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Osumilite

A valid IMA mineral species - grandfathered
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About OsumiliteHide

03867830014952087182958.jpg
Sakkabira from Sakurajima peninsula

Sakkabira, Kagoshima Prefecture, Japan
Formula:
K◻2Fe2+2Al3[Al2Si10O30]
some Na reported in the B site (dominated by ◻ in the end-member formula);
some Mg reported in the A site (dominated by Fe in the end-member formula)
Colour:
Black, dark blue, dark brown, pink, gray
Lustre:
Vitreous
Hardness:
5 - 6
Specific Gravity:
2.58 - 2.68
Crystal System:
Hexagonal
Member of:
Name:
Named in 1953 by Akiho Miyashiro for the Osumi Peninsula, Japan, on which the type locality is found.
Osumilite Group.

Difficult to distinguish from Osumilite-(Mg).

Compare 'UM1984-35-SiO:AlCaFeKMg'.


From Belakovskiy (2013), summarizing Chukanov et al. (2013):
"Chemical data for osumilite in original paper (Miyashiro 1956) show that it is Mg‑dominant. However this analysis shows the sum of cations Si+Al+Fe+Mg+Mn (for O = 30) is 0.78 more then the theoretical value. The study of osumilite type locality material (Armbruster and Oberhänsli 1988; abstracted paper) show the significant Fe2+ prevalence over Mg. Anyway, the name osumilite had been assigned by IMA CNMNC Fe2+-dominant osumilite."


Unique IdentifiersHide

Mindat ID:
3039
Long-form identifier:
mindat:1:1:3039:3
GUID
(UUID V4):
134ee8fe-98fe-4468-a169-e88e227da07b

IMA Classification of OsumiliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
KFe2(Al5Si10)O30
First published:
1953

Classification of OsumiliteHide

9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)
63.2.1a.6

63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)
16.24.16

16 : Silicates Containing Aluminum and other Metals
24 : Aluminosilicates of Fe, Mg, Ca and alkalis

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
OsmIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
OsuSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
OsmWhitney & Evans (2010)Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
OsmThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of OsumiliteHide

Vitreous
Transparency:
Transparent, Translucent
Colour:
Black, dark blue, dark brown, pink, gray
Comment:
Strongly pleochroic
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Indistinct, parallel and perpendicular {0001}
Density:
2.58 - 2.68 g/cm3 (Measured)    2.71 g/cm3 (Calculated)

Optical Data of OsumiliteHide

Type:
Uniaxial (+/-)
RI values:
nω = 1.539 - 1.547 nε = 1.545 - 1.551
2V:
Measured: 28° to 45°, Calculated: 0.0° to 0.0°
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Optical Extinction:
Nominally uniaxial(+/-), but may be anomalously biaxial (+/-) with a 2V° from 0 (so true uniaxial) up to ~45°.
Pleochroism:
Visible
Comments:
O = light blue to bluish purple, pale pink, pale yellow-brown; E = colorless to brown.
Comments:
Anomalously biaxial.

Chemistry of OsumiliteHide

Mindat Formula:
K◻2Fe2+2Al3[Al2Si10O30]

some Na reported in the B site (dominated by ◻ in the end-member formula);
some Mg reported in the A site (dominated by Fe in the end-member formula)
Common Impurities:
Ti,Mn,Ba,Na,Mg

Crystallography of OsumiliteHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:
P6/mcc
Setting:
P6/mcc
Cell Parameters:
a = 10.13(4) Å, c = 14.31(5) Å
Ratio:
a:c = 1 : 1.413
Unit Cell V:
1,271.71 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Hexagonal, tabular. Well developed {0001}, {1010}, {1120}. Also {2130}, {1011}, {1012}, {1122}.
Twinning:
Rarely, perpendicular to {0001}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000078OsumiliteMiyashiro A (1956) Osumilite, a new silicate mineral, and its crystal structure American Mineralogist 41 104-11619560293
0000188OsumiliteBrown G E, Gibbs G V (1969) Refinement of the crystal structure of osumilite American Mineralogist 54 101-11619690293
0001149OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001150OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001151OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001152OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001153OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001154OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites Japan-Hayasaki American Mineralogist 73 585-59419880293
0001155OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0001156OsumiliteArmbruster T, Oberhansli R (1988) Crystal chemistry of double-ring silicates: Structural, chemical, and optical variation in osumilites American Mineralogist 73 585-59419880293
0006584OsumiliteWinter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-28619950293
0006585OsumiliteWinter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-28619950293
0006586OsumiliteWinter W, Armbruster T, Lengauer C (1995) Crystal structure refinement of synthetic osumilite-type phases: BaMg2Al6Si9O30, SrMg2Al6Si9O30 and Mg2Al4Si11O30 European Journal of Mineralogy 7 277-28619950293
0007256OsumiliteSeryotkin Y V, Sokol E V, Bakakin V V, Likhacheva A Y (2008) Pyrometamorphic osumilite: occurrence, paragenesis, and crystal structure as compared to cordierite European Journal of Mineralogy 20 191-1982008South Urals, Russia0293
0007263OsumiliteBalassone G, Mormone A, Rossi M, Bernardi A, Fisch M, Armbruster T, Malsy K, Berger A (2008) Crystal chemical and structural characterization of an Mg-rich osumilite from Vesuvius volcano (Italy) European Journal of Mineralogy 20 713-7202008Vesuvius volcano, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.24 Å(very strong)
7.17 Å(strong)
5.08 Å(strong)
2.930 Å(strong)
4.41 Å(medium)
3.74 Å(medium)
2.776 Å(medium)
Comments:
Nearly identical to merrihueite.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)
10 : Basalt-hosted zeolite minerals
Stage 4a: Earth’s earliest continental crust>4.4-3.0
20 : Acidic volcanic rocks
Near-surface Processes
26 : Hadean detrital minerals
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)

Type Occurrence of OsumiliteHide

General Appearance of Type Material:
In crystals, a few millimeters or less in size, black to the unaided eye, and prismatic or tabular in habit. Previously mistaken for cordierite.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA, 104744.
Geological Setting of Type Material:
Biotite-bearing hypersthene-plagioliparite (rhyodacite).
Reference:
Miyashiro, A. (1953) Osumilite, a new mineral, and cordierite in volcanic rocks. Proceedings of the Japan Academy: 29(7): 321-323.

