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Zincolibethenite

A valid IMA mineral species
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About ZincolibetheniteHide

Formula:
CuZn(PO4)(OH)
Colour:
Bright green, bluish tint
Hardness:
Specific Gravity:
3.972 (Calculated)
Crystal System:
Orthorhombic
Member of:
Name:
Named for its relationship to libethenite.
Olivenite Group

Structurally distinct, intermediate member of the solid solution series between Libethenite and synthetic orthorhombic Zn2[OH|PO4] with a Zn:Cu ratio of (ideally) 1:1; Zn and Cu atoms are ordered on two different sites in the crystal structure.

Phosphate analogue of Zincolivenite.


Unique IdentifiersHide

Mindat ID:
25713
Long-form identifier:
mindat:1:1:25713:6
GUID
(UUID V4):
97c6e85f-4fe7-43ff-9c84-34867a766ae2

IMA Classification of ZincolibetheniteHide

Approved
Approval year:
2003
First published:
2005

Classification of ZincolibetheniteHide

8.BB.30

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
B : With only medium-sized cations, (OH, etc.):RO4 about 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
ZlibIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ZincolibetheniteHide

Transparency:
Transparent, Translucent
Colour:
Bright green, bluish tint
Hardness:
3½ on Mohs scale
Density:
3.972 g/cm3 (Calculated)

Optical Data of ZincolibetheniteHide

Type:
Biaxial (-)
RI values:
nα = 1.660 nβ = 1.705 nγ = 1.715
2V:
Calculated: 49°
Max Birefringence:
δ = 0.055
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r < v, medium
Pleochroism:
Non-pleochroic

Chemistry of ZincolibetheniteHide

Mindat Formula:
CuZn(PO4)(OH)

Crystallography of ZincolibetheniteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnnm
Cell Parameters:
a = 8.3263 Å, b = 8.2601 Å, c = 5.8771 Å
Ratio:
a:b:c = 1.008 : 1 : 0.712
Unit Cell V:
404.20 ų (Calculated from Unit Cell)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012060ZincolibetheniteWilliams P A, Leverett P, Birch W D, Hibbs D E, Kilitsch U, Mihajlovic T (2006) Zinc-rich zincolibethenite from Broken Hill, New South Wales Australian Journal of Mineralogy 12 3-72006Block 14 open cut, Broken Hill, New South Wales, Australia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.87 Å(39)
4.79 Å(100)
3.699 Å(22)
2.935 Å(33)
2.632 Å(47)
2.405 Å(19)
2.304 Å(18)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of ZincolibetheniteHide

General Appearance of Type Material:
Bright blue-green, transparent, prismatic crystals < 1 mm long, terminated by domes or prisms, in tightly packed sheaves and radiating clusters. Also as translucent, compact, radiating spherical clusters ~ 1 mm in diameter, along with aggregates of clusters in which individual crystals cannot be distinguished.
Place of Conservation of Type Material:
Parts of the type specimen are preserved at the Institut fur Mineralogie, Universitat Salzburg, Austria, and the Royal Scottish Museum. The polished section used for the microprobe analysis is at the Natural History Museum, London.
Associated Minerals at Type Locality:

Synonyms of ZincolibetheniteHide

Other Language Names for ZincolibetheniteHide

Simplified Chinese:羟磷铜锌石
Traditional Chinese:羥磷銅鋅石

Relationship of Zincolibethenite to other SpeciesHide

Member of:
Other Members of this group:
AdamiteZn2(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
EveiteMn2+2(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
LibetheniteCu2(PO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
Unnamed (Sb-analogue of Auriacusite)Fe3+Cu2+[(Sb,As)O4]O
ZincoliveniteCuZn(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm

Common AssociatesHide

Associated Minerals Based on Photo Data:
14 photos of Zincolibethenite associated with HemimorphiteZn4Si2O7(OH)2 · H2O
3 photos of Zincolibethenite associated with Kipushite(Cu,Zn)5Zn(PO4)2(OH)6 · H2O
3 photos of Zincolibethenite associated with Veszelyite(Cu,Zn)2Zn(PO4)(OH)3 · 2H2O
2 photos of Zincolibethenite associated with LibetheniteCu2(PO4)(OH)
1 photo of Zincolibethenite associated with QuartzSiO2
1 photo of Zincolibethenite associated with HerbertsmithiteCu3Zn(OH)6Cl2
1 photo of Zincolibethenite associated with SantabarbaraiteFe3+3(PO4)2(OH)3 · 5H2O
1 photo of Zincolibethenite associated with MixiteBiCu6(AsO4)3(OH)6 · 3H2O
1 photo of Zincolibethenite associated with HydrozinciteZn5(CO3)2(OH)6
1 photo of Zincolibethenite associated with HetaeroliteZnMn2O4

Related Minerals - Strunz-mindat GroupingHide

8.BB.TilasiteCaMg(AsO4)FMon.
8.BB.XArsenowagneriteMg2(AsO4)FMon. 2/m : P21/b
8.BB.MoabiteNiFe3+(PO4)OOrth. mmm (2/m 2/m 2/m) : Pnma
8.BB.KarlditmariteCu9O4(PO4)2(SO4)2Tric. 1 : P1
8.BB.MilkovoiteCu4O(PO4)(AsO4)Orth. mmm (2/m 2/m 2/m) : Pnma
8.BB.PaulgrothiteCu9Fe3+O4(PO4)4Cl3Orth. mm2 : Cmc21
8.BB.05AmblygoniteLiAl(PO4)FTric. 1 : P1
8.BB.05MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
8.BB.05TavoriteLiFe3+(PO4)(OH)Tric. 1 : P1
8.BB.10TripliteMn2+2(PO4)FMon. 2/m
8.BB.10ZwieseliteFe2+2(PO4)FMon. 2/m : P21/b
8.BB.15SarkiniteMn2+2(AsO4)(OH)Mon. 2/m : P21/b
8.BB.15TriploiditeMn2+2(PO4)(OH)Mon. 2/m : P2/b
8.BB.15Wagnerite(Mg,Fe2+)2(PO4)FMon. 2/m : P21/b
8.BB.15WolfeiteFe2+2(PO4)(OH)Mon. 2/m : P21/b
8.BB.15Stanĕkite(Mn2+,Fe2+,Mg)Fe3+(PO4)OMon. 2/m : P21/b
8.BB.15JoosteiteMn2+(Mn3+,Fe3+)(PO4)OMon. 2/m
8.BB.15HydroxylwagneriteMg2(PO4)(OH)Mon. 2/m : P21/b
8.BB.15Unnamed (Sb-analogue of Auriacusite)Fe3+Cu2+[(Sb,As)O4]O
8.BB.20HoltedahliteMg2(PO4)(OH)Trig. 3m : P3 1m
8.BB.20Satterlyite(Fe2+,Mg,Fe)12(PO4)5(PO3OH)(OH,O)6Trig. 3m (3 2/m) : P3 1m
8.BB.25AlthausiteMg4(PO4)2(OH,O)(F,◻)Orth. mmm (2/m 2/m 2/m) : Pnma
8.BB.30AdamiteZn2(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
8.BB.30EveiteMn2+2(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
8.BB.30LibetheniteCu2(PO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
8.BB.30OliveniteCu2(AsO4)(OH)Mon. 2/m : P21/m
8.BB.30ZincoliveniteCuZn(AsO4)(OH)Orth. mmm (2/m 2/m 2/m) : Pnnm
8.BB.30AuriacusiteFe3+Cu2+(AsO4)OOrth. mmm (2/m 2/m 2/m) : Pnnm
8.BB.35ParadamiteZn2(AsO4)(OH)Tric. 1 : P1
8.BB.35TarbuttiteZn2(PO4)(OH)Tric. 1 : P1
8.BB.40BarbosaliteFe2+Fe3+2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40HentscheliteCuFe3+2(PO4)2(OH)2Mon. 2/m : P21/m
8.BB.40LazuliteMgAl2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40ScorzaliteFe2+Al2(PO4)2(OH)2Mon. 2/m : P21/b
8.BB.40WilhelmkleiniteZnFe3+2(AsO4)2(OH)2Mon. 2/m : P21/m
8.BB.45TrolleiteAl4(PO4)3(OH)3Mon. 2/m : B2/b
8.BB.45YaroshevskiteCu9O2(VO4)4Cl2 Tric. 1 : P1
8.BB.45DokuchaeviteCu8O2(VO4)3Cl3Tric. 1 : P1
8.BB.50NamibiteCu(BiO)2(VO4)(OH)Tric. 1 : P1
8.BB.50Aleutite[Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)ClMon. 2/m : B2/m
8.BB.52aEriclaxmaniteCu4O(AsO4)2Tric. 1 : P1
8.BB.52bKozyrevskiteCu4O(AsO4)2Orth. mmm (2/m 2/m 2/m) : Pnma
8.BB.55Phosphoellenbergerite(Mg,◻)2Mg12(PO4,PO3OH)6(PO3OH,CO3)2(OH)6Hex. 6mm : P63mc
8.BB.55PopoviteCu5O2(AsO4)2Tric. 1 : P1
8.BB.60UrusoviteCuAl(AsO4)OMon. 2/m : P21/b
8.BB.65TheoparacelsiteCu3(As2O7)(OH)2Orth. mmm (2/m 2/m 2/m) : Pmma
8.BB.70TuraniteCu5(VO4)2(OH)4Tric. 1 : P1
8.BB.75StoiberiteCu5(VO4)2O2Mon. 2/m
8.BB.80FingeriteCu11(VO4)6O2Tric. 1 : P1
8.BB.85AverieviteCu6(VO4)2O2Cl2Trig. 3 : P3
8.BB.90LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet. 4 2 2 : P41 21 2
8.BB.90RichelliteCaFe3+2(PO4)2(OH,F)2Amor.
8.BB.90ZinclipscombiteZnFe3+2(PO4)2(OH)2Tet. 4 2 2 : P43 21 2

