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Natanite

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About NataniteHide

00367040015153659695146.jpg
Natan I. Ginzburg
Formula:
Fe2+[Sn(OH)6]
Colour:
Greenish-brown
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
4.035 (Calculated)
Crystal System:
Isometric
Name:
Named in honor of Natan Il'ich Ginzburg (Натана (Анатолия) Ильича Гинзбурга) (1 March 1917, Petrograd, Russian Empire - 15 September 1984, Moscow, USSR), mineralogist and geologist at All-Union Research Institute of Mineral Resources, Moscow, Russia, who researched oxidized tin deposits.
Dimorph of:
The Fe analogue of schoenfliesite. Natanite and jeanbandyite are the only hydroxide minerals with dominant Fe and Sn. Compare 'UM1982-07-OH:FeSn'.


Classification of NataniteHide

Approved
Approval Year:
1980
4.FC.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
C : Hydroxides with OH, without H2O; corner-sharing octahedra
6.3.6.3

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
3 : X(OH)3
7.11.10

7 : Oxides and Hydroxides
11 : Oxides of Sn and Pb

Physical Properties of NataniteHide

Vitreous
Transparency:
Transparent
Colour:
Greenish-brown
Comment:
Semitransparent
Hardness:
Hardness:
VHN100=315 - Vickers
Comment:
H = 4.7
Density:
4.035 g/cm3 (Calculated)

Optical Data of NataniteHide

Type:
Isotropic
RI values:
n = 1.755
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
High
Colour in reflected light:
Dark gray

Chemical Properties of NataniteHide

Formula:
Fe2+[Sn(OH)6]
IMA Formula:
Fe2+Sn4+(OH)6

Crystallography of NataniteHide

Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Pn3m
Cell Parameters:
a = 7.69(1) Å
Unit Cell V:
454.76 ų (Calculated from Unit Cell)
Z:
4

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
1.710 Å(100)
3.729 Å(90)
1.563 Å(75)
2.709 Å(70)
2.221 Å(50)
1.031 Å(40)
1.920 Å(30)

Type Occurrence of NataniteHide

Synonyms of NataniteHide

Other Language Names for NataniteHide

German:Natanit
Simplified Chinese:铁锡石
Spanish:Natanita

Relationship of Natanite to other SpeciesHide

Other Members of this group:
BurtiteCa[Sn(OH)6]Iso.
JeanbandyiteFe3+xFe2+1-xSn(OH)6-xOx (1 >= x > 0.5)Tet. 4/m : P42/n
Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]Iso. m3m (4/m 3 2/m) : Pn3m
SchoenfliesiteMg[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
VismirnoviteZn[Sn(OH)6]Iso.
WickmaniteMn2+[Sn(OH)6]Iso. m3 (2/m 3) : Pn3

Common AssociatesHide

Associated Minerals Based on Photo Data:
9 photos of Natanite associated with IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)
2 photos of Natanite associated with VismirnoviteZn[Sn(OH)6]
1 photo of Natanite associated with ArsenopyriteFeAsS
1 photo of Natanite associated with TetrahedriteCu6(Cu4X2)Sb4S13
1 photo of Natanite associated with Varlamoffite(Sn,Fe)(O,OH)2
1 photo of Natanite associated with AmblygoniteLiAl(PO4)F
1 photo of Natanite associated with ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2O
1 photo of Natanite associated with Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]
1 photo of Natanite associated with QuartzSiO2
1 photo of Natanite associated with CassiteriteSnO2

