Laffittite
A valid IMA mineral species
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About Laffittite
Formula:
AgHgAsS3
Colour:
Dark red to cherry-red, may be very dark-red with only red glints
Lustre:
Adamantine, Metallic
Hardness:
3½
Specific Gravity:
6.11
Crystal System:
Monoclinic
Name:
Named in 1974 by Zdeněk Johan, Joseph Mantienne, and R. Picot in honor of Pierre Paul Laffitte (January 1, 1925 Saint-Paul-de-Vence, Alpes-Maritimes, France - ), director of BRGM (French Geological Survey), then director and president of Ecole Nationale Supérieure des Mines de Paris.
Unique Identifiers
Mindat ID:
2311
Long-form identifier:
mindat:1:1:2311:1
GUID
(UUID V4):
(UUID V4):
0a01ab84-2d53-4a1f-8aac-c14c55ff8c5e
IMA Classification of Laffittite
Approved
First published:
1974
Classification of Laffittite
2.GA.35
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
A : Neso-sulfarsenites, etc. without additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
A : Neso-sulfarsenites, etc. without additional S
3.4.10.2
3 : SULFOSALTS
4 : ø = 3
3 : SULFOSALTS
4 : ø = 3
5.4.4
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
4 : Sulpharsenites etc. of Zn and Hg
5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
4 : Sulpharsenites etc. of Zn and Hg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Lft | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Laffittite
Adamantine, Metallic
Transparency:
Opaque
Colour:
Dark red to cherry-red, may be very dark-red with only red glints
Streak:
Pale cherry-red to brownish red
Hardness:
3½ on Mohs scale
Hardness:
VHN25=92 - 138 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Distinct/Good
Good to imperfect on {010}
Good to imperfect on {010}
Fracture:
Conchoidal
Density:
6.11 g/cm3 (Measured) 6.195 g/cm3 (Calculated)
Comment:
Measured is on synthetic material
Optical Data of Laffittite
Anisotropism:
Strong to moderate, pale gray-blue to dark gray
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
400nm | 34.5% | 38.4% |
420nm | 34.6% | 37.7% |
440nm | 34.7% | 37.0% |
460nm | 34.4% | 36.1% |
480nm | 33.8% | 35.2% |
500nm | 32.9% | 34.3% |
520nm | 31.8% | 33.4% |
540nm | 30.7% | 32.5% |
560nm | 29.5% | 31.7% |
580nm | 28.6% | 30.8% |
600nm | 28.0% | 30.1% |
620nm | 27.4% | 29.7% |
640nm | 27.1% | 29.4% |
660nm | 26.8% | 29.4% |
680nm | 26.6% | 29.2% |
700nm | 26.3% | 28.9% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 38.4%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Bluish white
Internal Reflections:
Purple-red
Pleochroism:
Strong
Chemistry of Laffittite
Mindat Formula:
AgHgAsS3
Elements listed:
Crystallography of Laffittite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 7.732(3) Å, b = 11.285(7) Å, c = 6.643(4) Å
β = 115.16(3)°
β = 115.16(3)°
Ratio:
a:b:c = 0.685 : 1 : 0.589
Unit Cell V:
524.65 ų (Calculated from Unit Cell)
Z:
4
Twinning:
{100}, twin axis ⊥ {100}; also by an unknown law giving intergrowths at a 60 degree angle
Comment:
Space Group: A2/a
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000889 | Laffittite | Nakai I, Appleman D E (1983) Laffittite, AgHgAsS3: crystal structure and second occurrence from the Getchell mine, Nevada American Mineralogist 68 235-244 | 1983 | 0 | 293 | ||
0017799 | Laffittite | Pervukhina N V, Borisov S V, Magarill S A, Vasil'ev V I, Kuratieva N V (2010) Redetermination and crystallographic analysis of the structure of Sb-containing laffittite AgHg(As,Sb)S3 from Chauvai (Kyrgyzstan) Journal of Structural Chemistry 51 683-688 | 2010 | Chauvai deposit, Kyrgyzstan | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.682 Å | (100) |
3.198 Å | (80) |
3.005 Å | (80) |
3.505 Å | (70) |
2.133 Å | (60) |
5.31 Å | (50) |
1.905 Å | (50) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Laffittite
General Appearance of Type Material:
Grains up to 0.2 mm
Place of Conservation of Type Material:
National School of Mines, Paris, France.