Synonyms of OsumiliteHide

Other Language Names for OsumiliteHide

Japanese:大隅石
Simplified Chinese:大隅石
Spanish:Osumilita

Relationship of Osumilite to other SpeciesHide

Member of:
Other Members of this group:
Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm (2/m 2/m 2/m) : Pnna
BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
KlöchiteK◻2(Fe2+Fe3+)Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
MerrihueiteK(◻Na)Fe2+2Fe2+3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6 m2 : P62c
ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
UM1990-73-SiO:KMnNaZnK(KNa0.50.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
Unnamed (Mn3+-dominant analog of Sugilite)KNa2Mn3+2Li3[Si12O30]
YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc

Common AssociatesHide

Associated Minerals Based on Photo Data:
30 photos of Osumilite associated with TridymiteSiO2
11 photos of Osumilite associated with HematiteFe2O3
9 photos of Osumilite associated with PhlogopiteKMg3(AlSi3O10)(OH)2
8 photos of Osumilite associated with PseudobrookiteFe2TiO5
6 photos of Osumilite associated with QuartzSiO2
6 photos of Osumilite associated with MulliteAl4+2xSi2-2xO10-x
3 photos of Osumilite associated with Cordierite(Mg,Fe)2Al3(AlSi5O18)
3 photos of Osumilite associated with SanidineK(AlSi3O8)
2 photos of Osumilite associated with MagnetiteFe2+Fe3+2O4
1 photo of Osumilite associated with Osumilite Group(XIIC)(IXB)2(VIA)2(IVT2)3[(IVT1)12O30]

Related Minerals - Strunz-mindat GroupingHide

9.CM.Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm (2/m 2/m 2/m) : Pnna
9.CM.05BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05MerrihueiteK(◻Na)Fe2+2Fe2+3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6 m2 : P62c
9.CM.05SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.CM.05Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05KlöchiteK◻2(Fe2+Fe3+)Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.CM.05FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05UM1990-73-SiO:KMnNaZnK(KNa0.50.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
9.CM.05LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.9.CM.AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.10FaizieviteK2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for OsumiliteHide

References for OsumiliteHide

Reference List:

Localities for OsumiliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Antarctica
 
  • Eastern Antarctica
Ellis et al. (1980) +1 other reference
      • Napier Complex
granulite-facies rocks of Casey Bay +1 other reference
Austria
 
  • Burgenland
    • Oberpullendorf District
      • Markt Sankt Martin
        • Pauliberg
U. Kolitsch et al. (2009)
Georgia
 
  • Mtskheta-Mtianeti
    • Kazbegi Municipality
      • Kel’ volcanic area
Станкевич Е.К. ...
Germany
 
  • Bavaria
    • Upper Palatinate
      • Tirschenreuth District
        • Kulmain
Weiß (1990)
  • Hesse
    • Giessen Region
      • Vogelsbergkreis
        • Mücke
          • Ober-Ohmen
Betz (2019)
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
Schreyer et al. (1983)
  • Saxony
    • Mittelsachsen
      • Waldheim
Borghini et al. (2023)
Hungary
 
  • Szabolcs-Szatmár-Bereg County
    • Tarpa
Koch: Minerals of Hungary
India
 
  • Andhra Pradesh
    • Visakhapatnam District
Divya Prakash et al. (2015)
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
        • Mount Vesuvius
Balassone et al. (2004)
Balassone et al. (2013)
  • Sardinia
    • Oristano Province
      • Marrubiu
Olsen et al. (1970) +3 other references
Japan
 
  • Kagoshima Prefecture
    • Kagoshima City
      • Sakurajima
- (mistaken locality attribution occasionally seen on labels because osumilite's type locality is nearby, but not on Sakurajima)
    • Kirishima City
      • Hayato
Kobayashi (1978)
Miyashiro (1953) +1 other reference
  • Tokyo Metropolis
    • Ōshima Subprefecture
photo in: Koubutsu Doshikai (2017)
  • Yamaguchi Prefecture
    • Yamaguchi City
      • Yoshiki
Miura (2011)
Madagascar
 
  • Anosy
    • Amboasary Sud District
      • Behara
Holder et al. (2018)
      • Mahaly
Holder et al. (2018)
Holder et al. (2018)
      • Tranomaro
Holder et al. (2018)
    • Taolagnaro District
      • Mandromodromotra
Holder et al. (2018)
Holder et al. (2018)
New Zealand
 
  • Waikato Region
    • Taupo District
      • Atiamuri
Personal collection of Rod Martin
Norway
 
  • Rogaland
    • Bjerkreim
      • Vikeså
Laurent (2016)
Russia
 
  • Chelyabinsk Oblast
Cesnokov et al. (1998)
[World of Stones 12:49]
Tajikistan
 
  • Districts of Republican Subordination
Belakowski (1991)
USA
 
  • Nevada
    • Pershing County
      • Seven Troughs Mining District
Walstrom (n.d.)
  • Oregon
    • Lane County
      • McKenzie Pass
        • North Sister Mountain
Olsen et al. (1970) +1 other reference
 
矿物 and/or 产地  
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