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Natronambulite

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About NatronambuliteHide

Formula:
(Na,Li)(Mn,Ca)4Si5O14OH
Colour:
Pinkish orange
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
3.51
Crystal System:
Triclinic
Name:
Named for its relation to nambulite, with dominant sodium, NATRium in Latin.

Classification of NatronambuliteHide

Approved
First Published:
1985
9.DK.05

9 : SILICATES (Germanates)
D : Inosilicates
K : Inosilicates with 5-periodic single chains
65.4.1.5

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
4 : Single-Width Unbranched Chains, W=1 with chains P=5
14.18.2

14 : Silicates not Containing Aluminum
18 : Silicates of Mn and Na, K, Mg, Ca or Fe

Physical Properties of NatronambuliteHide

Vitreous
Colour:
Pinkish orange
Streak:
White
Hardness:
5½ - 6 on Mohs scale
Cleavage:
Perfect
[100] and [100] perfect
Density:
3.51 g/cm3 (Measured)    3.50 g/cm3 (Calculated)

Optical Data of NatronambuliteHide

Type:
Biaxial (+)
RI values:
nα = 1.706 nβ = 1.710 nγ = 1.730
2V:
Measured: 45° , Calculated: 50°
Max Birefringence:
δ = 0.024
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r > v weak

Chemical Properties of NatronambuliteHide

Formula:
(Na,Li)(Mn,Ca)4Si5O14OH
IMA Formula:
NaMn2+4Si5O14(OH)
Common Impurities:
Fe,Mg,Ca,H2O

Crystallography of NatronambuliteHide

Crystal System:
Triclinic
Cell Parameters:
a = 7.62 Å, b = 11.76 Å, c = 6.73 Å
α = 92.81°, β = 94.55°, γ = 106.87°
Ratio:
a:b:c = 0.648 : 1 : 0.572
Unit Cell V:
573.67 ų (Calculated from Unit Cell)
Comment:
Nagashima et al. (2014) give 7.6115(1), 11.7340(2), 6.7324(1) Å, 92.876(1), 94.846(1), 106.650(1)°, V = 572.28(2) Å3, for a sample from the Gozaisho mine.

Type Occurrence of NatronambuliteHide

Place of Conservation of Type Material:
Department of Geology, National Science Museum, Tokyo, Japan.
Geological Setting of Type Material:
contact metamorphosed bedded manganese ore deposits
Reference:
Matsubara, S., Kato, A., Tiba, T. (1985) Natronambulite, (Na,Li)(Mn,Ca)4Si5O14OH, a new mineral from the Tanohata mine, Iwate Prefecture, Japan. Mineralogical Journal: 12: 332-340.

Synonyms of NatronambuliteHide

Other Language Names for NatronambuliteHide

Relationship of Natronambulite to other SpeciesHide

Related Minerals - Nickel-Strunz GroupingHide

9.DK.05BabingtoniteCa2(Fe,Mn)FeSi5O14(OH)Tric. 1 : P1
9.DK.05LithiomarsturiteLiCa2Mn2Si5O14(OH)Tric.
9.DK.05ManganbabingtoniteCa2(Mn,Fe)FeSi5O14(OH)Tric.
9.DK.05MarsturiteNaCaMn3Si5O14(OH)Tric. 1 : P1
9.DK.05NambuliteLiMn2+4Si5O14(OH)Tric.
9.DK.05RhodoniteMn2+SiO3Tric. 1
9.DK.05ScandiobabingtoniteCa2(Fe2+,Mn)ScSi5O14(OH)Tric.
9.DK.05Fowlerite(Mn2+,Zn,Ca)SiO3
9.DK.10SantaclaraiteCaMn4[Si5O14OH](OH) · H2OTric.
9.DK.15SaneroiteNaMn2+5[Si5O14(OH)](VO3)(OH)Tric.
9.DK.20Hellandite-(Y)(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2Mon.
9.DK.20Tadzhikite-(Ce)Ca4Ce3+2Ti◻(B4Si4O22)(OH)2Mon.
9.DK.20Mottanaite-(Ce)Ca4(Ce,REE)Σ2Al(Be1.50.5)Σ2[B4Si4O22]O2Mon. 2/m
9.DK.20CiprianiiteCa4[(Th,U),Ca]Σ2Al(Be0.51.5)Σ2[B4Si4O22](OH)2Mon.
9.DK.20Hellandite-(Ce)(Ca,REE)4Ce2Al□2(B4Si4O22) (OH)2Mon. 2/m

