoidal
Density:
3.18 - 3.44 g/cm3 (Measured) 3.439(63) g/cm3 (Calculated)
Optical Data of Rinkite-(Ce)
Type:
Biaxial (+)
RI values:
nα = 1.665 nβ = 1.668 nγ = 1.681
2V:
Measured: 43° , Calculated: 52°
Max Birefringence:
δ = 0.016
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
strong
Optical Extinction:
X ∧ c = 3°.
Comments:
Absorption: Z > Y > X.
Chemistry of Rinkite-(Ce)
Mindat Formula:
(Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2
Common Impurities:
Zr,Th,Y,La,Fe,Mn,Mg,K,H2O
Crystallography of Rinkite-(Ce)
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 7.441 Å, b = 5.663 Å, c = 18.832 Å
β = 101.383°
β = 101.383°
Ratio:
a:b:c = 1.314 : 1 : 3.325
Unit Cell V:
777.94 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals prismatic along [001] and flattened on {100} with {hk0} faces strongly striated.
Twinning:
Lamellar, polysynthetic on {100}.
X-Ray Powder Diffraction
Image Loading
Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.071 Å | (100) |
2.702 Å | (70) |
2.945 Å | (40) |
2.798 Å | (40) |
1.853 Å | (30) |
3.581 Å | (25) |
2.024 Å | (25) |
Comments:
Ilímaussaq complex, Kujalleq, Greenland.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Rinkite-(Ce)
Place of Conservation of Type Material:
In the Natural History Museum of Denmark, University of Copenhagen.
Synonyms of Rinkite-(Ce)
Other Language Names for Rinkite-(Ce)
Relationship of Rinkite-(Ce) to other Species
Member of:
Other Members of this group:
Batievaite-(Y) | Y2Ca2Ti(Si2O7)2(OH)2(H2O)4 | Tric. 1 : P1 |
Fogoite-(Y) | Na3Ca2Y2Ti(Si2O7)2OF3 | Tric. 1 : P1 |
Götzenite | NaCa6Ti(Si2O7)2OF3 | Tric. 1 : P1 |
Grenmarite | Na4MnZr3(Si2O7)2O2F2 | Mon. 2/m : P2/b |
Hainite-(Y) | Na2Ca4(Y,REE)Ti(Si2O7)2OF3 | Tric. 1 : P1 |
Kochite | Na3Ca2MnZrTi(Si2O7)2OF3 | Tric. 1 : P1 |
Mosandrite-(Ce) | (Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2 | Mon. 2/m : P21/b |
Nacareniobsite-(Ce) | Na3Ca3(Ce,REE)Nb(Si2O7)2OF3 | Mon. 2/m : P21/b |
Nacareniobsite-(Y) | Na3Ca3YNb(Si2O7)2OF3 | Mon. 2/m : P21/b |
Rinkite-(Y) | Na2Ca4YTi(Si2O7)2OF3 | Mon. 2/m : P21/b |
Rosenbuschite | Na6Ca6Zr3Ti(Si2O7)4O2F6 | Tric. 1 : P1 |
Roumaite | (Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3 | Mon. m : Bb |
Seidozerite | Na4MnZr2Ti(Si2O7)2O2F2 | Mon. 2/m : P2/b |
Unnamed (Ca-deficient Mosandrite) | (Ca1.2REE0.9Th0.1Zn0.1Al0.1Na0.2K0.1)((H2O)2◻)(Ti,Nb)(Si2O7)2(OH,F,Cl)2(H2O)2 |
Structurally related to group(s):
Rinkite Group | AP2MH2MO4(Si2O7)2(XOM)2(XOA)2 |
Common Associates
Associated Minerals Based on Photo Data:
26 photos of Rinkite-(Ce) associated with Eudialyte | Na15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2 |
14 photos of Rinkite-(Ce) associated with Aegirine | NaFe3+Si2O6 |
11 photos of Rinkite-(Ce) associated with Arfvedsonite | [Na][Na2][Fe2+4Fe3+]Si8O22(OH)2 |
10 photos of Rinkite-(Ce) associated with Amphibole Supergroup | AB2C5((Si,Al,Ti)8O22)(OH,F,Cl,O)2 |
10 photos of Rinkite-(Ce) associated with Calcite | CaCO3 |
9 photos of Rinkite-(Ce) associated with Albite | Na(AlSi3O8) |
7 photos of Rinkite-(Ce) associated with Eudialyte Group | [N(1)N(2)N(3)N(4)N(5)]3[M(1.1)M(1.2)]3[M(2.1)M(2.2)M(2.3)]3-6[M(3)M(4)]Z3[Si24O72]Θ4X(1)X(2) |
