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Nickelalumite

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About NickelalumiteHide

Formula:
(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2O
Specific Gravity:
2.231 (Calculated)
Crystal System:
Monoclinic
Chalcoalumite Group.

Originally reported from Mbobo Mkulu Cave, Nelspruit District, Mpumalanga Province, South Africa.


Classification of NickelalumiteHide

Notes:
Unnamed (probably valid)
Approval History:
Unnamed, but probably valid.
7.DD.75

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.3.1.2

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
3 : (AB)5(XO4)Zq·xH2O
13.13

13 : Nitrates

Physical Properties of NickelalumiteHide

Density:
2.231 g/cm3 (Calculated)

Optical Data of NickelalumiteHide

Type:
Biaxial
RI values:
nα = 1.532 nγ = 1.543
Max Birefringence:
δ = 0.011
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
medium

Chemical Properties of NickelalumiteHide

Formula:
(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2O

Crystallography of NickelalumiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 10.2567 Å, b = 8.8815 Å, c = 17.0989 Å
β = 95.548°
Ratio:
a:b:c = 1.155 : 1 : 1.925
Unit Cell V:
1550.3 ų

Other Language Names for NickelalumiteHide

Relationship of Nickelalumite to other SpeciesHide

Other Members of this group:
ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
Mbobomkulite(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 3H2OMon.

Related Minerals - Nickel-Strunz GroupingHide

7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon.
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon.
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2•6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl·6H2OHex.
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Related Minerals - Dana Grouping (8th Ed.)Hide

31.3.1.1ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

13.1NitratineNaNO3Trig. 3m (3 2/m) : R3c
13.2NiterKNO3Orth. mmm (2/m 2/m 2/m) : Pmma
13.3GerhardtiteCu2(NO3)(OH)3Orth. 2 2 2 : P21 21 21
13.4NitromagnesiteMg(NO3)2 · 6H2OMon. 2/m
13.5NitrocalciteCa(NO3)2 · 4H2OMon. 2/m
13.6NitrobariteBa(NO3)2Iso. m3 (2/m 3) : Pa3
13.7ButtgenbachiteCu19(NO3)2(OH)32Cl4 · 2H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
13.8SveiteKAl7(NO3)4(OH)16Cl2 · 8H2OMon.
13.9DarapskiteNa3(SO4)(NO3) · H2OMon. 2/m
13.10HumberstoniteNa7K3Mg2(SO4)6(NO3)2 · 6H2OTrig. 3 : R3
13.11Mbobomkulite(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 3H2OMon.
13.12Hydrombobomkulite(Ni,Cu)Al4((NO3)2,SO4)(OH)12 · 13-14H2OMon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for NickelalumiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Martini, J.E.J. (1980) Mbobomkulite, hydrombobomkulite, and nickelalumite, new minerals from Mbobo Mkulu cave, eastern Transvaal. Annals of the Geological Survey of South Africa: 14(2): 1-110 (see: American Mineralogist (1982): 67: 415-416).
American Mineralogist (1982): 67: 416.
Karpenko, V.V., Agakhanov, A.A., Pautov, L.A., Dikaya, T.V., and Bekenova, G.K. (2004b) New occurrence of nickelalumite on Kara-Chagyr, South Kirgizia. New Data on Minerals: 39: 32-39.
Uvarova, Y.A., Sokolova, E., Hawthorne, F.C., Karpenko, V.V., Agakhanov, A.A., and Pautov, L.A. (2005) The crystal chemistry of the "nickelalumite"-group minerals. Canadian Mineralogist: 43: 1511-1519.

Internet Links for NickelalumiteHide

Localities for NickelalumiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • West Coast municipality
      • Zeehan district
Bottrill (unpub); Bottrill, R.S. & Baker, W.E. (2008) A Catalogue of the Minerals of Tasmania. Bull. 73. Tasmanian Geological Survey
Kyrgyzstan
 
  • Batken Region
V.Y. Karpenko et al.: Zap. Vses. Mineral. Obshch. 133(2):59-68 (2004); New Data on Minerals: 39: 32-39.; Karpenko, V. Y., Pautov, L. A., Agakhanov, A. A., & Bekenova, G. K. (2011). Mannardite from vanadium-bearing schists of Kazakhstan and Central Asia. New Data on Minerals, 46, 25-33.
Canadian Mineralogist: 43: 1511-1519.; Atali A. Agakhanov et al (2005) New Data on Minerals Vol 40 pp23-28; Karpenko, V. Y., Pautov, L. A., Agakhanov, A. A., & Bekenova, G. K. (2011). Mannardite from vanadium-bearing schists of Kazakhstan and Central Asia. New Data on Minerals, 46, 25-33.
South Africa
 
  • Mpumalanga
    • Ehlanzeni District
      • Mbombela (Nelspruit)
Ann.Geol.Surv.S.Africa,(1980) 14, n2, 1-110;Martini, J.E.J. et al (1997), "Mbobo Mkulu Cave, South Africa", in "Cave Minerals of the World" (1997)
Switzerland
 
  • Valais
    • Goms
      • Obergoms
        • Oberwald
          • Furka pass area
            • Gletsch
Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): Mineralienlexikon der Schweiz. Wepf (Basel), p. 288.
 
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