Related Minerals - Dana Grouping (8th Ed.)Hide

65.4.1.1RhodoniteMn2+SiO3Tric. 1
65.4.1.2BabingtoniteCa2(Fe,Mn)FeSi5O14(OH)Tric. 1 : P1
65.4.1.3ManganbabingtoniteCa2(Mn,Fe)FeSi5O14(OH)Tric.
65.4.1.4NambuliteLiMn2+4Si5O14(OH)Tric.
65.4.1.6MarsturiteNaCaMn3Si5O14(OH)Tric. 1 : P1
65.4.1.7LithiomarsturiteLiCa2Mn2Si5O14(OH)Tric.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

14.18.1NambuliteLiMn2+4Si5O14(OH)Tric.
14.18.3ZakharoviteNa4Mn5Si10O24(OH)6 · 6H2OTrig.
14.18.4NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
14.18.5ShafranovskiteNa3K2(Mn,Fe,Na)4[Si9(O,OH)27](OH)2 · nH2OTrig.
14.18.6AbswurmbachiteCuMn3+6(SiO4)O8Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
14.18.7Donpeacorite(Mn2+,Mg)Mg[SiO3]2Orth.
14.18.8KanoiteMn2+(Mg,Mn2+)Si2O6Mon. 2/m : P21/b
14.18.9CaryopiliteMn2+3Si2O5(OH)4Mon.
14.18.10Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
14.18.11Tirodite
14.18.12Manganhumite(Mn2+,Mg)7(SiO4)3(OH)2Orth.
14.18.13BustamiteCaMn2+(Si2O6)Tric. 1 : P1
14.18.14GlaucochroiteCaMn2+SiO4Orth. mmm (2/m 2/m 2/m)
14.18.15Truscottite(Ca,Mn)14Si24O58(OH)8 · 2H2OTrig.
14.18.16SantaclaraiteCaMn4[Si5O14OH](OH) · H2OTric.
14.18.17FerrobustamiteCaFe2+(Si2O6)Tric.
14.18.18JohannseniteCaMn2+Si2O6Mon. 2/m : B2/b
14.18.19NeltneriteCaMn3+6(SiO4)O8Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
14.18.20OrlymaniteCa4Mn3Si8O20(OH)6 · 2H2OHex.
14.18.21InesiteCa2(Mn,Fe)7Si10O28(OH)2 · 5H2OTric. 1 : P1
14.18.22OrientiteCa8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O Orth.
14.18.23RuiziteCa2Mn3+2[Si4O11(OH)2](OH)2·2H2OMon. 2
14.18.24BostwickiteCaMn6Si3O16 · 7H2OOrth.
14.18.25KittatinnyiteCa2Mn2Mn(SiO4)2(OH)4 · 9H2OHex.
14.18.26LithiomarsturiteLiCa2Mn2Si5O14(OH)Tric.
14.18.27SeranditeNaMn2+2Si3O8(OH)Tric. 1 : P1
14.18.28KvanefjelditeNa4(Ca,Mn)(Si3O7)2(OH)2Orth.
14.18.29MarsturiteNaCaMn3Si5O14(OH)Tric. 1 : P1
14.18.30RaiteNa4Mn2+3Ti0.25Si8O20(OH)2 · 10H2OOrth. 2 2 2 : C2 2 2
14.18.31Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
14.18.32Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2OOrth. mm2 : Ama2
14.18.33Deerite(Fe,Mn)6(Fe,Al)3[Si6O17]O3(OH)5Mon.
14.18.34Calderite(Mn2+,Ca)3(Fe3+,Al)2(SiO4)3Iso.
14.18.35PyroxmangiteMnSiO3Tric. 1
14.18.36Dannemorite☐{Mn2+2}{Fe2+5}(Si8O22)(OH)2
14.18.37Neotocite(Mn,Fe,Mg)SiO3 · H2OAmor.
14.18.38BabingtoniteCa2(Fe,Mn)FeSi5O14(OH)Tric. 1 : P1
14.18.39ManganbabingtoniteCa2(Mn,Fe)FeSi5O14(OH)Tric.
14.18.40ÖrebroiteMn2+3(Sb5+,Fe3+)(SiO4)(O,OH)3Hex.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for NatronambuliteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
American Mineralogist (1973): 58: 162.
Matsubara, S., Kato, A., Tiba, T. (1985) Natronambulite, (Na,Li)(Mn,Ca)4Si5O14OH, a new mineral from the Tanohata mine, Iwate Prefecture, Japan. Mineralogical Journal: 12: 332-340.
Hawthorne, F.C., Bladh, K.W., Burke, E.A.J., Grew, E.S., Langley, R.H., Puciewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E., Vanko, D.A. (1987) New mineral names. American Mineralogist: 72: 222-230.
American Mineralogist (1990): 75: 412.
Nagashima, M., Armbruster, T., Kolitsch, U., Pettke, T. (2014) The relation between Li <-> Na substitution and hydrogen bonding in five-periodic single-chain silicates nambulite and marsturite: A single-crystal X-ray study. American Mineralogist: 99: 1462–1470.