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ZincolibetheniteHide

References for ZincolibetheniteHide

Localities for ZincolibetheniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Broken Hill district
        • Broken Hill
Williams et al. (2006)
Chile
 
  • Atacama
    • Copiapó Province
      • Tierra Amarilla
maurizio dini & arturo molina ...
China
 
  • Yunnan
    • Kunming
Hercule Shen
Hercule Shen
France
 
  • Occitanie
    • Aveyron
      • Villefranche-de-Rouergue
        • Monteils
Favreau et al. (2010)
Japan
 
  • Shiga Prefecture
    • Konan City
      • Ishibe
Masutomi Museum specimen and analyses (Kyoto)
Namibia
 
  • ǁKaras Region
    • Oranjemund Constituency
      • Rosh Pinah
Jahn (2007)
Portugal
 
  • Beja
    • Odemira
      • São Luís
Alves et al. (2017)
Republic of the Congo
 
  • Bouenza Department
    • Mfouati District
      • Mfouati
www.spiriferminerals.com (2020)
Spain
 
  • Andalusia
    • Córdoba
      • Belalcázar
        • La Ventosilla farmhouse
Rewitzer et al. (2018)
  • Castile and Leon
    • Salamanca
      • Golpejas-Vega de Tirados
        • Golpejas Mining group
Calvo (2015)
USA
 
  • Nevada
    • Elko County
      • Snowstorm Mountains Mining District
Collected and analyzed by Tim Rose.
    • Lander County
      • North Battle Mountain Mining District
Steve Silva (2010)
Zambia (TL)
 
  • Central Province
    • Kabwe District
      • Kabwe
Am Min 90:1950 +1 other reference
 
矿物 and/or 产地  
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