Apatite Supergroup
A group of related mineral species
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About Apatite Supergroup
Formula:
M12 M23(TO4)3 X
M= Ca2+, Pb2+, Ba2+, Sr2+, Mn2+, Na+, Ce3+, La3+, Y3+, Bi3+
T= P5+, As5+, V5+, Si4+, S6+, B3+
X= F-, (OH)-, C l-,O2-
T= P5+, As5+, V5+, Si4+, S6+, B3+
X= F-, (OH)-, C l-,O2-
Crystal System:
Hexagonal
Name:
The supergroup has its name after the generic name apatite first introduced by the German mineralogist Abraham Gottlob Werner in 1786 (Gerards 1786). It is derived from the Greek ἀπατάω (apatao), to deceive, in allusion to apatite often being confused with other minerals (e.g., beryl, milarite).
A supergroup that includes minerals with a generic chemical formula IXM12VIIM23(IVTO4)3X (Z = 2). A large number of ions may occupy the key sites in the structure, and thus the possible number of distinct minerals is large. The members of the apatite supergroup characteristically show a wide range of substitutional solid solutions. The nomenclature of the apatite supergroup was approved by the IMA in 2010 (Pasero et al. 2010).
Note that the apatite supergroup is broader and includes more minerals than the historically used "apatite group". (The latter is not to be confused with the new approved subgroup of the apatite supergroup, also named the apatite group). It includes arsenate, vanadate, silicate, silicate-sulphate and sulphate minerals.
Based on both crystallographic and chemical criteria the apatite supergroup is divided into five groups: Apatite Group, Hedyphane Group, Belovite Group, Britholite Group and Ellestadite Group.
Bromine concentration in samples analyzed by Dong (2005) is of a trace level (e.g., 57 ppm). A single study (Broska et al., 2014) reports a possible trace-amount occurrence of CN- (cyanide) admixture in fluorapatite. Vanadium-rich members of the ellestadite group are observed in pyrometamorphic rocks formed in a burning coal-mining dump (Kruszewski, pers. obs.). A manganate(V) (MnO43-) substitution, likely induced by heat treatment, was determined in blue mastodon ivory (hydroxylapatite) bones (Chadefaux et al., 2009).
Note that the apatite supergroup is broader and includes more minerals than the historically used "apatite group". (The latter is not to be confused with the new approved subgroup of the apatite supergroup, also named the apatite group). It includes arsenate, vanadate, silicate, silicate-sulphate and sulphate minerals.
Based on both crystallographic and chemical criteria the apatite supergroup is divided into five groups: Apatite Group, Hedyphane Group, Belovite Group, Britholite Group and Ellestadite Group.
Bromine concentration in samples analyzed by Dong (2005) is of a trace level (e.g., 57 ppm). A single study (Broska et al., 2014) reports a possible trace-amount occurrence of CN- (cyanide) admixture in fluorapatite. Vanadium-rich members of the ellestadite group are observed in pyrometamorphic rocks formed in a burning coal-mining dump (Kruszewski, pers. obs.). A manganate(V) (MnO43-) substitution, likely induced by heat treatment, was determined in blue mastodon ivory (hydroxylapatite) bones (Chadefaux et al., 2009).
Unique Identifiers
Mindat ID:
274
Long-form identifier:
mindat:1:1:274:9
GUID
(UUID V4):
(UUID V4):
6dc61942-4df8-4aab-a04c-ecad22ef39c5
IMA Classification of Apatite Supergroup
IMA status notes:
IMA Approved Group Name
Chemistry of Apatite Supergroup
Mindat Formula:
M12 M23(TO4)3 X
M= Ca2+, Pb2+, Ba2+, Sr2+, Mn2+, Na+, Ce3+, La3+, Y3+, Bi3+
T= P5+, As5+, V5+, Si4+, S6+, B3+
X= F-, (OH)-, C l-,O2-
M= Ca2+, Pb2+, Ba2+, Sr2+, Mn2+, Na+, Ce3+, La3+, Y3+, Bi3+
T= P5+, As5+, V5+, Si4+, S6+, B3+
X= F-, (OH)-, C l-,O2-
Crystallography of Apatite Supergroup
Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Setting:
P63/m
Crystallographic forms of Apatite Supergroup
Crystal Atlas:
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0009691 | Alforsite | Hata M, Marumo F, Iwai S, Aoki H (1979) Structure of barium chlorapatite Acta Crystallographica B35 2382-2384 | 1979 | 0 | 293 | ||
0005690 | Belovite-(Ce) | Rakovan J F, Hughes J M (2000) Strontium in the apatite structure: Strontian fluorapatite and belovite-(Ce) The Canadian Mineralogist 38 839-845 | 2000 | 0 | 293 | ||
