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Orthoserpierite

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About OrthoserpieriteHide

Formula:
Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1985 by Halil Sarp for being the orthorhombic polymorph of serpierite.
A species very hard to distinguish from devilline and bladed serpierite.


Classification of OrthoserpieriteHide

Approved
7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.6.7.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
25.5.8

25 : Sulphates
5 : Sulphates of Zn and Hg

Optical Data of OrthoserpieriteHide

Type:
Biaxial (-)
RI values:
nα = 1.586 nβ = 1.645 nγ = 1.650
2V:
Measured: 32° , Calculated: 30°
Max Birefringence:
δ = 0.064
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
small

Chemical Properties of OrthoserpieriteHide

Formula:
Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O
IMA Formula:
CaCu4(SO4)2(OH)6 · 3H2O

Crystallography of OrthoserpieriteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pca21
Cell Parameters:
a = 22.10(2) Å, b = 6.20(2) Å, c = 20.39(2) Å
Ratio:
a:b:c = 3.565 : 1 : 3.289
Unit Cell V:
2,793.84 ų (Calculated from Unit Cell)
Z:
8

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.21 Å(100)
5.10 Å(90)
3.400 Å(90)
3.184 Å(50)
2.610 Å(50)
2.558 Å(50)
2.384 Å(60)

Type Occurrence of OrthoserpieriteHide

Synonyms of OrthoserpieriteHide

Other Language Names for OrthoserpieriteHide

Relationship of Orthoserpierite to other SpeciesHide

Member of:
Other Members of this group:
Aldridgeite(Cd,Ca)(Cu,Zn)4(SO4)2(OH)6 · 3H2O Mon. 2/m : B2/b
CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon.
DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
KobyasheviteCu5(SO4)2(OH)6·4H2OTric. 1 : P1
LautenthalitePbCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
Structurally related to group(s):

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Orthoserpierite associated with TennantiteCu6(Cu4X2)As4S12S
5 photos of Orthoserpierite associated with PyriteFeS2
4 photos of Orthoserpierite associated with LinaritePbCu(SO4)(OH)2
4 photos of Orthoserpierite associated with AnglesitePbSO4
1 photo of Orthoserpierite associated with NamuwiteZn4(SO4)(OH)6 · 4H2O
1 photo of Orthoserpierite associated with SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2O
1 photo of Orthoserpierite associated with Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2O
1 photo of Orthoserpierite associated with BrochantiteCu4(SO4)(OH)6
1 photo of Orthoserpierite associated with GypsumCaSO4 · 2H2O

Related Minerals - Nickel-Strunz GroupingHide

7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon.
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon.
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2•6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75Nickelalumite(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2OMon.
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl·6H2OHex.
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

25.5.1ZinkositeZnSO4Orth.
25.5.2GoslariteZnSO4 · 7H2OOrth. 2 2 2 : P21 21 21
25.5.3NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
25.5.4KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon.
25.5.5Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
25.5.6Boyleite(Zn,Mg)SO4 · 4H2OMon. 2/m : P21/b
25.5.7SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
25.5.9ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
25.5.10Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
25.5.11GunningiteZnSO4 · H2OMon. 2/m : B2/b
25.5.12ChaidamuiteZnFe3+(SO4)2(OH) · 4H2OTric. 1 : P1
25.5.13Bianchite(Zn,Fe)SO4 · 6H2OMon. 2/m : P2/m
25.5.15Zincmelanterite(Zn,Cu,Fe)SO4 · 7H2OMon.
25.5.16Zincobotryogen(Zn,Mg,Mn2+)Fe3+(SO4)2(OH) · 7H2OMon. 2/m
25.5.17SchuetteiteHg2+3(SO4)O2Trig. 3 2 : P31 2 1
25.5.18Gianellaite[(NHg2)2](SO4)(H2O)xIso. 4 3m : F4 3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for OrthoserpieriteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Schweizerische mineralogische und petrographische Mitteilungen (1985): 65: 1-7.
American Mineralogist (1987): 72: 1026.
Ondruš, P. & Hyršl, J. (1989): New finds and revision of secondary minerals from Příbram district. Acta Universitatis Carolinae, Geologica 1989, 521-533. [PXRD data]
Krause, W. & Täuber, H. (1992): Zum Kenntnisstand der Minerale Serpierit, Orthoserpierit und Devillin. Aufschluss 43, 1-25. (in German)

