Cupromakovickyite

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Emil Makovicky

Formula:

Cu₄AgPb₂Bi₉S₁₈

Also given as Cu8Ag2Pb4Bi18S36 (doubled formula).

Colour:

grayish white

Lustre:

Metallic

Hardness:

4 - 4½

Specific Gravity:

6.78 (Calculated)

Crystal System:

Monoclinic

Member of:

Pavonite Homologous Series Group

Name:

For its chemical relation to makovickyite. The root name is for Emil Makovicky (18 August 1940, Bratislava, Slovakia – ), Slovak–Danish mineralogist, University of Copenhagen, Copenhagen, Denmark and sulphosalt specialist.

Type Locality:

ⓘ Western ore field, Mittersill Scheelite deposit, Mittersill, Zell am See District, Salzburg, Austria

Cu analogue of makovickyite.

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Classification of CupromakovickyiteHide

IMA status:

Approved

Approval year:

2002

First published:

2008

Strunz 8th ed.:

2/E.09-70

Nickel-Strunz 10th (pending) ed.:

2.JA.05d

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
A : Galena derivatives with little or no Pb

Physical Properties of CupromakovickyiteHide

Lustre:

Metallic

Colour:

grayish white

Hardness:

4 - 4½ on Mohs scale

Cleavage:

None Observed

Density:

6.78 g/cm³ (Calculated)

Chemical Properties of CupromakovickyiteHide

Formula:

Cu₄AgPb₂Bi₉S₁₈

Also given as Cu8Ag2Pb4Bi18S36 (doubled formula).

Elements listed:

Ag, Bi, Cu, Pb, S - search for minerals with similar chemistry

Crystallography of CupromakovickyiteHide

Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Space Group:

B2/m

Cell Parameters:

a = 13.405(8) Å, b = 4.016(3) Å, c = 29.949(19) Å
β = 99.989(16)°

Ratio:

a:b:c = 3.338 : 1 : 7.457

Unit Cell V:

1587.8 Å³

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0006187	Cupromakovickyite	Topa D, Makovicky E, Balic-Zunic T (2008) What is the reason for the doubled unit-cell volumes of copper-lead-rich pavonite homologues? The crystal structures of cupromakovickyite and makovickyite The Canadian Mineralogist 46 515-523		2008	Baita Bihor, Romania	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Cupromakovickyite'
loop_
_publ_author_name
'Topa D'
'Makovicky E'
'Balic-Zunic T'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 46 
_journal_year 2008
_journal_page_first 515
_journal_page_last 523
_publ_section_title
;
 What is the reason for the doubled unit-cell volumes of
 copper-lead-rich pavonite homologues? The crystal structures of
 cupromakovickyite and makovickyite
;
_database_code_amcsd 0006187
_chemical_compound_source 'Baita Bihor, Romania'
_chemical_formula_sum 'Bi4.48 Ag.52 Pb Cu2 S9'
_cell_length_a 13.405
_cell_length_b 4.016
_cell_length_c 29.949
_cell_angle_alpha 90
_cell_angle_beta 99.989
_cell_angle_gamma 90
_cell_volume 1587.848
_exptl_crystal_density_diffrn      6.757
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Bi1   0.34910   0.00000   0.46675   0.83400   0.02110
Ag1   0.34910   0.00000   0.46675   0.16600   0.02110
Bi2   0.44698   0.50000   0.09518   1.00000   0.01790
Bi3   0.64982   0.00000   0.03264   0.81200   0.02170
Ag3   0.64982   0.00000   0.03264   0.18800   0.02170
Bi4   0.55023   0.50000   0.40700   0.83400   0.02040
Ag4   0.55023   0.50000   0.40700   0.16600   0.02040
Bi5   0.23915   0.00000   0.19489   1.00000   0.02070
Pb   0.74078   0.00000   0.32562   1.00000   0.03170
Cu1  -0.01975   0.50000   0.21158   1.00000   0.03100
Cu2   0.45067   0.50000   0.27437   1.00000   0.02880
S1   0.50000   0.50000   0.00000   1.00000   0.02100
S2   0.40887   0.00000   0.38753   1.00000   0.01800
S3   0.29366   0.00000   0.06067   1.00000   0.02500
S4   0.20840   0.50000   0.43626   1.00000   0.02400
S5   0.59356   0.00000   0.11343   1.00000   0.01600
S6   0.50000   0.50000   0.50000   1.00000   0.02300
S7   0.14852   0.50000   0.23335   1.00000   0.01340
S8   0.40537   0.50000   0.17803   1.00000   0.01680
S9   0.36457   0.00000   0.27147   1.00000   0.01230
S10   0.59796   0.50000   0.32498   1.00000   0.01530
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Bi1 0.01870 0.02220 0.02180 0.00000 0.00200 0.00000
Ag1 0.01870 0.02220 0.02180 0.00000 0.00200 0.00000
Bi2 0.01970 0.02090 0.01330 0.00000 0.00330 0.00000
Bi3 0.01790 0.02150 0.02540 0.00000 0.00280 0.00000
Ag3 0.01790 0.02150 0.02540 0.00000 0.00280 0.00000
Bi4 0.02070 0.02320 0.01700 0.00000 0.00290 0.00000
Ag4 0.02070 0.02320 0.01700 0.00000 0.00290 0.00000
Bi5 0.01540 0.02660 0.01790 0.00000 -0.00290 0.00000
Pb 0.03540 0.02290 0.03930 0.00000 0.01310 0.00000
Cu1 0.01700 0.03300 0.04000 0.00000 -0.00500 0.00000
Cu2 0.02100 0.02200 0.04000 0.00000 -0.00600 0.00000
S1 0.02300 0.02300 0.01500 0.00000 -0.00040 0.00000
S2 0.01400 0.02000 0.01700 0.00000 -0.00090 0.00000
S3 0.02100 0.01900 0.03500 0.00000 0.00030 0.00000
S4 0.01300 0.01600 0.03800 0.00000 0.00500 0.00000
S5 0.01700 0.01300 0.01500 0.00000 -0.01100 0.00000
S6 0.02500 0.02100 0.01900 0.00000 -0.00300 0.00000
S7 0.00800 0.01700 0.01500 0.00000 0.00200 0.00000
S8 0.01900 0.01800 0.01520 0.00000 0.00800 0.00000
S9 0.01200 0.01500 0.01000 0.00000 0.00200 0.00000
S10 0.01300 0.01900 0.01500 0.00000 0.00400 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
3.478 Å	(100)
2.842 Å	(94)
3.646 Å	(57)
3.486 Å	(41)
3.345 Å	(33)
2.964 Å	(33)
2.282 Å	(31)

Type Occurrence of CupromakovickyiteHide

Type Locality:

ⓘ Western ore field, Mittersill Scheelite deposit, Mittersill, Zell am See District, Salzburg, Austria

General Appearance of Type Material:

minute segregation lamellae in makovickyite

Geological Setting of Type Material:

sulphosalt bearing quartz veins, hosted by paleozoic amphibolites, hornblendites and granite gneisses

Associated Minerals at Type Locality:

Wittichenite	Tetradymite	Makovickyite	Kupčíkite	Hodrušite
Emplectite	Cuprobismutite

Reference:

Topa, D., Paar, W.H. (2008) Cupromakovickyite, Cu8Pb4Ag2Bi18S36, a new mineral species of the pavonite homologous series. Canadian Mineralogist: 46: 503-514.

Synonyms of CupromakovickyiteHide

IMA2002-058

Other Language Names for CupromakovickyiteHide

German:Cupromakovickyit

Simplified Chinese:硫铋银铅铜矿

Relationship of Cupromakovickyite to other SpeciesHide

Member of:

Pavonite Homologous Series Group

Other Members of this group:

Benjaminite	Ag₃Bi₇S₁₂	Mon. 2/m : B2/m
Cupromakopavonite	Ag₃Cu₈Pb₄Bi₁₉S₃₈	Mon. 2/m : B2/m
Cupropavonite	Cu_0.9Ag_0.5Pb_0.6Bi_2.5S₅	Mon. 2/m : B2/m
Dantopaite	Ag₅Bi₁₃S₂₂	Mon. 2/m : B2/m
Luboržákite	Mn₂AsSbS₅	Mon. 2/m : B2/m
Makovickyite	Cu_1.12Ag_0.81Pb_0.27Bi_5.35S₉	Mon. 2/m
Mummeite	Cu_0.58Ag_3.11Pb_1.10Bi_6.65S₁₃	Mon.
Pavonite	AgBi₃S₅	Mon. 2/m : B2/m