Internet Links for NatronambuliteHide

Localities for NatronambuliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Japan
 
  • Fukushima Prefecture
    • Iwaki City
Nagashima, M., Armbruster, T., Kolitsch, U. and Pettke, T. (2014): The relation between Li <-> Na substitution and hydrogen bonding in five-periodic single-chain silicates nambulite and marsturite: A single-crystal X-ray study. American Mineralogist 99, 1462–1470.
  • Iwate Prefecture
    • Shimohei District
      • Tanohata-mura
Mineral.Journ.Japan (1985) 12, 332-340
Nagase, Toshiro; Hori, Hidemichi; Kitamine, Mizuya; Nagashima, Mariko; Abduriyim, Ahmadjan; Kuribayashi, Takahiro (2012): Tanohataite, LiMn2Si3O8(OH): a new mineral from the Tanohata mine, Iwate Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 107, 149-154.
  • Kochi Prefecture
    • Nankoku city
Journal of Mineralogical and Petrological Sciences 103,400-406(2008)
  • Tochigi Prefecture
    • Kanuma City
Matsubara, S., Kato, A., Miyawaki, R., Komuro, Y. and Okada, Y. (2007) Natronambulite from the Dohnoiri mine, Kanuma City, Tochigi Prefecture, Japan. Bulletin of the National Museum of Natural Sciences, Ser. C. 33, 1-5.
Namibia
 
  • Otjozondjupa Region
    • Grootfontein
      • Kombat
von Knorring, O., T.G., Sahama, and R. Törnroos (1978) Second find of nambulite. Neues Jahrb. Mineral., Monatsh., 346-348.
Romania
 
Hirtopanu, P. (2006). One hundred minerals for one hundred years (dedicated to the Centennial of the Geological Institute of Romania). In 3rd Conference on Mineral Sciences in the Carpathians, Miskolc Hungary. Acta Mineralogica–Petrographica, Abstract series (Vol. 5, p. 86).
  • Suceava
    • Suceava district
      • Iacobeni (Jakobeny; Jacobeny; Jakabfalva)
http://minerals-of-the-carpathians.eu
Spain
 
  • Catalonia
    • Tarragona
      • Priorat
        • Bellmunt del Priorat
Joan Abella i Creus (2008): Minerals I Mines De La Conca De Bellmunt Del Priorat.
 
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