Internet Links for OrthoserpieriteHide

Localities for OrthoserpieriteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • South Australia
    • Mt Lofty Ranges
      • South Mt Lofty Ranges (Adelaide Hills)
        • Chandlers Hill
Kolitsch, U. and Elliott, P. (1999): Mineralogy of the Mount Malvern Mine near Clarendon, South Australia. Australian J. Mineral. 5, 3-17.
Austria
 
  • Tyrol
    • Kufstein District
      • Brixlegg
        • Geyer - Silberberg District
          • Silberberg
Schnorrer, G. and Poeverlein, R. (2002) Schwaz-Brixlegg-Fundstellen: 2. Die Minerale des Stockerstollens bei Brixlegg in Tirol. Aufschluss, 53, 209-228.
            • West slope ("Am Geyer")
Der Aufschluß (2006)
Lapis 19(7/8):13-78 (1994); Schnorrer, G. & Poeverlein, R. (2008): Schwaz-Brixlegger Fundstellen. 6. Die Minerale des Gratlspitz bei Brixlegg in Tirol. Aufschluss 59, 7-28.
    • Schwaz District
      • Ringenwechsel District
        • Weißer Schrofen
Schnorrer, G., Poeverlein, R. (2007): Die Minerale des Martinstollens am Weißen Schrofen, Der Aufschluss, Vol. 58, 27-40
Chile
 
  • Atacama
    • Huasco Province
      • Vallenar
        • Sierra Bolsico area
maurizio dini - analysed with EDX, Pdf and microprobe (by dr. Jochen Scluter)
Czech Republic
 
  • Central Bohemian Region
    • Příbram District
      • Březové Hory ore region (Birkenberg)
        • Březové Hory deposit
Ondruš, P. & Hyršl, J. (1989): New finds and revision of secondary minerals from Příbram district. Acta Universitatis Carolinae, Geologica 1989, 521-533.
        • Černojamské deposit (Black pits deposit)
Ondruš, P. & Hyršl, J. (1989): New finds and revision of secondary minerals from Příbram district. Acta Universitatis Carolinae, Geologica 1989, 521-533.
RÜSENBERG, K. A. & PAULIŠ, P. (1996): Umbildungen und Neubildungen in den Schlackehalden der Blei- und Silberhütte von Příbram/ČR. Aufschluss 47, 267-287 (in German).
France (TL)
 
  • Auvergne-Rhône-Alpes
    • Rhône
      • Villefranche
        • Chessy-les-Mines
Schweiz.Min.Petr.Mitt.(1985) 65, 1-7
  • Corsica
    • Haute-Corse
      • Corte
        • Venaco
Lheur, C., Meisser,N., Pecorini, R. and Steinmetz, A. (2011): Nouveautés minéralogiques en Corse. La Régne Minéral. 102: 33-40
  • Grand Est
    • Haut-Rhin
      • Colmar-Ribeauvillé
        • Ste Marie-aux-Mines
          • Neuenberg
            • Sankt Jakob vein
Arliguie M collection
Germany
 
  • Lower Saxony
    • Goslar
      • Clausthal-Zellerfeld
        • Oberschulenberg
No reference listed
      • Grane Reservoir
No reference listed
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Meschede
Wittern: "Mineralfundorte in Deutschland", 2001
SCHNORRER, G. (1995): Mineralogische Neuheiten von bekannten deutschen Fundorten. Lapis 20 (12), 43-48; 62.
      • Siegen-Wittgenstein
        • Siegen
          • Niederschelden
Heinrich, M. & Reinhardt, M. (2011): Die Mineralien der Kobaltgrube "Alte Buntekuh" bei Niederschelden im Siegerland. Mineralien Welt. 22 (3): 14-27
  • Rhineland-Palatinate
    • Rhein-Lahn-Kreis
      • Bad Ems
        • Frücht
Möhn, G., Frohwein, J. & Blaß, G. (2009): Neue Mineralfunde von der Grube Friedrichssegen bei Bad Ems. Lapis 34 (5), 35-40; 58.
  • Saxony
    • Erzgebirgskreis
Lapis 30(7/8):78-80 (2005)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
No reference listed
No reference listed
          • Sounion area
            • Sounion Mines
Lapis, 24, 7/8 (1999)
Ireland
 
  • Connacht
    • Co. Galway
      • Killimor
Sarp, H.; Perroud, P.; DeHaller, A. (1987): Second occurrence of orthoserpierite in the Tynagh mine (Ireland). Arch. Sci. Genève, 40, 47-50. (in French)
  • Leinster
    • Co. Wicklow
      • Glendasan
XRD of specimens from nos. 3 & 4 levels by Dr Green, Manchester Museum.
Italy
 
  • Tuscany
    • Grosseto Province
      • Massa Marittima
Ciriotti, M.E., Blaß, G. (2010): Pot-pourri 2009: Identificazioni UKiS AMI, Minerali italiani di interesse. Micro, 1/2010, 124-127
Mexico
 
  • Durango
    • Mapimí Municipality
      • Bermejillo
Origlieri, unpub
Namibia
 
  • Oshikoto Region
    • Tsumeb
In the collection of Shields Flynn. Analyzed at the University of Arizona.
Portugal
 
  • Vila Real
    • Sabrosa
      • Souto Maior
Alves, P. (2017) The Mining District of Vale das Gatas, Sabrosa, Portugal. Mineral Up Vol. IV, nº5, 8-53.
Alves, P. (2017) The Mining District of Vale das Gatas, Sabrosa, Portugal. Mineral Up Vol. IV, nº5, 8-53.
Spain
 
  • Catalonia
    • Girona (Gerona)
      • Ripollès
        • Camprodon
          • Rocabruna
Joan Rosell
    • Tarragona
      • Priorat
        • Ulldemolins
Minerals as determined by analysis by the Dr Joan Vinals Barcelona
Switzerland
 
  • Valais
    • Anniviers Valley
      • Saint-Luc
Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
    • Martigny
      • Mont Chemin
UK
 
  • England
    • County Durham
      • Castleside
Norman Wilson Personal Collection
USA
 
  • Arizona
    • Pinal Co.
      • Galiuro Mts
        • Bunker Hill District (Copper Creek District)
T. Kennedy collection
            • Copper Creek
Shannon, David (1996) Orthoserpierite from the Copper Creek District, Pinal County, Arizona. Mineralogical Record: 27: 189-190. Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 7.
Mielke-Wilson
      • Mammoth Mining District
Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 7.
  • California
    • Inyo Co.
      • Inyo Mts (Inyo Range)
        • Malpais Mesa
In the collection of Brent Thorne. Specimens collected by Paul Adams and available at the 2017 Pacific Micromount conference.
    • San Bernardino Co.
      • Silver Lake Mining District
        • Soda Mts
          • Zzyzx (Fort Soda; Soda; Soda Springs; Zzyzx Mineral Spring Resort)
Housley R., pers. comm., 2018
  • Colorado
    • San Miguel Co.
      • Slick Rock Mining District
Kampf, A. R., Plášil, J., Nash, B. P., & Marty, J. (2019). Ammoniomathesiusite, a new uranyl sulfate–vanadate mineral from the Burro mine, San Miguel County, Colorado, USA. Mineralogical Magazine, 83(1), 115-121.
  • New Jersey
    • Sussex Co.
      • Franklin Mining District
        • Ogdensburg
          • Sterling Hill
Jenkins, R.E., II: The Picking Table:33(2):12-13 (1992); Dunn(1995):Pt5:639.
  • Utah
    • Piute Co.
      • Cottonwood Creek
        • Mount Baldy Mining District
Collected by and in the collection of Brent Thorne.
    • Tooele Co.
      • Oquirrh Mts
        • Ophir Mining District
          • Ophir
Rocks & Minerals 83:1 pp 52-62
          • Ophir Hill area
Rocks & Minerals 83:1 pp 52-62
 
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