0011042 | Britholite-(Ce) | Noe D C, Hughes J M, Mariano A N, Drexler J W, Kato A (1993) The crystal structure of monoclinic britholite-(Ce) and britholite-(Y) Zeitschrift fur Kristallographie 206 233-246 | 1993 | the Kipawa syenite gneiss complex | 0 | 293 | |
0011043 | Britholite-(Ce) | Noe D C, Hughes J M, Mariano A N, Drexler J W, Kato A (1993) The crystal structure of monoclinic britholite-(Ce) and britholite-(Y) Zeitschrift fur Kristallographie 206 233-246 | 1993 | the Kipawa syenite gneiss complex | 0 | 293 | |
0011044 | Britholite-(Y) | Noe D C, Hughes J M, Mariano A N, Drexler J W, Kato A (1993) The crystal structure of monoclinic britholite-(Ce) and britholite-(Y) Zeitschrift fur Kristallographie 206 233-246 | 1993 | Suishoyama, Japan | 0 | 293 | |
0011045 | Britholite-(Y) | Noe D C, Hughes J M, Mariano A N, Drexler J W, Kato A (1993) The crystal structure of monoclinic britholite-(Ce) and britholite-(Y) Zeitschrift fur Kristallographie 206 233-246 | 1993 | Suishoyama, Japan | 0 | 293 | |
0014733 | Caracolite | Schneider W (1967) Caracolit, das Na3Pb2(SO4)3Cl mit apatitstruktur Neues Jahrbuch fur Mineralogie, Monatshefte 1967 284-289 | 1967 | 0 | 293 | ||
0014735 | Caracolite | Schneider W (1969) Bestimmung einer uberstruktur am caracolit Neues Jahrbuch fur Mineralogie, Monatshefte 1969 58-64 | 1969 | Caracoles, Chile | 0 | 293 | |
0002812 | Cesanite | Piotrowski A, Kahlenberg V, Fischer R X, Lee Y, Parise J B (2002) The crystal structures of cesanite and its synthetic analogue - A comparison American Mineralogist 87 715-720 | 2002 | 0 | 293 | ||
0002813 | Cesanite | Piotrowski A, Kahlenberg V, Fischer R X, Lee Y, Parise J B (2002) The crystal structures of cesanite and its synthetic analogue - A comparison American Mineralogist 87 715-720 | 2002 | 0 | 293 | ||
0014476 | Cesanite | Tazzoli V (1983) The crystal structure of cesanite, Ca1+xNa4-x(SO4)3(OH)x*(1-x)H2O, a sulphate isotypic of apatite Mineralogical Magazine 47 59-63 | 1983 | core samples of the Cesano I geothermal well, Cesano area, Latium, Italy | 0 | 293 | |
0001258 | Chlorapatite | Hughes J M, Cameron M, Crowley K D (1989) Structural variations in natural F, OH, and Cl apatites American Mineralogist 74 870-876 | 1989 | Kragero, Norway | 0 | 293 | |
0001291 | Chlorapatite | Hughes J M, Cameron M, Crowley K D (1990) Crystal structures of natural ternary apatites: Solid solution in the Ca5(PO4)3X (X = F,OH,Cl) system American Mineralogist 75 295-304 | 1990 | 0 | 293 | ||
0002516 | Chlorapatite | Fleet M E, Liu X, Pan Y (2000) Rare-earth elements in chlorapatite [Ca10(PO4)6(Cl)2]: Uptake, site preference, and degradation of monoclinic structure American Mineralogist 85 1437-1446 | 2000 | 0 | 293 | ||
0002517 | Chlorapatite | Fleet M E, Liu X, Pan Y (2000) Rare-earth elements in chlorapatite [Ca10(PO4)6(Cl)2]: Uptake, site preference, and degradation of monoclinic structure American Mineralogist 85 1437-1446 | 2000 | 0 | 293 | ||
0002518 | Chlorapatite | Fleet M E, Liu X, Pan Y (2000) Rare-earth elements in chlorapatite [Ca10(PO4)6(Cl)2]: Uptake, site preference, and degradation of monoclinic structure American Mineralogist 85 1437-1446 | 2000 | 0 | 293 | ||
0002519 | Chlorapatite | Fleet M E, Liu X, Pan Y (2000) Rare-earth elements in chlorapatite [Ca10(PO4)6(Cl)2]: Uptake, site preference, and degradation of monoclinic structure American Mineralogist 85 1437-1446 | 2000 | 0 | 293 | ||
0004838 | Chlorapatite | Luo Y, Hughes J M, Rakovan J, Pan Y (2009) Site preference of U and Th in Cl, F, and Sr apatites American Mineralogist 94 345-351 | 2009 | synthetic | 0 | 293 | |
0004840 | Chlorapatite | Luo Y, Hughes J M, Rakovan J, Pan Y (2009) Site preference of U and Th in Cl, F, and Sr apatites American Mineralogist 94 345-351 | 2009 | synthetic | 0 | 293 | |
0017642 | Chlorapatite | Hendricks S, Jefferson M, Mosley V (1932) The Crystal Structures of Some Natural and Synthetic Apatite-Like Substances _cod_database_code 1010916 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0015526 | Chlorellestadite | Saint-Jean S J, Hansen S (2005) Nonstoichiometry in chlorellestadite Solid State Sciences 7 97-102 | 2005 | synthetic | 0 | 293 | |
0015527 | Chlorellestadite | Saint-Jean S J, Hansen S (2005) Nonstoichiometry in chlorellestadite Solid State Sciences 7 97-102 | 2005 | synthetic | 0 | 293 | |
0001256 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1989) Structural variations in natural F, OH, and Cl apatites American Mineralogist 74 870-876 | 1989 | Durango Mexico | 0 | 293 | |
0001290 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1990) Crystal structures of natural ternary apatites: Solid solution in the Ca5(PO4)3X (X = F,OH,Cl) system American Mineralogist 75 295-304 | 1990 | 0 | 293 | ||
0001372 | Fluorapatite | Hughes J M, Cameron M, Mariano A N (1991) Rare-earth-element ordering and structural variations in natural rare-earth-bearing apatites sample from Pajarito, New Mexico American Mineralogist 76 1165-1173 | 1991 | 0 | 293 | ||
0001373 | Fluorapatite | Hughes J M, Cameron M, Mariano A N (1991) Rare-earth-element ordering and structural variations in natural rare-earth-bearing apatites sample from Kipawa, Quebec American Mineralogist 76 1165-1173 | 1991 | 0 | 293 | ||
0001374 | Fluorapatite | Hughes J M, Cameron M, Mariano A N (1991) Rare-earth-element ordering and structural variations in natural rare-earth-bearing apatites sample from the Oka carbonatite American Mineralogist 76 1165-1173 | 1991 | 0 | 293 | ||
0001421 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1991) Ordering of divalent cations in the apatite structure: Crystal structure refinements of natural Mn- and Sr-bearing apatite sample Sr.63 American Mineralogist 76 1857-1862 | 1991 | 0 | 293 | ||
0001422 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1991) Ordering of divalent cations in the apatite structure: Crystal structure refinements of natural Mn- and Sr-bearing apatite sample Sr.29 American Mineralogist 76 1857-1862 | 1991 | 0 | 293 | ||
0001423 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1991) Ordering of divalent cations in the apatite structure: Crystal structure refinements of natural Mn- and Sr-bearing apatite sample Mn1.21 American Mineralogist 76 1857-1862 | 1991 | 0 | 293 | ||
0001424 | Fluorapatite | Hughes J M, Cameron M, Crowley K D (1991) Ordering of divalent cations in the apatite structure: Crystal structure refinements of natural Mn- and Sr-bearing apatite sample Mn.42 American Mineralogist 76 1857-1862 | 1991 | 0 | 293 | ||
0001723 | Fluorapatite | Fleet M E, Pan Y (1995) Site preference of rare earth elements in fluorapatite American Mineralogist 80 329-335 | 1995 | 0 | 293 | ||
0001724 | Fluorapatite | Fleet M E, Pan Y (1995) Site preference of rare earth elements in fluorapatite American Mineralogist 80 329-335 | 1995 | 0 | 293 | ||
0001725 | Fluorapatite | Fleet M E, Pan Y (1995) Site preference of rare earth elements in fluorapatite American Mineralogist 80 329-335 | 1995 | 0 | 293 | ||
0001726 | Fluorapatite | Fleet M E, Pan Y (1995) Site preference of rare earth elements in fluorapatite American Mineralogist 80 329-335 | 1995 | 0 | 293 | ||
0001934 | Fluorapatite | Fleet M E, Pan Y (1997) Site preference of rare earth elements in fluorapatite: Binary (LREE+HREE)- substituted crystals American Mineralogist 82 870-877 | 1997 | 0 | 293 | ||
0001935 | Fluorapatite | Fleet M E, Pan Y (1997) Site preference of rare earth elements in fluorapatite: Binary (LREE+HREE)- substituted crystals American Mineralogist 82 870-877 | 1997 | 0 | 293 | ||
0001936 | Fluorapatite | Fleet M E, Pan Y (1997) Site preference of rare earth elements in fluorapatite: Binary (LREE+HREE)- substituted crystals American Mineralogist 82 870-877 | 1997 | 0 | 293 | ||
0001937 | Fluorapatite | Fleet M E, Pan Y (1997) Site preference of rare earth elements in fluorapatite: Binary (LREE+HREE)- substituted crystals American Mineralogist 82 870-877 | 1997 | 0 | 293 | ||
0003527 | Fluorapatite | Hughes J M, Ertl A, Bernhardt H J, Rossman G R, Rakovan J F (2004) Mn-rich fluorapatite from Autria: Crystal structure, chemical analysis, and spectroscopic investigations American Mineralogist 89 629-632 | 2004 | 0 | 293 | ||
0004514 | Fluorapatite | McCubbin F M, Mason H E, Park H, Phillips B L, Parise J B, Nekvasil H, Lindsley D H (2008) Synthesis and characterization of low-OH- fluor-chlorapatite: a single-crystal XRD and NMR spectroscopic study American Mineralogist 93 210-216 | 2008 | synthetic | 0 | 293 | |
0004637 | Fluorapatite | Fleet M E, Liu X (2008) Accommodation of the carbonate ion in fluorapatite synthesized at high pressure American Mineralogist 93 1460-1469 | 2008 | synthetic | 0 | 293 | |
0004638 | Fluorapatite | Fleet M E, Liu X (2008) Accommodation of the carbonate ion in fluorapatite synthesized at high pressure American Mineralogist 93 1460-1469 | 2008 | synthetic | 0 | 293 | |
0004639 | Fluorapatite | Fleet M E, Liu X (2008) Accommodation of the carbonate ion in fluorapatite synthesized at high pressure American Mineralogist 93 1460-1469 | 2008 | synthetic | 0 | 293 | |
0004837 | Fluorapatite | Luo Y, Hughes J M, Rakovan J, Pan Y (2009) Site preference of U and Th in Cl, F, and Sr apatites American Mineralogist 94 345-351 | 2009 | synthetic | 0 | 293 | |
0004839 | Fluorapatite | Luo Y, Hughes J M, Rakovan J, Pan Y (2009) Site preference of U and Th in Cl, F, and Sr apatites American Mineralogist 94 345-351 | 2009 | synthetic | 0 | 293 | |
0005688 | Fluorapatite | Rakovan J F, Hughes J M (2000) Strontium in the apatite structure: Strontian fluorapatite and belovite-(Ce) The Canadian Mineralogist 38 839-845 | 2000 | 0 | 293 | ||
0008534 | Fluorapatite | Comodi P, Liu Y, Zanazzi P F, Montagnoli M (2001) Structural and vibrational behaviour of fluorapatite with pressure. Part 1: in situ single-crystal X-ray diffraction investigation Physics and Chemistry of Minerals 28 219-224 | 2001 | 0.0001 | 293 | ||
0008535 | Fluorapatite | Comodi P, Liu Y, Zanazzi P F, Montagnoli M (2001) Structural and vibrational behaviour of fluorapatite with pressure. Part 1: in situ single-crystal X-ray diffraction investigation Physics and Chemistry of Minerals 28 219-224 | 2001 | 3.04 | 293 | ||
0008536 | Fluorapatite | Comodi P, Liu Y, Zanazzi P F, Montagnoli M (2001) Structural and vibrational behaviour of fluorapatite with pressure. Part 1: in situ single-crystal X-ray diffraction investigation Physics and Chemistry of Minerals 28 219-224 | 2001 | 4.72 | 293 | ||
0017946 | Fluorapatite | Naray-Szabo S (1930) The structure of apatite (Ca F) Ca4 (P O4)3 _cod_database_code 1011044 Zeitschrift fur Kristallographie 75 387-398 | 1930 | 0 | 293 | ||
0017911 | Fluorapatite | Hendricks S, Jefferson M, Mosley V (1932) The Crystal Structures of Some Natural and Synthetic Apatite-Like Substances _cod_database_code 1010996 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0017528 | Fluorapatite | Bale W (1940) A comparative Roentgen-ray diffraction study of several natural apatites and the apatite-like constituent of bone and tooth substance _cod_database_code 1010647 American Journal of Roentgenology 43 735-747 | 1940 | 0 | 293 | ||
0020482 | Fluorapatite | Hughes J M, Fransolet A M, Schreyer W (1993) The atomic arrangement of iron-bearing apatite Neues Jahrbuch fur Mineralogie, Monatshefte 1993 504-510 | 1993 | Northampton Block, Western Australia | 0 | 293 | |
0002669 | Fluorbritholite-(Ce) | Oberti R, Ottolini L, Della Ventura G, Parodi G C (2001) On the symmetry and crystal chemistry of britholite: New structural and microanalytical data American Mineralogist 86 1066-1075 | 2001 | 0 | 293 | ||
0002670 | Fluorbritholite-(Ce) | Oberti R, Ottolini L, Della Ventura G, Parodi G C (2001) On the symmetry and crystal chemistry of britholite: New structural and microanalytical data American Mineralogist 86 1066-1075 | 2001 | 0 | 293 | ||
0015322 | Fluorellestadite | Pajares I, De la Torre A G, Martinez-Ramirez S, Puertas F, Blanco-Varela M T, Aranda M A G (2002) Quantitative analysis of mineralized white Portland clinkers: The structure of fluorellestadite Powder Diffraction 17 281-286 | 2002 | synthetic | 0 | 293 | |
0000957 | Hedyphane | Rouse R C, Dunn P J, Peacor D R (1984) Hedyphane from Franklin, New Jersey and Langban, Sweden: Cation ordering in an arsenate apatite sample H90417 from Langban, Sweden American Mineralogist 69 920-927 | 1984 | 0 | 293 | ||
0004257 | Hydroxylellestadite | Onac B P, Effenberger H, Ettinger K, Panzaru S P (2006) Hydroxylellestadite from Cioclovina Cave (Romania): Microanalytical, structural, and vibrational spectroscopy data American Mineralogist 91 1927-1931 | 2006 | Cioclovina Cave, Sureanu Mountains, Romania | 0 | 293 | |
0014857 | Hydroxylellestadite | Hughes J M, Drexler J W (1991) Cation substitution in the apatite tetrahedral site: crystal structures of type hydroxylellestadtite and type fermorite Neues Jahrbuch fur Mineralogie, Monatshefte 1991 327-336 | 1991 | Crestmore, California, USA | 0 | 293 | |
0001257 | Hydroxylapatite | Hughes J M, Cameron M, Crowley K D (1989) Structural variations in natural F, OH, and Cl apatites American Mineralogist 74 870-876 | 1989 | Holly Springs, Georgia, USA | 0 | 293 | |
0001375 | Hydroxylapatite | Hughes J M, Cameron M, Mariano A N (1991) Rare-earth-element ordering and structural variations in natural rare-earth-bearing apatites sample B from the Oka carbonatite American Mineralogist 76 1165-1173 | 1991 | 0 | 293 | ||
0002281 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002282 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002283 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002284 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002285 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002286 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002287 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002288 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002289 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002290 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002291 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002292 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002293 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002294 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002295 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0002296 | Hydroxylapatite | Wilson R M, Elliot J C, Dowker S E P (1999) Rietveld refinement of the crystallographic structure of human dental enamel apatites American Mineralogist 84 1406-1414 | 1999 | 0 | 293 | ||
0003640 | Hydroxylapatite | Fleet M E, Liu X, King P L (2004) Accommodation of the carbonate ion in apatite: An FTIR and X-ray structure study of crystals synthesized at 2-4 GPa American Mineralogist 89 1422-1432 | 2004 | 0 | 293 | ||
0003641 | Hydroxylapatite | Fleet M E, Liu X, King P L (2004) Accommodation of the carbonate ion in apatite: An FTIR and X-ray structure study of crystals synthesized at 2-4 GPa American Mineralogist 89 1422-1432 | 2004 | 0 | 293 | ||
0004924 | Hydroxylapatite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0004925 | Hydroxylapatite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0004926 | Hydroxylapatite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0004927 | Hydroxylapatite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0009353 | Hydroxylapatite | Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite Acta Crystallographica B25 1534-1543 | 1969 | Holly Springs, Cherokee County, Georgia, USA | 0 | 293 | |
0009354 | Hydroxylapatite | Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite Acta Crystallographica B25 1534-1543 | 1969 | Holly Springs, Cherokee County, Georgia, USA | 0 | 293 | |
0009355 | Hydroxylapatite | Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite Acta Crystallographica B25 1534-1543 | 1969 | Holly Springs, Cherokee County, Georgia, USA | 0 | 293 | |
0009356 | Hydroxylapatite | Sudarsanan K, Young R A (1969) Significant precision in crystal structural details: Holly Springs hydroxyapatite Acta Crystallographica B25 1534-1543 | 1969 | Holly Springs, Cherokee County, Georgia, USA | 0 | 293 | |
0018108 | Hydroxylapatite | Hendricks S, Jefferson M, Mosley V (1932) The Crystal Structures of Some Natural and Synthetic Apatite-Like Substances _cod_database_code 1011242 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0004928 | Johnbaumite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0004929 | Johnbaumite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0004930 | Johnbaumite | Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution American Mineralogist 94 666-675 | 2009 | synthetic | 0 | 293 | |
0020732 | Johnbaumite | Biagioni C, Pasero M (2013) The crystal structure of johnbaumite, Ca5(AsO4)3OH, the arsenate analogue of hydroxylapatite American Mineralogist 98 1580-1584 | 2013 | Harstigen mine, Varmland, Sweden | 0 | 293 | |
0014546 | Mattheddleite | Steele I M, Pluth J J, Livingstone A (2000) Crystal structure of mattheddleite: a Pb, S, Si phase with the apatite structure Mineralogical Magazine 64 915-921 | 2000 | Leadhills, Scotland | 0 | 293 | |
0020250 | Mimetite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Pingtouling mine, Guangdong, China | 0 | 293 | |
0020251 | Mimetite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Pingtouling mine, Guangdong, China | 0 | 293 | |
0005264 | Mimetite | Yongshan D, Hughes J M, Moore P B (1991) The crystal structures of mimetite and clinomimetite, Pb5(AsO4)3Cl The Canadian Mineralogist 29 369-376 | 1991 | Durango, Mexico | 0 | 293 | |
0005265 | Mimetite | Yongshan D, Hughes J M, Moore P B (1991) The crystal structures of mimetite and clinomimetite, Pb5(AsO4)3Cl The Canadian Mineralogist 29 369-376 | 1991 | Johanngeorgenstat, Erzgebirge, Sachsen, Germany | 0 | 293 | |
0017912 | Mimetite | Hendricks S, Jefferson M, Mosley V (1932) The Crystal Structures of Some Natural and Synthetic Apatite-Like Substances _cod_database_code 1010997 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0020489 | Mimetite | Sokolova E V, Egorov-Tismenko Y K (1982) Study of crystalline structures of rare arsentates: duftite and mimetite Vestnik Moskovskogo Universiteta Geologiya 37 50-56 | 1982 | Cassiterite-sulfide field, Festivalnyi, East Siberia, Russia | 0 | 293 | |
0010345 | Morelandite | Dordevic T, Sutovic S, Stojanovic J, Karanovic L (2008) Sr, Ba and Cd arsenates with the apatite-type structure Acta Crystallographica C64 i82-i86 | 2008 | synthetic | 0 | 293 | |
0010488 | Morelandite | Bell A M T, Henderson C M B, Wendlandt R F, Harrison W J (2008) Rietveld refinement of Ba5(AsO4)3Cl from high-resolution synchrotron data Acta Crystallographica E64 i63-i64 | 2008 | synthetic | 0 | 293 | |
0020825 | Pyromorphite | Mills S J, Ferraris G, Kampf A R, Favreau G (2012) Twinning in pyromorphite: The first documented occurrence of twinning by merohedry in the apatite supergroup American Mineralogist 97 415-418 | 2012 | Puech de Compolibat, Combret, Aveyron | 0 | 293 | |
0020246 | Pyromorphite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Daoping mine, Guangxi, China | 0 | 293 | |
0020247 | Pyromorphite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Daoping mine, Guangxi, China | 0 | 293 | |
0005226 | Pyromorphite | Dai Y S, Hughes J M (1989) Crystal-structure refinements of vanadinite and pyromorphite The Canadian Mineralogist 27 189-192 | 1989 | 0 | 293 | ||
0018026 | Pyromorphite | Hendricks S, Jefferson M, Mosley V (1932) The crystal structures of some natural and synthetic apatite-like substances _cod_database_code 1011137 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0013570 | Pyromorphite | Miyake M, Ishigaki K, Suzuki T (1986) Structure refinements of Pb2+ ion-exchanged apatites by X-ray powder pattern-fitting Journal of Solid State Chemistry 61 230-235 | 1986 | synthetic | 0 | 293 | |
0013571 | Pyromorphite | Miyake M, Ishigaki K, Suzuki T (1986) Structure refinements of Pb2+ ion-exchanged apatites by X-ray powder pattern-fitting Journal of Solid State Chemistry 61 230-235 | 1986 | synthetic | 0 | 293 | |
0014055 | Fluorstrophite | Klevtsova R F (1964) The crystal structure of strontium-apatite Journal of Structural Chemistry 5 318-320 | 1964 | 0 | 293 | ||
0010311 | Turneaureite | Wardojo T A, Hwu S-J (1996) Chlorapatite: Ca5(AsO4)3Cl Acta Crystallographica C52 2959-2960 | 1996 | synthetic | 0 | 293 | |
0020248 | Vanadinite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Mibladen, Morocco | 0 | 293 | |
0020249 | Vanadinite | Okudera H (2013) Relationships among channel typology and atomic displacements in the structures of Pb5(BO4)3Cl with B = P (pyromorphite), V (vanadinite), and As (mimetite) American Mineralogist 98 1573-1579 | 2013 | Mibladen, Morocco | 0 | 293 | |
0005076 | Vanadinite | Trotter J, Barnes W H (1958) The structure of vanadinite The Canadian Mineralogist 6 161-173 | 1958 | 0 | 293 | ||
0005225 | Vanadinite | Dai Y S, Hughes J M (1989) Crystal-structure refinements of vanadinite and pyromorphite The Canadian Mineralogist 27 189-192 | 1989 | 0 | 293 | ||
0018027 | Vanadinite | Hendricks S, Jefferson M, Mosley V (1932) The Crystal Structures of Some Natural and Synthetic Apatite-Like Substances _cod_database_code 1011138 Zeitschrift fur Kristallographie 81 352-369 | 1932 | 0 | 293 | ||
0014110 | Vanadinite | Laufek F, Skala R, Haloda J, Cisarova I (2006) Crystal structure of vanadinite: refinement of anisotropic displacement parameters Journal of the Czech Geological Society 51 271-275 | 2006 | Mibladen, Morocco | 0 | 293 | |
0015622 | Belovite-(La) | Kabalov Y K, Sokolova E V, Pekov I V (1997) Crystal structure of belovite-(La) Soviet Physics Doklady 42 344-348 | 1997 | Mt. Kukisvumchorr, Khibiny alkaline massif, Kola Peninsula, Russia | 0 | 293 | |