6 photos of Rinkite-(Ce) associated with Nepheline | Na3K(Al4Si4O16) |
4 photos of Rinkite-(Ce) associated with Magnesio-arfvedsonite | {Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2 |
4 photos of Rinkite-(Ce) associated with Microcline | K(AlSi3O8) |
Related Minerals - Strunz-mindat Grouping
9.00. | Clino-ferri-holmquistite | ◻{Li2}{Mg3Fe3+2}(Si8O22)(OH)2 |
9.00. | Shkatulkalita | |
9.00. | Alflarsenite | NaCa2Be3Si4O13(OH) · 2H2O |
9.00. | Yegorovite | Na4[Si4O8(OH)4] · 7H2O |
9.00. | Ferroericssonite | BaFe2+2 Fe3+(Si2O7)O(OH) |
9.00. | Ferrisepiolite | (Fe3+,Fe2+,Mg)4((Si,Fe3+)6O15)(O,OH)2 · 6H2O |
9.00. | Zvyaginite | NaZnNb2Ti[Si2O7]20(OH,F)3(H2O)4 + (x < 1) |
9.00. | Burnettite | CaVAlSiO6 |
9.00. | Mendigite | Mn2Mn2MnCa(Si3O9)2 |
9.00. | Bridgmanite Subgroup | ABSiO3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Rinkite-(Ce)
mindat.org URL:
https://www.mindat.org/min-3422.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Rinkite-(Ce)
Reference List:
Lorenzen, Joh. (1884) XII. Untersuchung einiger Mineralien aus Kangerdluarsuk in Grönland. Zeitschrift für Kristallographie - Crystalline Materials, 9 (1) 243 doi:10.1524/zkri.1884.9.1.243
Galli, E., Alberti, A. (1971) The crystal structure of rinkite. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 27 (7) 1277-1284 doi:10.1107/s056774087100387x
Sokolova, E. (2006) From structure topology to chemical composition. I. Structural hierarchy and stereochemistry in titanium disilicate minerals. The Canadian Mineralogist, 44 (6) 1273-1330 doi:10.2113/gscanmin.44.6.1273
Sokolova, E., Cámara, F. (2008) From structure topology to chemical composition.VIII. Titanium silicates: the crystal chemistry of mosandrite from type locality of Låven (Skådön), Langesundsfjorden, Larvik, Vestfold, Norway. Mineralogical Magazine, 72 (4) 887-897 doi:10.1180/minmag.2008.072.4.887
Bellezza, M., Merlino, S., Perchiazzi, N. (2009) Mosandrite: structural and crystal-chemical relationships with rinkite. The Canadian Mineralogist, 47 (4) 897-908 doi:10.3749/canmin.47.4.897
Larsen, Alf Olav, Erambert, Muriel (2010) Mosandritt og rinkitt fra nefelinsyenitt-pegmatitter i Langesundsfjordområdet [Mosandrite and rinkite from nepheline-syenite pegmatittes in the Langesundsfjord area]. Norsk Bergverksmuseum Skrift, 43. 95-102
Cámara, F., Sokolova, E., Hawthorne, F. C. (2011) From structure topology to chemical composition. XII. Titanium silicates: the crystal chemistry of rinkite, Na2Ca4REETi(Si2O7)2OF3. Mineralogical Magazine, 75 (6) 2755-2774 doi:10.1180/minmag.2011.075.6.2755
Sokolova, E., Cámara, F. (2017) The seidozerite supergroup of TS-block minerals: nomenclature and classification, with change of the following names: rinkite to rinkite-(Ce), mosandrite to mosandrite-(Ce), hainite to hainite-(Y) and innelite-1T to innelite-1A. Mineralogical Magazine, 81 (6) 1457-1484 doi:10.1180/minmag.2017.081.010
Localities for Rinkite-(Ce)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Takhtarvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia