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Mereheadite

A valid IMA mineral species
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About MereheaditeHide

02046040014965073166079.jpg
Torr Works Quarry General View, July 2005

Torr Works Quarry, Cranmore, Mendip, Somerset, England, UK
Formula:
Pb47Cl25(OH)13O24(CO3)(BO3)2
Formula originally assumed to be Pb2O(OH)Cl.
Colour:
Pale yellow to reddish-orange
Lustre:
Vitreous, Resinous
Hardness:
Specific Gravity:
7.12
Crystal System:
Monoclinic
Name:
Named after Merehead quarry, Somerset, the source of this and other unusual lead secondary minerals.
Related to symesite.


Unique IdentifiersHide

Mindat ID:
2648
Long-form identifier:
mindat:1:1:2648:8
GUID
(UUID V4):
53ec3e74-441e-4f23-906e-faa554aa2f5a

IMA Classification of MereheaditeHide

Approved
IMA Formula:
Pb47O24(OH)13Cl25(BO3)2(CO3)
First published:
1998

Classification of MereheaditeHide

3.DC.45

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
MrhIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MereheaditeHide

Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Pale yellow to reddish-orange
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
(001)
Fracture:
Hackly, Conchoidal
Density:
7.12 g/cm3 (Measured)    7.31 g/cm3 (Calculated)

Optical Data of MereheaditeHide

Type:
Biaxial
RI values:
nα = 2.190 nγ = 2.280
Max Birefringence:
δ = 0.090
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
relatively strong
Reflectivity:
WavelengthR1R2
400nm17.20%17.95%
420nm16.50%17.40%
440nm15.90%16.90%
460nm15.50%16.50%
480nm15.10%16.10%
500nm14.90%15.80%
520nm14.50%15.50%
540nm14.30%15.30%
560nm14.10%15.20%
580nm14.00%15.00%
600nm13.90%14.90%
620nm13.80%14.80%
640nm13.80%14.80%
660nm13.70%14.70%
680nm13.60%14.65%
700nm13.60%14.60%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 17.95%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Gray
Internal Reflections:
Light yellow
Pleochroism:
Non-pleochroic

Chemistry of MereheaditeHide

Mindat Formula:
Pb47Cl25(OH)13O24(CO3)(BO3)2

Formula originally assumed to be Pb2O(OH)Cl.

Crystallography of MereheaditeHide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Cell Parameters:
a = 17.372(1) Å, b = 27.9419(19) Å, c = 10.6661(6) Å
β = 93.152(5)°
Ratio:
a:b:c = 0.622 : 1 : 0.382
Unit Cell V:
5169.6 ų
Comment:
SG Cm; originally reported cell (Welch et al., 1998): C2/c, 5.680, 5.565, 13.143 A, 90.64°.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014589MereheaditeKrivovichev S V, Turner R, Rumsey M, Sidra O I, Kirk C A (2009) The crystal structure and chemistry of mereheadite Mineralogical Magazine 73 103-1172009Merehead Quarry, Cranmore, Somerset, England0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.930 Å(100)
3.785 Å(48)
2.825 Å(43)
6.581 Å(37)
2.182 Å(37)
2.780 Å(36)
3.267 Å(35)
Comments:
Merehead Quarry, Somerset, England. Data from the type description.

Geological EnvironmentHide

Type Occurrence of MereheaditeHide

General Appearance of Type Material:
Polycrystalline aggregates, up to 10 x 30 mm, in which individual grains are anhedral and rarely exceed 2 mm.
Place of Conservation of Type Material:
Natural History Museum, London, England, specimen BM 1965,285 and polished mount E.1175.

Geological Setting of Type Material:
Lead bearing lenses and cavities in veins of manganese and iron oxide minerals that cut through a sequence of dolomitic limestone.
Associated Minerals at Type Locality:

Synonyms of MereheaditeHide

Other Language Names for MereheaditeHide

German:Mereheadit
Spanish:Mereheadita

Common AssociatesHide

Associated Minerals Based on Photo Data:
22 photos of Mereheadite associated with MendipitePb3Cl2O2
9 photos of Mereheadite associated with RickturneritePb7O4[Mg(OH)4](OH)Cl3
8 photos of Mereheadite associated with ChloroxiphitePb3CuO2Cl2(OH)2
7 photos of Mereheadite associated with CredneriteCuMnO2
3 photos of Mereheadite associated with ParalaurionitePbCl(OH)
3 photos of Mereheadite associated with SymesitePb10(SO4)O7Cl4 · H2O
3 photos of Mereheadite associated with PlumbonacritePb5O(OH)2(CO3)3
3 photos of Mereheadite associated with MimetitePb5(AsO4)3Cl
3 photos of Mereheadite associated with HydrocerussitePb3(CO3)2(OH)2
3 photos of Mereheadite associated with ParkinsonitePb7MoO9Cl2

Related Minerals - Strunz-mindat GroupingHide

3.DC.Lucabindiite(K,NH4)As4O6(Cl,Br)Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
3.DC.TorrecillasiteNa(As,Sb)3+4O6ClOrth.
3.DC.GajardoiteKCa0.5As3+4O6Cl2 · 5H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
3.DC.Cuatrocapaite-(NH₄)(NH4)3(NaMg◻)(As2O3)6Cl6 · 16H2OTrig. 3m (3 2/m) : R3m
3.DC.Cuatrocapaite-(K)K3(NaMg◻)(As2O3)6Cl6 · 16H2OTrig. 3m (3 2/m) : R3m
3.DC.NapoliitePb2OFClTet. 4/mmm (4/m 2/m 2/m) : P42/mcm
3.DC.05LaurionitePbCl(OH)Orth. mmm (2/m 2/m 2/m)
3.DC.05ParalaurionitePbCl(OH)Mon. 2/m : B2/m
3.DC.05Russoite(NH4)ClAs2O3(H2O)0.5Hex. 6 2 2 : P6 2 2
3.DC.05Mauriziodiniite(NH4)(As2O3)2IHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
3.DC.10FiedleritePb3FCl4(OH) · H2OMon. 2/m
3.DC.15PenfielditePb2Cl3(OH)Hex. 6 : P6
3.DC.15TelluroperitePb3TeO4Cl2Orth. mmm (2/m 2/m 2/m)
3.DC.20LaurelitePb7F12Cl2Hex. 6 : P6
3.DC.25BismocliteBiOClTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
3.DC.25MatlockitePbFClTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
3.DC.25RorisiteCaFClTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
3.DC.25Zavaritskite(BiO)FTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
3.DC.25ZhangpeishaniteBaFClTet. 4/mmm (4/m 2/m 2/m) : P4/nmm
3.DC.30NadoritePbSbClO2Orth. mmm (2/m 2/m 2/m) : Cmcm
3.DC.30PeritePbBiClO2Orth. mmm (2/m 2/m 2/m) : Cmcm
3.DC.40ThorikositePb3Cl2(OH)(SbO3,AsO3)Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.DC.50BlixitePb8O5(OH)2Cl4Orth.
3.DC.52RumseyitePb2OClF Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.DC.55PinalitePb3WO5Cl2Orth. mmm (2/m 2/m 2/m)
3.DC.55Vladkrivovichevite[Pb32O18][Pb4Mn2O]Cl14(BO3)8 · 2H2O Orth. mmm (2/m 2/m 2/m) : Pmmn
3.DC.57YeomanitePb2O(OH)ClOrth. mmm (2/m 2/m 2/m) : Pnma
3.DC.60LorettoitePb7O6Cl2Orth.
3.DC.60SymesitePb10(SO4)O7Cl4 · H2OTric. 1 : P1
3.DC.62Sarawakite (of Frenzel)Sb, O, Cl (?)
3.DC.65EcdemitePb6Cl4(As2O7)Mon. 2 : P21
3.DC.70MendipitePb3Cl2O2Orth. 2 2 2 : P21 21 21
3.DC.75DamaraitePb3Cl(OH)O2Orth. mm2 : Pmc21
3.DC.80OnoratoiteSb8Cl2O11Tric. 1 : P1
3.DC.95BarstowitePb4Cl6(CO3) · H2OMon. 2/m : P21/m

Fluorescence of MereheaditeHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MereheaditeHide

References for MereheaditeHide

Localities for MereheaditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • General Lamadrid Department
      • Villa Castelli
Grundmann et al. (2018)
  • Mendoza Province
    • Luján de Cuyo department
      • Cacheuta District
        • Sierra de Cacheuta
          • Cerro de Cacheuta
Grundmann et al. (2018)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Ortenaukreis
        • Oberwolfach
Walenta (1999) +1 other reference
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Brilon
Rouse et al. (1990) +1 other reference
UK
 
  • England
    • Bristol
      • Westbury on Trym
Day (1999)
    • Somerset
      • Mendip
        • Cranmore
Alabaster (1989) +7 other references
 
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