0012350 | Deloneite | Rastsvetaeva R K, Khomyakov A P (1996) Structural features of a new naturally occurring representative of the fluorapatite-deloneite series Crystallography Reports 41 789-792 | 1996 | Khibini alkaline massif, Kola Peninsula, Russia | 0 | 293 | |
0012491 | Deloneite | Rastsvetaeva R F, Khomyakov A P (1996) Crystal structure of deloneite-(Ce), high ordered Ca analogue of belovite Doklady Akademii Nauk SSSR 349 354-357 | 1996 | 0 | 293 | ||
0006014 | Fluorcaphite | Chakhmouradian A R, Hughes J M, Rakovan J F (2005) Fluorcaphite, a second occurrence and detailed structural analysis: Simultaneous accommodation of Ca, Sr, Na, LREE in the apatite atomic arrangement The Canadian Mineralogist 43 735-746 | 2005 | 0 | 293 | ||
0006015 | Fluorcaphite | Chakhmouradian A R, Hughes J M, Rakovan J F (2005) Fluorcaphite, a second occurrence and detailed structural analysis: Simultaneous accommodation of Ca, Sr, Na, LREE in the apatite atomic arrangement The Canadian Mineralogist 43 735-746 | 2005 | 0 | 293 | ||
0005927 | Kuannersuite-(Ce) | Friis H, Balic-Zunic T, Pekov I V, Petersen O V (2004) Kuannersuite-(Ce), Ba6Na2REE2(PO4)6FCl, a new member of the apatite group, from the Ilimaussaq Alkaline Complex, South Greenland: Description and crystal chemistry The Canadian Mineralogist 42 95-106 | 2004 | Ilimaussaq Alkaline Complex, South Greenland | 0 | 293 | |
0004255 | Phosphohedyphane | Kampf A R, Steele I M, Jenkins R A (2006) Phosphohedyphane, Ca2Pb3(PO4)3Cl, the phosphate analogue of hedyphane: Description and crystal structure American Mineralogist 91 1909-1917 | 2006 | Capitana mine, Copiapo, Atacama Province, Chile | 0 | 293 | |
0004841 | Stronadelphite | Luo Y, Hughes J M, Rakovan J, Pan Y (2009) Site preference of U and Th in Cl, F, and Sr apatites American Mineralogist 94 345-351 | 2009 | synthetic | 0 | 293 | |
0017880 | Stronadelphite | Pekov I V, Britvin S N, Zubkova N V, Pushcharovsky D Y, Pasero M, Merlino S (2010) Stronadelphite, Sr5(PO4)3F, a new apatite-group mineral in the southern part of the Khibiny alkaline complex, Kola peninsula, Russia European Journal of Mineralogy 22 869-874 | 2010 | Belovitovoye pegmatite, Kirovskii apatite mine at Mt. Kukisvumchorr, | 0 | 293 | |
0005030 | Aiolosite | Demartin F, Gramaccioli C M, Campostrini I, Pilati T (2010) Aiolosite, Na2(Na2Bi)(SO4)3Cl, a new sulfate isotypic to apatite from La Fossa Crater, Vulcano, Aeolian Islands, Italy American Mineralogist 95 382-385 | 2010 | La Fossa Crater, Vulcano Island, Aeolian Archipelago, Sicily Italy | 0 | 293 | |
0018322 | Fluorphosphohedyphane | Kampf A R, Housley R M (2011) Fluorphosphohedyphane, Ca2Pb3(PO4)3F, the first apatite supergroup mineral with essential Pb and F American Mineralogist 96 423-429 | 2011 | Blue Bell claims, near Baker, San Bernardino County, California, USA | 0 | 293 | |
0013569 | Fluorphosphohedyphane | Miyake M, Ishigaki K, Suzuki T (1986) Structure refinements of Pb2+ ion-exchanged apatites by X-ray powder pattern-fitting Journal of Solid State Chemistry 61 230-235 | 1986 | synthetic | 0 | 293 | |
0018905 | Fluorbritholite-(Y) | Pekov I V, Zubkova N V, Chukanov N V, Husdal T A, Zadov A E, Pushcharovsky D Y (2011) Fluorbritholite-(Y), (Y,Ca,Ln)5[(Si,P)O4]3F, a new mineral of the britholite group Neues Jahrbuch fur Mineralogie, Abhandlungen 188 191-197 | 2011 | Lagmannsvik, Hamaroy, Nordland, Norway | 0 | 293 | |
0019705 | Carlgieseckeite-(Nd) | Pekov I V, Zubkova N V, Husdal T A, Kononkova N N, Agakhanov A A, Zadov A E, Pushcharovsky D Y (2012) Carlgieseckeite-(Nd), NaNdCa3(PO4)3F, a new belovite-group mineral species from the Ilimaussaq alkaline complex, South Greenland The Canadian Mineralogist 50 571-580 | 2012 | the Ilimaussaq alkaline complex, South Greenland | 0 | 293 | |
0020469 | Pieczkaite | Tait K, Ball N A, Hawthorne F C (2015) Pieczkaite, ideally Mn5(PO4)3Cl, a new apatite-supergroup mineral from Cross Lake, Manitoba, Canada: Description and crystal structure American Mineralogist 100 1047-1052 | 2015 | Cross Lake, Manitoba, Canada | 0 | 293 | |
0020231 | Pieczkaite | Engel G, Pretzsch J, Gramlich V, Baur W H (1975) The crystal structure of hydrothermally grown manganese chlorapatite, Mn5(PO4)3Cl0.9(OH)0.1 Acta Crystallographica B31 1854-1860 | 1975 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
Relationship of Apatite Supergroup to other Species
Group Members:
Apatite Group | ||
Alforsite | Ba5(PO4)3Cl | Hex. 6/m : P63/m |
Apatite | Ca5(PO4)3(Cl/F/OH) | |
Chlorapatite | Ca5(PO4)3Cl | Hex. 6/m : P63/m |
Fluoralforsite | Ba5(PO4)3F | Hex. 6/m : P6/m |
Fluorapatite | Ca5(PO4)3F | Hex. 6/m : P63/m |
Fluorpyromorphite | Pb5(PO4)3F | Hex. 6/m : P63/m |
Hydroxylapatite | Ca5(PO4)3(OH) | Hex. 6/m : P63/m |
Hydroxylpyromorphite | Pb5(PO4)3(OH) | Hex. 6/mmm (6/m 2/m 2/m) : P63/mcm |
Johnbaumite | Ca5(AsO4)3(OH) | Hex. 6/m : P63/m |
Mimetite | Pb5(AsO4)3Cl | Hex. 6/m : P63/m |
Oxypyromorphite | Pb10(PO4)6O | |
Pieczkaite | Mn5(PO4)3Cl | Hex. 6/m : P63/m |
Pliniusite | Ca5(VO4)3F | Hex. 6/m : P63/m |
Pyromorphite | Pb5(PO4)3Cl | Hex. 6/m : P63/m |
Stronadelphite | Sr5(PO4)3F | Hex. 6/m : P63/m |
Svabite | Ca5(AsO4)3F | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Turneaureite | Ca5(AsO4)3Cl | Hex. 6/m : P63/m |
Unnamed (OH-analogue of Mimetite) | Pb5(AsO4)3(OH) | Hex. 6/m : P63/m |
Vanadinite | Pb5(VO4)3Cl | Hex. 6/m : P63/m |
Belovite Group | ||
Belovite-(Ce) | NaCeSr3(PO4)3F | Trig. 3 : P3 |
Belovite-(La) | NaLaSr3(PO4)3F | Trig. 3 : P3 |
Carlgieseckeite-(Nd) | NaNdCa3(PO4)3F | Trig. 3 : P3 |
Deloneite | (Na0.5REE0.25Ca0.25)(Ca0.75REE0.25)Sr1.5(CaNa0.25REE0.25)(PO4)3F0.5(OH)0.5 | Trig. 3 : P3 |
Fluorcaphite | SrCaCa3(PO4)3F | Hex. 6/m : P63/m |
Fluorstrophite | SrCaSr3(PO4)3F | Hex. 6/m : P63/m |
Kuannersuite-(Ce) | NaCeBa3(PO4)3F0.5Cl0.5 | Trig. 3 : P3 |
Britholite Group | (REE,Ca)5[(Si,P)O4]3X | |
Britholite-(Ce) | (Ce,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
Britholite-(La) | Ca2(La,Ce,Ca)3(SiO4,PO4)3(OH,F) | |
Britholite-(Y) | (Y,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
Calciobritholite | (Ca,Y)5(SiO4,PO4)3(OH) | |
Fluorbritholite-(Ce) | (Ce,Ca)5(SiO4)3F | Hex. 6/m : P63/m |
Fluorbritholite-(Nd) | Ca2Nd3(SiO4)3F | Hex. 6/m : P63/m |
Fluorbritholite-(Y) | (Y,Ca)5(SiO4)3F | Hex. 6/m : P63/m |
Fluorcalciobritholite | (Ca,REE)5(SiO4,PO4)3F | Hex. 6/m : P63/m |
Tritomite-(Ce) | Ce5(SiO4,BO4)3(OH,O) | |
Tritomite-(Y) | Y5(SiO4,BO4)3(O,OH,F) | |
Ellestadite Group | ||
Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl | Hex. 6/m : P63/m |
Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F | Hex. 6/m : P63/m |
Hydroxylellestadite | Ca5(SiO4)1.5(SO4)1.5(OH) | Hex. 6/mmm (6/m 2/m 2/m) : P63/mcm |
Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) | Hex. 6/m : P63/m |
Hedyphane Group | ||
Aiolosite | Na4Bi(SO4)3Cl | Hex. 6/m : P63/m |
Caracolite | Na3Pb2(SO4)3Cl | Mon. 2/m : P21/m |
Cesanite | Na3Ca2(SO4)3(OH) | Hex. 6 : P6 |
Fluorphosphohedyphane | Ca2Pb3(PO4)3F | Hex. 6/m : P63/m |
Fluorsigaiite | Ca2Sr3(PO4)3F | Hex. 6/m : P63/m |
Hedyphane | Ca2Pb3(AsO4)3Cl | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Hydroxylhedyphane | Ca2Pb3(AsO4)3(OH) | Trig. 3 : P3 |
Miyahisaite | (Sr,Ca)2Ba3(PO4)3F | Hex. 6/m : P63/m |
Morelandite | Ca2Ba3(AsO4)3Cl | Hex. |
Parafiniukite | Ca2Mn3(PO4)3Cl | Hex. 6/m : P63/m |
Phosphohedyphane | Ca2Pb3(PO4)3Cl | Hex. 6/m : P63/m |
UM2002-53-PO:CaHPb | Ca2Pb3(PO4)3(OH,Cl,F) | |
Vanackerite | Pb4Cd(AsO4)3Cl | Trig. 3 : P3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Apatite Supergroup in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
- Igneous rock
- Sedimentary rock and sediment
- Metamorphic rock
- Meteorite and other extra-terrestrial rock and sediment
Internet Links for Apatite Supergroup
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References for Apatite Supergroup
Reference List:
Náray-Szabó (1930) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 75: 387.
McConnell, Duncan (1938) A structural investigation of the isomorphism of the apatite group. American Mineralogist, 23 (1) 1-19
Pasero, Marco, Kampf, Anthony R., Ferraris, Cristiano, Pekov, Igor V., Rakovan, John, White, Timothy J. (2010) Nomenclature of the apatite supergroup minerals. European Journal of Mineralogy, 22 (2) 163-179 doi:10.1127/0935-1221/2010/0022-2022
Broska, Igor, Krogh Ravna, Erling J., Vojtko, Peter, Janák, Marian, Konečný, Patrik, Pentrák, Martin, Bačík, Peter, Luptáková, Jarmila, Kullerud, Kåre (2014) Oriented inclusions in apatite in a post-UHP fluid-mediated regime (Tromsø Nappe, Norway) European Journal of Mineralogy, 26 (5) 623-634 doi:10.1127/0935-1221/2014/0026-2396
Ipirá complex, Bahia, Brazil