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Palenzonaite

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About PalenzonaiteHide

08371840014949232581785.jpg
Prof. Andrea Palenzona
Formula:
(NaCa2)Mn2+2(VO4)3
Colour:
Dark red
Lustre:
Adamantine, Sub-Adamantine, Greasy
Hardness:
5 - 5½
Specific Gravity:
3.63
Crystal System:
Isometric
Name:
Named in 1987 in honor of Andrea Palenzona (b. 1935), professor of chemistry (and amateur mineralogist) at the University of Genoa, who discovered the mineral.
This page provides mineralogical data about Palenzonaite.


Classification of PalenzonaiteHide

Approved
Approval Year:
1986
8.AC.25

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.2.1.3
38.2.1.3

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
21.4.15

21 : Vanadates (and vanadates with arsenate or phosphate)
4 : Vanadates of U, Mn, Fe or Ni

Physical Properties of PalenzonaiteHide

Adamantine, Sub-Adamantine, Greasy
Transparency:
Transparent
Colour:
Dark red
Hardness:
5 - 5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
3.63 g/cm3 (Measured)    3.78 g/cm3 (Calculated)

Optical Data of PalenzonaiteHide

Type:
Isotropic
RI values:
n = 1.965
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Very High
Pleochroism:
Non-pleochroic

Chemical Properties of PalenzonaiteHide

Formula:
(NaCa2)Mn2+2(VO4)3

Crystallography of PalenzonaiteHide

Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Ia3d
Setting:
Ia3d
Cell Parameters:
a = 12.534 Å
Unit Cell V:
1,969.11 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Granular, trapezohedral crystals rare.
Comment:
NJMM 136(1987) structure.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019609PalenzonaiteNagashima M, Armbruster T (2012) Palenzonaite, berzeliite, and manganberzeliite:(As5+,V5+,Si4+)O4 tetrahedra in garnet structures Mineralogical Magazine 76 1081-10972012Molinello mine, Italy0293
0019610PalenzonaiteNagashima M, Armbruster T (2012) Palenzonaite, berzeliite, and manganberzeliite:(As5+,V5+,Si4+)O4 tetrahedra in garnet structures Mineralogical Magazine 76 1081-10972012Gambatesa mine, Italy0293
0019611PalenzonaiteNagashima M, Armbruster T (2012) Palenzonaite, berzeliite, and manganberzeliite:(As5+,V5+,Si4+)O4 tetrahedra in garnet structures Mineralogical Magazine 76 1081-10972012Fianel mine, Switzerland0293
0014813PalenzonaiteBasso R (1987) The crystal structure of palenzonaite, a new vanadate garnet from Val Graveglia (Northern Apennines, Italy) Neues Jahrbuch fur Mineralogie, Monatshefte 1987 136-1441987Val Graveglia, Northern Apennines, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.12 Å(10)
3.13 Å(60)
2.80 Å(100)
2.67 Å(20)
2.56 Å(60)
2.46 Å(10)
1.738 Å(20)
1.675 Å(40)

Type Occurrence of PalenzonaiteHide

Geological Setting of Type Material:
Veinlets in Manganese ore
Associated Minerals at Type Locality:

Synonyms of PalenzonaiteHide

Other Language Names for PalenzonaiteHide

Simplified Chinese:钒钙锰石
Spanish:Palenzonaita
Traditional Chinese:釩鈣錳石

Relationship of Palenzonaite to other SpeciesHide

Other Members of this group:
Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
Schäferite(NaCa2)Mg2(VO4)3Iso.

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Palenzonaite associated with CarpholiteMn2+Al2(Si2O6)(OH)4
1 photo of Palenzonaite associated with NambuliteLiMn2+4Si5O14(OH)

Related Minerals - Nickel-Strunz GroupingHide

8.AC.AngarfiteNaFe3+5(PO4)4(OH)4 · 4H2O Orth. 2 2 2 : C2 2 21
8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4Trig. 3m : R3c
8.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric. 1 : P1
8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 : P1
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon.
8.AC.10Arseniopleite(Ca,Na)NaMn2+(Mn2+,Mg,Fe2+)2(AsO4)3Mon. 2/m
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(◻,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3Mon.
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10YazganiteNaFe3+2(Mg,Mn2+)(AsO4)3 · H2OMon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaMn3+Mg(Al,Fe3+)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon.
8.AC.15Qingheiite-(Fe2+)Na2Fe2+MgAl(PO4)3Mon. 2/m : P21/m
8.AC.18ManitobaiteNa16Mn2+25Al8(PO4)30Mon. m : Pb
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso.
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.50ChladniiteNa3CaMg11(PO4)9Trig. 3 : R3
8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig. 3 : R3
8.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig.
8.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig. 3 : R3
8.AC.50Stornesite-(Y){(Y, Ca)}{Na62}{(Ca,Na)8}{(Mg,Fe2+)43}(PO4)36Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.55HarrisoniteCa(Fe2+,Mg)6(PO4)2(SiO4)2Trig.
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.70StanfielditeCa4Mg5(PO4)6Mon.
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Related Minerals - Dana Grouping (8th Ed.)Hide

38.2.1.1Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
38.2.1.2Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

21.4.1UvaniteU6+2V5+6O21 · 15H2O (?)Orth.
21.4.2Vanuranylite(H3O)2(UO2)2(VO4)2 · 4H2O
21.4.3StrelkiniteNa2(UO2)2(VO4)2 · 6H2OOrth.
21.4.4CarnotiteK2(UO2)2(VO4)2 · 3H2OMon. 2/m : P21/b
21.4.5Margaritasite(Cs,K,H3O)2(UO2)2(VO4)2 · H2OMon. 2/m : P21/b
21.4.6SengieriteCu2(UO2)2(VO4)2 · 6H2OMon. 2/m : P21/b
21.4.7MetatyuyamuniteCa(UO2)2(VO4)2 · 3H2OOrth. mmm (2/m 2/m 2/m)
21.4.8TyuyamuniteCa(UO2)2(VO4)2 · 5-8H2OOrth. mmm (2/m 2/m 2/m) : Pnna
21.4.9RauviteCa(UO2)2(V10O28) · 16H2O
21.4.10FrancevilliteBa(UO2)2(VO4)2 · 5H2OOrth.
21.4.11MetavanuraliteAl(UO2)2(VO4)2(OH) · 8H2OTric.
21.4.12VanuraliteAl(UO2)2(V2O8)(OH) · 11H2OMon.
21.4.13CurienitePb(UO2)2(VO4)2 · 5H2OOrth.
21.4.14FritzscheiteMn(UO2)2(PO4,VO4)2 · 10H2O (?)Tet.
21.4.16Santafeite(Na,Ca,Sr)12(Mn2+,Fe3+,Al,Mg)8Mn4+8(VO4)16(OH,O)20 · 8H2OOrth. mmm (2/m 2/m 2/m)
21.4.17PyrobelonitePbMn2+(VO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnma
21.4.18BrackebuschitePb2Mn3+(VO4)2(OH)Mon. 2/m : P21/m
21.4.19ČechitePbFe2+(VO4)(OH)Orth. mmm (2/m 2/m 2/m)
21.4.20HeyitePb5Fe2+2(VO4)2O4Mon.
21.4.21MounanaitePbFe3+2(VO4)2(OH,F)2Mon. 2/m : B2/m
21.4.22SchubneliteFe3+VO4 · H2OTric.
21.4.23FervaniteFe3+4V5+4O16 · 5H2OMon.
21.4.24KazakhstaniteFe3+5V4+3V5+12O39(OH)9 · 9H2OMon.
21.4.25Bokite(Al,Fe3+)1.3(V5+,V4+,Fe3+)8O20 · 7.4H2OMon.
21.4.26Rusakovite(Fe3+,Al)5(VO4,PO4)2(OH)9 · 3H2O
21.4.27KolovratiteNixZny(VO4)0.67(x+y) · nH2O

Fluorescence of PalenzonaiteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for PalenzonaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Palenzona, A. (1986): Palenzonaite, gamagarite ed haradaite - Val Graveglia, Liguria. Rivista Mineralogica Italiana, 1/1986, 13-16.
Basso, R. (1987): The crystal structure of palenzonaite, a new vanadate garnet from Val Graveglia (Northern Apennines, Italy). Neues Jahrbuch fuer Mineralogie Monatshefte, 1987, 136-144. [Abs. in American Mineralogist (1988): 73: 930.]
Nagashima, M. & Armbruster, T. (2012): Palenzonaite, berzeliite, and manganberzeliite: (As5+,V5+,Si4+)O4+ tetrahedra in garnet structures. Mineralogical Magazine, 76, 1081-1097.

Internet Links for PalenzonaiteHide

Localities for PalenzonaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Tyrol
    • Innsbruck-Land District
      • Obernberg am Brenner
Carinthia II 2020 Neue Mineralfunde LXIX 153-218.pdf http://forum.amiminerals.it/viewtopic.php?f=5&t=16381
Italy
 
  • Liguria
    • Genoa
      • Ne
G. Blass EDX (M.E. Ciriotti, 2007)
Palenzona A. (1986) - Palenzonaite, Gamagarite ed Haradaite, Val Graveglia, Liguria - Riv Min. It, Milano, n. 1, 1986 pp. 13-16 and [MinRec 32:355]
        • Reppia
          • Monte Copello
J. Brugger pers.comm. 2005
  • Piedmont
    • Cuneo Province
      • Bellino
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007): Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.; Piccoli, G.C., Vanini, F., Ciriotti, M.E., Marengo, A., Bittarello, E., Cámara, F., Kolitsch, U., Bracco, R., Balestra, C., Odicino, G., Brizio, P. (2020): Eggletonite e tamaite del Monte Maniglia, Bellino, Cuneo, Piemonte con aggiornamento sulla mineralogia locale. Micro, 18, 60-66.
      • Canosio
        • Vallone della Valletta
Bracco R. (2014) Sempre novità "estere". Segnalazioni in breve. Prie, 10, 48; Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., Marchesini, M. (2015) Arsenic-bearing new mineral species from Valletta mine, Maira Valley, Piedmont, Italy: II. Braccoite, NaMn2+5[Si5AsO17(OH)](OH), description and crystal structure. Mineralogical Magazine, 79, 171-189; Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., Massimi, F., Balestra, C., Bracco, R. (2017a) As-bearing new mineral species from Valletta mine, Maira Valley, Piedmont, Italy: III. Canosioite, Ba2Fe3+(AsO4)2(OH), description and crystal structure. Mineralogical Magazine, 81, 305–317.
Japan
 
  • Kagoshima Prefecture
    • Oshima District
      • Yamato village
Masutomi museum specimen (Kyoto)
Switzerland
 
  • Grisons
    • Viamala Region
      • Ferrera
        • Ausserferrera
Brugger, J., Berlepsch, P. (1996) Description and crystal structure of fianelite, Mn2V(V,As)O7.2H2O, a new mineral from Fianel, Val Ferrera, Graubünden, Switzerland. American Mineralogist: 81: 1270-1276.
Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 230; Lapis 36 (4) (2011), p. 14 (ad); Brugger, J. (1996): The Fe, Mn, (V, Sb, As, Be, W) deposits of Val Ferrera (Graubünden, Switzerland). Unpublished PhD Thesis, Univ. Basel. 188 p.; Brugger, J., Berlepsch, P. (1997) Johninnesite Na2(Mn)9(Mn,Mg)7(AsO4)2(Si6O17)2(OH)8: a new occurrence in Val Ferrera (Graubünden, Switzerland): Schweiz. Mineral. Petrogr. Mitt., 77, 449-455.
      • Rheinwald
        • Splügen
Roth, P. & Meisser, N. (2011): I minerali dell'Alpe Tanatz. Passo dello Spluga (Grigioni, Svizzera). Rivista Mineralogica Italiana, 2/2011, 90-99
 
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