Related Minerals - Nickel-Strunz GroupingHide

4.FC.05BernaliteFe(OH)3 · nH2O (n = 0.0 to 0.25)Orth. mmm (2/m 2/m 2/m) : Pmmn
4.FC.05DzhalinditeIn(OH)3Iso.
4.FC.05SöhngeiteGa(OH)3Tet.
4.FC.10BurtiteCa[Sn(OH)6]Iso.
4.FC.10Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]Iso. m3m (4/m 3 2/m) : Pn3m
4.FC.10SchoenfliesiteMg[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
4.FC.10VismirnoviteZn[Sn(OH)6]Iso.
4.FC.10WickmaniteMn2+[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
4.FC.15JeanbandyiteFe3+xFe2+1-xSn(OH)6-xOx (1 >= x > 0.5)Tet. 4/m : P42/n
4.FC.15MopungiteNa[Sb5+(OH)6]Tet. 4/m : P42/n
4.FC.15StottiteFe2+[Ge4+(OH)6]Tet.
4.FC.15TetrawickmaniteMn2+[Sn4+(OH)6]Tet. 4/m : P42/n
4.FC.20Ferronigerite-2N1S(Al,Fe,Zn)2(Al,Sn)6O11(OH)Trig. 3m (3 2/m) : P3m1
4.FC.20Magnesionigerite-6N6S(Mg,Al,Zn)3(Al,Sn,Fe)8O15(OH)Trig. 3m (3 2/m) : R3m
4.FC.20Magnesionigerite-2N1S(Mg,Al,Zn)2(Al,Sn)6O11(OH)Trig. 3m (3 2/m) : P3m1
4.FC.20Ferronigerite-6N6S(Al,Fe,Zn)3(Al,Sn,Fe)8O15(OH)Trig. 3m (3 2/m) : R3m
4.FC.20Zinconigerite-2N1S(Zn,Al,Mg)2(Al,Sn)6O11(OH)Trig. 3m (3 2/m) : P3m1
4.FC.20Zinconigerite-6N6S(Zn,Mg,Al)3(Al,Sn,Fe)8O15(OH)Trig. 3m (3 2/m) : R3m
4.FC.25Magnesiotaaffeite-6N’3SMg2BeAl6O12Trig.
4.FC.25Magnesiotaaffeite-2N’2SMg3Al8BeO16Hex. 6/mmm (6/m 2/m 2/m)

Related Minerals - Dana Grouping (8th Ed.)Hide

6.3.6.1WickmaniteMn2+[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
6.3.6.2SchoenfliesiteMg[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
6.3.6.4VismirnoviteZn[Sn(OH)6]Iso.
6.3.6.5BurtiteCa[Sn(OH)6]Iso.
6.3.6.6Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]Iso. m3m (4/m 3 2/m) : Pn3m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

7.11.1RomarchiteSnOTet.
7.11.2CassiteriteSnO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
7.11.4SchoenfliesiteMg[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
7.11.5BurtiteCa[Sn(OH)6]Iso.
7.11.6VismirnoviteZn[Sn(OH)6]Iso.
7.11.7WickmaniteMn2+[Sn(OH)6]Iso. m3 (2/m 3) : Pn3
7.11.8TetrawickmaniteMn2+[Sn4+(OH)6]Tet. 4/m : P42/n
7.11.9JeanbandyiteFe3+xFe2+1-xSn(OH)6-xOx (1 >= x > 0.5)Tet. 4/m : P42/n
7.11.11Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]Iso. m3m (4/m 3 2/m) : Pn3m
7.11.12Ferronigerite-2N1S(Al,Fe,Zn)2(Al,Sn)6O11(OH)Trig. 3m (3 2/m) : P3m1
7.11.13MagnesionigeriteTrig.
7.11.14ArgutiteGeO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
7.11.15BrunogeieriteGe4+Fe2+2O4Iso. m3m (4/m 3 2/m) : Fd3m
7.11.16StottiteFe2+[Ge4+(OH)6]Tet.
7.11.17CarboiriteFeAl2(GeO4)O(OH)2Tric.
7.11.18OtjisumeitePbGe4O9Tric.
7.11.19BartelkeitePb(Fe2+Ge)[Ge2O7](OH)2 · H2OMon. 2/m : P21/m
7.11.20MassicotPbOOrth. mmm (2/m 2/m 2/m) : Cmmm
7.11.21LithargePbOTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
7.11.22MiniumPb3O4Tet. 4/mmm (4/m 2/m 2/m) : P42/mbc
7.11.23PlattneritePbO2Tet. 4/mmm (4/m 2/m 2/m)
7.11.24Scrutinyiteα-PbO2Orth.
7.11.25MurdochitePbCu6O8-x(Cl,Br)2x where x<=0.5Iso. m3m (4/m 3 2/m) : Fm3m
7.11.26MacedonitePbTiO3Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm
7.11.27CesàrolitePb(Mn4+)3O6(OH)2
7.11.28CoronaditePb(Mn4+6Mn3+2)O16Mon. 2/m
7.11.29QuenselitePbMnO2(OH)Mon. 2/m : P2/b
7.11.30PlumboferritePb2(Fe3+,Mn2+,Mg)11O19Trig. 3 2 : P3 1 2
7.11.31Magnetoplumbite(Pb,Mn)(Fe,Mn)12O19Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
7.11.32SenaitePb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38Trig.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for NataniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Strunz, V.H., Contag, B. (1960) Hexahydroxostannate Fe, Mn, Co, Mg, Ca[Sn(OH)6] und deren kristallstruktur. Acta Crystallographica: 13: 601-603.
Christensen, A.N., Hazell, R.G. (1969) Hydrothermal preparation of hydroxy stannates. The crystal structure of MnSn(OH)6. Acta Chemica Scandinavica: 23: 1219-1224.
Marshukova, N.K., Palovskii, A.B., Sidorenko, G.A., Chistyakova, N.I. (1981) Vismirnovite, ZnSn(OH)6, and natanite, FeSn(OH)6, new tin minerals. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 110: 492–500 (in Russian).
Fleischer, M., Cabri, L.J., Chao, G.Y., Mandarino, J.A., Pabst, A. (1982) New mineral names. American Mineralogist: 67: 1074-1082.
Betterton, J., Green, D.I., Jewson, C., Spratt, J., Tandy, P. (1998) The composition and structure of jeanbandyite and natanite. Mineralogical Magazine: 62: 707-712.
Anthony, J.W., Bideaux, R.A., Bladh, K.W. and Nichols, M.C., Eds. Handbook of Mineralogy, Mineralogical Society of America, Chantilly, VA 20151-1110, USA. http://www.handbookofmineralogy.org/ (2016)
Welch, M.D., Kampf, A.R. (2017) Stoichiometric partially-protonated states in hydroxide perovskites: the jeanbandyite enigma revisited. Mineralogical Magazine: 81: 297-303.
Mitchell, R.H., Welch, M.D., Chakhmouradian, A.R. (2017) Nomenclature of the perovskite supergroup: A hierarchical system of classification based on crystal structure and composition. Mineralogical Magazine: 81: 411-461.

