Archerite
A valid IMA mineral species
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About Archerite
Formula:
(K,NH4)(H2PO4)
Colour:
White
Lustre:
Sub-Vitreous, Waxy, Greasy
Hardness:
1 - 2
Specific Gravity:
2.23 (Calculated)
Crystal System:
Tetragonal
Name:
Named in 1977 by Peter Bridge for Michael Archer (25 March 1945, Sydney, Australia - ), professor of Biology, University of New South Wales, Australia. While a curator for the Queensland Museum, Archer discovered Petrogale cave and collected samples that would contain the new mineral.
Isostructural with:
This page provides mineralogical data about Archerite.
Unique Identifiers
Mindat ID:
315
Long-form identifier:
mindat:1:1:315:5
GUID
(UUID V4):
(UUID V4):
39474e01-2b3c-4998-9965-f32b6d28763e
IMA Classification of Archerite
Approved
IMA Formula:
H2K(PO4)
First published:
1977
Classification of Archerite
8.AD.15
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
D : With only large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
D : With only large cations
Dana 7th ed.:
37.1.4.2
37.1.4.2
37 : ANHYDROUS ACID PHOSPHATES, ARSENATES AND VANADATES
1 : Miscellaneous
37 : ANHYDROUS ACID PHOSPHATES, ARSENATES AND VANADATES
1 : Miscellaneous
19.1.7
19 : Phosphates
1 : Phosphates of the alkali metals
19 : Phosphates
1 : Phosphates of the alkali metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Aht | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Archerite
Sub-Vitreous, Waxy, Greasy
Transparency:
Translucent
Colour:
White
Streak:
White
Hardness:
1 - 2 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
2.23 g/cm3 (Calculated)
Comment:
Ranges to 2.34
Optical Data of Archerite
Type:
Uniaxial (-)
RI values:
nω = 1.511 - 1.513 nε = 1.468 - 1.470
Birefringence:
0.041
Max Birefringence:
δ = 0.043
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Optical Extinction:
parallel
Chemistry of Archerite
Mindat Formula:
(K,NH4)(H2PO4)
Crystallography of Archerite
Crystal System:
Tetragonal
Class (H-M):
4 2m - Scalenohedral
Space Group:
I4 2d
Setting:
I4 2d
Cell Parameters:
a = 7.451 Å, c = 6.974 Å
Ratio:
a:c = 1 : 0.936
Unit Cell V:
387.18 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Prismatic crystals with pyramids.
Comment:
Ranges a 7.453, b 6.972
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0009154 | Archerite | Frazer B C, Pepinsky R (1953) X-ray analysis of the ferroelectric transition in KH2PO4 Acta Crystallographica 6 273-285 | 1953 | synthetic | 0 | 126 | |
0009155 | Archerite | Frazer B C, Pepinsky R (1953) X-ray analysis of the ferroelectric transition in KH2PO4 Acta Crystallographica 6 273-285 | 1953 | synthetic, low-temperature form | 0 | 116 | |
0017377 | Archerite | West J (1930) A quantitative X-ray analysis of the structure of potassium dihydrogen phosphate (KH2PO4) _cod_database_code 1010458 Zeitschrift fur Kristallographie 74 306-335 | 1930 | 0 | 293 | ||
0013164 | Archerite | Nelmes R J, Meyer G M, Tibballs J E (1982) The crystal structure of tetragonal KH2PO4 and KD2PO4 as a function of temperature Journal of Physics C: Solid State Physics 15 59-75 | 1982 | 0 | 293 | ||
0013165 | Archerite | Nelmes R J, Meyer G M, Tibballs J E (1982) The crystal structure of tetragonal KH2PO4 and KD2PO4 as a function of temperature Journal of Physics C: Solid State Physics 15 59-75 | 1982 | 0 | 293 | ||
0013166 | Archerite | Nelmes R J, Meyer G M, Tibballs J E (1982) The crystal structure of tetragonal KH2PO4 and KD2PO4 as a function of temperature Journal of Physics C: Solid State Physics 15 59-75 | 1982 | 0 | 293 | ||
0013167 | Archerite | Nelmes R J, Meyer G M, Tibballs J E (1982) The crystal structure of tetragonal KH2PO4 and KD2PO4 as a function of temperature Journal of Physics C: Solid State Physics 15 59-75 | 1982 | 0 | 293 | ||
0019080 | Archerite | Ono Y, Yamada N, Hikita T (1991) Structure refinements of the mixed crystal K0.78(NH4)0.22H2PO4 in the temperature range from 20 K to 250K Journal of the Physical Society of Japan 60 2673-2677 | 1991 | synthetic | 0 | 20 | |
0015150 | Archerite | Levy H A, Peterson S W, Simonsen S H (1954) Neutron diffraction study of the ferroelectric modification of potassium dihydrogen phosphate Physical Review 93 1120-1121 | 1954 | 0 | 113 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.09 Å | (10) |
3.72 Å | (100) |
3.01 Å | (10) |
2.91 Å | (80) |
2.64 Å | (20) |
2.34 Å | (10) |
1.982 Å | (10) |
1.953 Å | (50) |
Comments:
ICDD 35-807, also 20-203
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
52 : Guano- and urine-derived minerals | <0.4 |
Geological Setting:
Guano deposits
Type Occurrence of Archerite
General Appearance of Type Material:
Stalactites and wall and floor crusts. Crystals up to 2 mm in length.
