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Lintisite

A valid IMA mineral species
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About LintisiteHide

Formula:
LiNa3Ti2(Si2O6)2O2 · 2H2O
Colour:
Colorless, white to pale yellow
Lustre:
Vitreous, Pearly
Hardness:
5 - 6
Specific Gravity:
2.77
Crystal System:
Monoclinic
Name:
Named for its chemical composition that includes Li, Na, Ti, and Si.
Closely related (i.a., chemically) to punkaruaivite and eliseevite.

The Li analogue of kukisvumite and manganokukisvumite. AM-4 family of natural titanosilicates.


Unique IdentifiersHide

Mindat ID:
2410
Long-form identifier:
mindat:1:1:2410:1
GUID
(UUID V4):
b4e24286-dcf1-45b8-b8e3-19abb4c68253

IMA Classification of LintisiteHide

Classification of LintisiteHide

9.DB.15

9 : SILICATES (Germanates)
D : Inosilicates
B : Inosilicates with 2-periodic single chains, Si2O6; Pyroxene-related minerals
65.1.6.3

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
1 : Single-Width Unbranched Chains, W=1 with chains P=2
14.9.3

14 : Silicates not Containing Aluminum
9 : Silicates of Ti

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LtsIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of LintisiteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of LintisiteHide

Vitreous, Pearly
Transparency:
Transparent
Comment:
Vitreous on fractures, pearly on cleavages.
Colour:
Colorless, white to pale yellow
Streak:
White
Hardness:
5 - 6 on Mohs scale
Tenacity:
Elastic
Cleavage:
Perfect
{100} and {010}
Fracture:
Splintery
Density:
2.77(5) g/cm3 (Measured)    2.825 g/cm3 (Calculated)

Optical Data of LintisiteHide

Type:
Biaxial (-)
RI values:
nα = 1.672(2) nβ = 1.739(2) nγ = 1.802
2V:
Measured: 85° (1), Calculated: 84°
Max Birefringence:
δ = 0.130
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r < v, strong
Optical Extinction:
Z ∧ γ = 2°, Y = β. Extinction straight to very slightly oblique as result of flattening of the needles on {100}.

Chemistry of LintisiteHide

Mindat Formula:
LiNa3Ti2(Si2O6)2O2 · 2H2O
Common Impurities:
Nb,Fe,Mn,K

Crystallography of LintisiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 28.583(4) Å, b = 8.600(1) Å, c = 5.219(1) Å
β = 91.03(2)°
Ratio:
a:b:c = 3.324 : 1 : 0.607
Unit Cell V:
1,282.69 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Needlelike crystals, in fibrous or columnar aggregates. Elongate [001] and flattened on {100}.
Twinning:
Twin axis [100]

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010998LintisiteMerlino S, Pasero M (1990) The crystal structure of lintisite, Na3LiTi2[Si2O6]2O2*2H2O, a new titanosilicate from Lovozero (USSR) Zeitschrift fur Kristallographie 193 137-1481990Lovozero, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
14.29 Å(s)
2.996 Å(s)
6.39 Å(m)
4.77 Å(m)
3.69 Å(m)
2.744 Å(m)
2.709 Å(m)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of LintisiteHide

General Appearance of Type Material:
Fibrous or parallel-columnar aggregates, up to 0.5 mm thick and 5 mm long, that replaced lorenzenite on cleavages and crystal surfaces.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, p503/3; The Natural History Museum, London, England, 1994,13.
Geological Setting of Type Material:
Pegmatites of nepheline-sodalite syenite.
Associated Minerals at Type Locality:
Reference:
Khomyakov, A.P., Polezhaeva L.I., Merlino S., Pasero M.(1990): Lintisite, Na3LiTiSi4O14 2H2O - a new mineral. Zapinski Vsesoyuznogo Mineralogicheskogo Obshchestva, 119(3), 76-80.

Synonyms of LintisiteHide

Other Language Names for LintisiteHide

German:Lintisit
Spanish:Lintisita

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Lintisite associated with HackmaniteNa8Al6Si6O24(Cl2,S)
4 photos of Lintisite associated with UssingiteNa2AlSi3O8OH
3 photos of Lintisite associated with Eudialyte Group[N(1)N(2)N(3)N(4)N(5)]3[M(1.1)M(1.2)]3[M(2.1)M(2.2)M(2.3)]3-6[M(3)M(4)]Z3[Si24O724X(1)X(2)
1 photo of Lintisite associated with LorenzeniteNa2Ti2(Si2O6)O3
1 photo of Lintisite associated with ManganoneptuniteKNa2Li(Mn2+)2Ti2[Si4O12]2

Related Minerals - Strunz-mindat GroupingHide

9.DB.05BalipholiteBaLiMg2Al3(Si2O6)2(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05CarpholiteMn2+Al2(Si2O6)(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05FerrocarpholiteFe2+Al2Si2O6(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05MagnesiocarpholiteMgAl2Si2O6(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05PotassiccarpholiteK(Mn2+,Li)2Al4Si4O12(OH,F)8Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.05VanadiocarpholiteMn2+V3+Al(Si2O6)(OH)4Orth. mmm (2/m 2/m 2/m) : Ccca
9.DB.10LorenzeniteNa2Ti2(Si2O6)O3Orth. mmm (2/m 2/m 2/m) : Pbcn
9.DB.15PunkaruaiviteLiTi2(HSi4O12)(OH)2 · H2OMon. 2/m : B2/b
9.DB.17EliseeviteLiNa1.5Ti2(H1.5Si4O12)O2 · 2H2OMon. 2/m : B2/b
9.DB.20KukisvumiteNa6ZnTi4(Si8O24)O4 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pccn
9.DB.20ManganokukisvumiteNa6MnTi4(Si8O24)O4 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pccn
9.DB.25VinogradoviteNa4Ti4(Si2O6)2[(Si,Al)4O10]O4 · (H2O,Na,K)3Mon. 2/m : B2/b
9.DB.25ParavinogradoviteNa1-2(Ti,Fe3+)4(Si2O6)2(AlSi3O10)(OH)4 · H2OTric. 1 : P1
9.DB.30NchwaningiteMn2+2(SiO3)(OH)2 · H2OOrth. mm2 : Pca21
9.DB.35PlancheiteCu8(Si8O22)(OH)4 · H2OOrth. mmm (2/m 2/m 2/m)
9.DB.40ShattuckiteCu5(Si2O6)2(OH)2Orth. mmm (2/m 2/m 2/m)
9.DB.40UM2005-31-SiO:CuHCu11(SiO4)(OH)18 · 9H2O (?)
9.DB.45Aerinite(Ca5.1Na0.5)(Fe3+,Al,Fe2+,Mg)4(Al,Mg)6[HSi12O36(OH)12][(CO3)1.2(H2O)12]Trig. 3m : P3c1
9.DB.50CapranicaiteKCaNaAl4B4Si2O18Mon. 2/m : P21/m

Fluorescence of LintisiteHide

Fluoresces weak yellow in UV.

Other InformationHide

Thermal Behaviour:
Material dehydrated at 600°C gives an X-ray powder pattern of lorenzenite.
Notes:
Readily dissolves in 10% HCl, leaving a siliceous residue.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LintisiteHide

References for LintisiteHide

Localities for LintisiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
HORVÁTH et al. (2000)
Russia
 
  • Murmansk Oblast
...
    • Lovozersky District
Merlino S. et al. (1990) +1 other reference
      • Karnasurt Mountain
        • Karnasurt mine
Pekov I.V.. et al (2009)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
Dill et al. (2023)
Dill et al. (2023)
Dill et al. (2023)
 
矿物 and/or 产地  
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