Geological Setting of Type Material:
Dolomitic rocks
Associated Minerals at Type Locality:
Reference:
Johan, Z., Mantienne, J., Picot, R. (1974) La routhiérite, TlHgAsS3, et la laffittite, AgHgAsS3, deux nouvelles espèces minérales. Bulletin de la Société Française de Minéralogie et de Cristallographie: 97: 48-53.
Synonyms of Laffittite
Other Language Names for Laffittite
Common Associates
Associated Minerals Based on Photo Data:
19 photos of Laffittite associated with Orpiment | As2S3 |
9 photos of Laffittite associated with Realgar | As4S4 |
8 photos of Laffittite associated with Getchellite | AsSbS3 |
4 photos of Laffittite associated with Quartz | SiO2 |
3 photos of Laffittite associated with Stibnite | Sb2S3 |
2 photos of Laffittite associated with Routhierite | Tl(Cu,Ag)(Hg,Zn)2(As,Sb)2S6 |
2 photos of Laffittite associated with Calcite | CaCO3 |
1 photo of Laffittite associated with Cinnabar | HgS |
1 photo of Laffittite associated with Pierrotite | Tl2(Sb,As)10S16 |
Related Minerals - Strunz-mindat Grouping
2.GA. | Arsiccioite | AgHg2Tl(As,Sb)2S6 |
2.GA. | Eckerite | Ag2CuAsS3 |
2.GA. | Pyradoketosite | Ag3SbS3 |
2.GA.05 | Proustite | Ag3AsS3 |
2.GA.05 | Pyrargyrite | Ag3SbS3 |
2.GA.10 | Pyrostilpnite | Ag3SbS3 |
2.GA.10 | Xanthoconite | Ag3AsS3 |
2.GA.15 | Samsonite | Ag4MnSb2S6 |
2.GA.20 | Skinnerite | Cu3SbS3 |
2.GA.20 | Wittichenite | Cu3BiS3 |
2.GA.20 | Bytízite | Cu3SbSe3 |
2.GA.25 | Lapieite | NiCuSbS3 |
2.GA.25 | Mückeite | NiCu(Bi,Sb)S3 |
2.GA.25 | Malyshevite | PdCuBiS3 |
2.GA.25 | Lisiguangite | PtCuBiS3 |
2.GA.25 | Roterbärite | PdBiCuSe3 |
2.GA.30 | Aktashite | Cu6Hg3As4S12 |
2.GA.30 | Gruzdevite | Cu6Hg3Sb4S12 |
2.GA.30 | Nowackiite | Cu6Zn3As4S12 |
2.GA.30 | Zhengminghuaite | Cu6Fe3As4S12 |
2.GA.40 | Routhierite | Tl(Cu,Ag)(Hg,Zn)2(As,Sb)2S6 |
2.GA.40 | Stalderite | Tl(Cu,Ag)(Zn,Fe,Hg)2(As,Sb)2S6 |
2.GA.40 | Ralphcannonite | AgZn2TlAs2S6 |
2.GA.40 | Ferrostalderite | CuFe2TlAs2S6 |
2.GA.40 | Unnamed (Ag-Fe endmember of Routhierite Group) | AgFe2TlAs2S6 |
2.GA.45 | Erniggliite | Tl2SnAs2S6 |
2.GA.50 | Bournonite | PbCuSbS3 |
2.GA.50 | Seligmannite | PbCuAsS3 |
2.GA.50 | Součekite | PbCuBi(S,Se)3 |
2.GA.50 | Unnamed (Pb-Cu-Bi Selenide) | PbCuBiSe3 |
2.GA.50 | Cerromojonite | CuPbBiSe3 |
2.GA.55 | Eldragónite | Cu6BiSe4(Se2) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Laffittite
mindat.org URL:
https://www.mindat.org/min-2311.html
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References for Laffittite
Reference List:
Localities for Laffittite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
France (TL) | |
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Italy | |
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Kyrgyzstan | |
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Russia | |
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USA | |
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Jas Roux, La Chapelle-en-Valgaudemar, Gap, Hautes-Alpes, Provence-Alpes-Côte d'Azur, France