Place of Conservation of Type Material:
Government Chemical Laboratories, Perth, Australia, MDC 5901.
Geological Setting of Type Material:
Guano deposit.
Associated Minerals at Type Locality:
Reference:
Bridge, P.J. (1977) Archerite, (K,NH4)H2PO4, a new mineral from Madura, Western Australia. Mineralogical Magazine: 41: 33-35.
Synonyms of Archerite
Other Language Names for Archerite
Common Associates
Associated Minerals Based on Photo Data:
2 photos of Archerite associated with Biphosphammite | NH4(H2PO4) |
Related Minerals - Strunz-mindat Grouping
8.AD. | Keplerite | Ca9(Ca0.5◻0.5)Mg(PO4)7 |
8.AD. | Deynekoite | Ca9◻Fe3+(PO4)7 |
8.AD. | Mazorite | Ba3(PO4)2 |
8.AD. | Monazite-(Gd) | Gd(PO4) |
8.AD.05 | Nahpoite | Na2(PO3OH) |
8.AD.10 | Monetite | Ca(PO3OH) |
8.AD.10 | Weilite | Ca(HAsO4) |
8.AD.10 | Švenekite | Ca(H2AsO4)2 |
8.AD.15 | Biphosphammite | NH4(H2PO4) |
8.AD.20 | Phosphammite | (NH4)2(PO3OH) |
8.AD.25 | Buchwaldite | NaCa(PO4) |
8.AD.30 | Schultenite | Pb(HAsO4) |
8.AD.35 | Chernovite-(Y) | Y(AsO4) |
8.AD.35 | Dreyerite | Bi(VO4) |
8.AD.35 | Wakefieldite-(Ce) | Ce(VO4) |
8.AD.35 | Wakefieldite-(Y) | Y(VO4) |
8.AD.35 | Xenotime-(Y) | Y(PO4) |
8.AD.35 | Chernovite-(Ce) | (Ce,Y)(AsO4) |
8.AD.35 | Pretulite | Sc(PO4) |
8.AD.35 | Xenotime-(Yb) | Yb(PO4) |
8.AD.35 | Wakefieldite-(La) | La(VO4) |
8.AD.35 | Wakefieldite-(Nd) | Nd(VO4) |
8.AD.35 | Xenotime-(Gd) | Gd(PO4) |
8.AD.40 | Pucherite | Bi(VO4) |
8.AD.45 | Ximengite | Bi(PO4) |
8.AD.50 | Gasparite-(Ce) | Ce(AsO4) |
8.AD.50 | Monazite-(Ce) | Ce(PO4) |
8.AD.50 | Monazite-(La) | La(PO4) |
8.AD.50 | Monazite-(Nd) | Nd(PO4) |
8.AD.50 | Rooseveltite | Bi(AsO4) |
8.AD.50 | Cheralite | CaTh(PO4)2 |
8.AD.50 | Monazite-(Sm) | Sm(PO4) |
8.AD.50 | UM2005-35-VO:CaFePSiTh | (Th,Ca)(VO4,SiO4,PO4) |
8.AD.50 | Gasparite-(La) | La(AsO4) |
8.AD.55 | Tetrarooseveltite | Bi(AsO4) |
8.AD.60 | Chursinite | [Hg2]2+Hg2+2[AsO4]2 |
8.AD.65 | Clinobisvanite | Bi(VO4) |
8.AD.70 | Gurimite | Ba3(VO4)2 |
8.AD.75 | Picaite | NaCa[AsO3OH][AsO2(OH)2] |
Other Information
Notes:
Soluble in cold water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Archerite
mindat.org URL:
https://www.mindat.org/min-315.html
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References for Archerite
Localities for Archerite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| R Bottrill collection |
Mineralogical Magazine 39 (1973) | |
| Bridge (1977) |
Bahamas | |
| Onac B.P. et al. (2009) |
Egypt | |
| Mahmoud et al. (2022) |
Namibia | |
| Martini (1994) +1 other reference |
Saudi Arabia | |
| Saudi Geological Survey Open-File ... +1 other reference |
United Arab Emirates | |
| Audra et al. (2017) |
Quick NavTopAbout ArcheriteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List
Petrogale Cave, Madura Roadhouse, Dundas Shire, Western Australia, Australia