Related Minerals - Nickel-Strunz Grouping Hide

2.JA.05e	Benjaminite	Ag₃Bi₇S₁₂	Mon. 2/m : B2/m
2.JA.05g	Borodaevite	Ag₅(Bi,Pb,Fe)₈(Sb,Bi)₂S₁₇	Mon.
2.JA.05a	Cupropavonite	Cu_0.9Ag_0.5Pb_0.6Bi_2.5S₅	Mon. 2/m : B2/m
2.JA.05a	Kitaibelite	Ag₁₀PbBi₃₀S₅₁
2.JA.05i	Livingstonite	HgSb₄S₆(S₂)	Mon. 2/m : B2/b
2.JA.05d	Makovickyite	Cu_1.12Ag_0.81Pb_0.27Bi_5.35S₉	Mon. 2/m
2.JA.05f	Mummeite	Cu_0.58Ag_3.11Pb_1.10Bi_6.65S₁₃	Mon.
2.JA.05a	Pavonite	AgBi₃S₅	Mon. 2/m : B2/m
2.JA.05b	Grumiplucite	HgBi₂S₄	Mon. 2/m : B2/m
2.JA.05h	Mozgovaite	PbBi₄S₇	Orth.
2.JA.05c	Kudriavite	(Cd,Pb)Bi₂S₄	Mon. 2/m : B2/m
2.JA.05a	Cupromakopavonite	Ag₃Cu₈Pb₄Bi₁₉S₃₈	Mon. 2/m : B2/m
2.JA.05	Dantopaite	Ag₅Bi₁₃S₂₂	Mon. 2/m : B2/m
2.JA.10a	Cuprobismutite	Cu₈AgBi₁₃S₂₄	Mon. 2/m : B2/m
2.JA.10c	Hodrušite	Cu₈Bi₁₂S₂₂	Mon. 2/m
2.JA.10e	Padĕraite	Cu₇[(Cu,Ag)_0.33Pb_1.33Bi_11.33]S₂₂	Mon.
2.JA.10d	Pizgrischite	(Cu,Fe)Cu₁₄PbBi₁₇S₃₅	Mon. 2/m : B2/m
2.JA.10b	Kupčíkite	Cu_3.4Fe_0.6Bi₅S₁₀	Mon. 2/m : B2/m
2.JA.15	Schapbachite	Ag_0.4Pb_0.2Bi_0.4S	Iso.
2.JA.15	Cuboargyrite	AgSbS₂	Iso. m3m (4/m 3 2/m)
2.JA.20	Bohdanowiczite	AgBiSe₂	Trig. 3m (3 2/m) : P3m1
2.JA.20	Matildite	AgBiS₂	Trig. 3m (3 2/m) : P3m1
2.JA.20	Volynskite	AgBiTe₂	Orth.

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for CupromakovickyiteHide

Reference List:

Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)

L. Zak et al.: N. Jb. Mineral. Abh. 168:147-169 (1994)

D. Topa et al.: Can. Mineral. 40:849-869 (2002)

D. Topa et al.: Can. Mineral. 41:1155-1166 (2003)

Lapis 29(5):42 (2004)

Topa, D., Paar, W.H. (2008) Cupromakovickyite, Cu8Pb4Ag2Bi18S36, a new mineral species of the pavonite homologous series. Canadian Mineralogist: 46: 503-514.

Topa, D., Makovicky, E., Balić-Žunić, T. (2008) What is the reason for the doubled unit-cell volumes of copper-lead-rich pavonite homologues? The crystal structures of cupromakovickyite and makovickyite. Canadian Mineralogist: 46: 515-523.

Internet Links for CupromakovickyiteHide

mindat.org URL:

https://www.mindat.org/min-26457.html
Please feel free to link to this page.

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External Links:

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Look for Cupromakovickyite on Wikipedia

Look for Cupromakovickyite on Mineralien Atlas

Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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Localities for CupromakovickyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.


Austria (TL)
Salzburg Zell am See District Mittersill Mittersill Scheelite deposit ⓘ Western ore field (TL)	D. Topa et al.: Can. Mineral. 40:849-869 (2002); D. Topa et al.: Can. Mineral. 41:1155-1166 (2003)

Japan
Yamagata Prefecture ⓘ Ohari mine (Obari mine)	Yuya Izumino, Kazuo Nakashima, Mariko Nagashima (2013) Makovickyite and cupromakovickyite from the Obari mine, Yamagata Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 108, #2 (April 2013), 94-100. ; Izumino, Y., Nakashima, K., & Nagashima, M. (2014). Cuprobismutite group minerals (cuprobismutite, hodrušhite, kupčíkite and padĕraite), other Bi–sulfosalts and Bi–tellurides from the Obari mine, Yamagata Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 109(4), 177-190.

Romania
Bihor Nucet ⓘ Băiţa mining district (Baita Bihor; Rézbánya)	L. Zak et al.: N. Jb. Mineral. Abh. 168:147-169 (1994)

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