Internet Links for NataniteHide

Localities for NataniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Nepean
Calderwood, M.A., Grguric, B.A., Jacobson, M.I. (2007) Guidebook to the Pegmatites of Western Australia. Hesperian Press, Carlisle, Western Australia, 394 pages.
Bolivia
 
  • Potosí
    • Rafael Bustillo
      • Llallagua
Hyrsl, J. & A. Petrov (2006): Famous Mineral Localities: Llallagua, Bolivia. Mineralogical Record. 37: 117-162
France
 
  • Nouvelle-Aquitaine
    • Creuse
      • Soumans
        • Montebras
Patureau, J., Chiappero, P-J. & Lebocey, J. (2011): Mines et minéraux de Montebras, Soumans, Creuse. Le Règne Minéral. 99, 5-33 and Patrice Queneau Collection ( ex Varlamoffite , visual identification )
    • Haute-Vienne
      • Nantiat
        • Vaulry
          • Vaulry Mines
Patrice Queneau Collection
Kyrgyzstan (TL)
 
  • Issyk-Kul Region
    • Inyl'chek Range
ZVMO,(1981) 110, 492-500; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
  • Talas Region
    • Tallas Alatan
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Mexico
 
  • Chihuahua
    • Aquiles Serdán Municipality
      • Santa Eulalia Mining District
        • East Camp
http://rruff.geo.arizona.edu/doclib/hom/natanite.pdf.
        • West Camp
          • Francisco Portillo
Panczner (1987):94-366.
Russia
 
  • Magadan Oblast
    • Kolyma River Basin
      • Ducat District
        • Omsukchan
http://rruff.geo.arizona.edu/doclib/hom/natanite.pdf.
  • Primorsky Krai
    • Karadubsky ore field
N.V., Gorelikova analytical data
  • Sakha Republic (Yakutia)
    • Verkhoyansk District
      • Yana River Basin
        • Yana-Adycha Region
          • Arga-Ynnakh-Khaya granite Massif
Pavel M. Kartashov data
Tajikistan (TL)
 
  • Sughd
    • Zeravshan Range
      • Pendzhikent (Penjikent; Panjakent)
        • Kaznok Valley
ZVMO,(1981) 110, 492-500; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
UK
 
  • England
    • Cornwall
      • Calstock
        • Gunnislake
[C.Jewson, pers. comm.]; Weiss, S., Green, D.H., Hooper, J.J. & Elton, N. (2007): Erzgänge und "alpine " klüfte: Die Mineralien des Hingston Quarry, Calstock, Cornwall. LAPIS 32 (11), 13-25
      • Penzance
        • Newlyn
G. Curtis
G. Curtis collection (Uwe Kolitsch SXRD and EDS analyses)
      • St Hilary
Betterton, J. (2000) Famous Mineral Localities: Penberthy Croft Mine, St. Hilary, Cornwall, England. UK Journal of Mines & Minerals, 20, 7-37. Betterton, J., Green, D.I., Jewson, C., Spratt, J., Tandy, P. (1998) The composition and structure of jeanbandyite and natanite. Mineralogical Magazine, 62:5, 707-712.
 
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