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Labuntsovite-Mn

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About Labuntsovite-MnHide

02642390014947074957902.jpg
Russian mineralogist Aleksander Nikolaevich Labuntsov.
Formula:
Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O
Hardness:
6
Crystal System:
Monoclinic
Name:
Named after the Russian mineralogists Aleksander Nikolaevich Labuntsov and Ekaterina Eutiikkieva Labuntsov-Kostyleva (for whom the mineral kostylevite is also named).
This is the original labuntsovite. It is now designated labuntsovite-Mn for the dominance of manganese among the divalent cations.



Classification of Labuntsovite-MnHide

Approved, 'Grandfathered' (first described prior to 1959)
9.CE.30e

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
16.14.8

16 : Silicates Containing Aluminum and other Metals
14 : Aluminosilicates of Ti, Zr, Sn and Pb

Physical Properties of Labuntsovite-MnHide

Hardness:

Optical Data of Labuntsovite-MnHide

Type:
Biaxial (+)
RI values:
nα = 1.684 - 1.695 nβ = 1.693 - 1.702 nγ = 1.792 - 1.814
2V:
Measured: 20° to 44°, Calculated: 30° to 36°
Max Birefringence:
δ = 0.108 - 0.119
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
strong

Chemical Properties of Labuntsovite-MnHide

Formula:
Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O
IMA Formula:
Na4K4Mn2+2Ti8O4(Si4O12)4(OH)4 · 10-12H2O
Common Impurities:
Fe,Mn,Mg,Ca

Crystallography of Labuntsovite-MnHide

Crystal System:
Monoclinic

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012358Labuntsovite-MnRastsvetaeva R K, Chukanov N V, Pekov I V, Shlyukova Z V, Khomyakov A P (1998) Structures of two potassium-rich labuntsovites in relation to the crystal chemistry of minerals of the labuntsovite-nenadkevichite family Crystallography Reports 43 820-82719980293
0015562Labuntsovite-MnGolovastikov N I (1973) Crystal structure of the alkali titanosilicate labuntsovite Soviet Physics Crystallography 18 950-95519730293
0015563Labuntsovite-MnGolovastikov N I (1974) Crystal structure of the alkali titanosilicate labuntsovite Soviet Physics Crystallography 18 596-59919740293
CIF Raw Data - click here to close

Type Occurrence of Labuntsovite-MnHide

Synonyms of Labuntsovite-MnHide

Other Language Names for Labuntsovite-MnHide

Relationship of Labuntsovite-Mn to other SpeciesHide

Other Members of this group:
Labuntsovite-FeNa4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
Labuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
UM2006-16- SiO:BaFeHKMgMnNaNbTiK3.58Na2.06Ba1.65(H2O)1.58(Mn0.42Mg0.20Fe0.16)[Ti6.75Nb0.65(OH)0.9O0.1)8(Si4O12)4]•11.5H2O

Common AssociatesHide

Associated Minerals Based on Photo Data:
10 photos of Labuntsovite-Mn associated with NatroliteNa2Al2Si3O10 · 2H2O
8 photos of Labuntsovite-Mn associated with CalciteCaCO3
6 photos of Labuntsovite-Mn associated with Tsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O
5 photos of Labuntsovite-Mn associated with AegirineNaFe3+Si2O6
4 photos of Labuntsovite-Mn associated with MicroclineK(AlSi3O8)
3 photos of Labuntsovite-Mn associated with ElpiditeNa2ZrSi6O15 · 3H2O
3 photos of Labuntsovite-Mn associated with ManganoneptuniteNa2KLiMn2+2Ti2Si8O24
2 photos of Labuntsovite-Mn associated with Burovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O
2 photos of Labuntsovite-Mn associated with RhodochrositeMnCO3
1 photo of Labuntsovite-Mn associated with Lemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O

Related Minerals - Nickel-Strunz GroupingHide

9.CE.05PapagoiteCaCu[H3AlSi2O9]Mon.
9.CE.10VerplanckiteBa2(Mn,Fe,Ti)Si2O6(O,OH,Cl,F)2 · 3H2O or nearHex.
9.CE.15BaotiteBa4Ti8Si4O28ClTet. 4/m : I41/a
9.CE.20NagashimaliteBa4(V,Ti)4B2Si8O27(O,OH)2ClOrth. mmm (2/m 2/m 2/m) : Pmmn
9.CE.20TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m) : Pmmn
9.CE.20TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth.
9.CE.25Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
9.CE.25Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2OOrth. mm2 : Ama2
9.CE.25Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
9.CE.25Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.25StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
9.CE.25Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
9.CE.25Orthojoaquinite-(La)NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.30aNenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30dLemmleinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OOrth.
9.CE.30aKorobitsyniteNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30cKuzmenkoite-MnK2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2OMon.
9.CE.30bVuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon.
9.CE.30bTsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon.
9.CE.30cKarupmøllerite-Ca(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2OMon. 2/m : B2/m
9.CE.30eLabuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
9.CE.30eLabuntsovite-FeNa4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
9.CE.30dLemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-FeK2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30hNeskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2OMon. m : Bm
9.CE.30bTsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. 2/m : B2/m
9.CE.30bParatsepinite-BaBa4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2OMon. 2/m : B2/m
9.CE.30bTsepinite-CaCa(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. 2/m : B2/m
9.CE.30hAlsakharovite-ZnNaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30cGjerdingenite-MnK2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cLepkhenelmite-Zn(Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30bTsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-Na(Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8·nH2O n ~ 8Mon. 2/m : B2/m
9.CE.30fParalabuntsovite-MgNa8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2OMon. 2/m
9.CE.30cGjerdingenite-CaK2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-NaK2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2OMon. 2/m : B2/m
9.CE.30hGutkovaite-MnK2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon.
9.CE.30cKuzmenkoite-ZnK2Zn(Ti,Nb)4(Si4O12)2(OH,O)4·6-8H2OMon. m : Bm
9.CE.30gOrganovaite-MnK2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-ZnK2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30gParakuzmenkoite-Fe(K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2OMon. 2/m : B2/m
9.CE.30cBurovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2OMon. 2/m : B2/m
9.CE.45Komarovite(Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2OOrth.
9.CE.45Natrokomarovite(Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2OOrth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.14.1ZoriteNa8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2OOrth.
16.14.2VinogradoviteNa4Ti4(Si2O6)2[(Si,Al)4O10]O4 · (H2O,Na,K)3Mon. 2/m : B2/b
16.14.3RhöniteCa4[Mg8Fe3+2Ti2]O4[Si6Al6O36]Tric. 1 : P1
16.14.4KaersutiteNaCa2(Mg3AlTi4+)(Si6Al2)O22O2Mon.
16.14.5Ferro-kaersutiteNaCa2{Fe2+3AlTi}(Al2Si6O22)O2Mon.
16.14.6JonesiteBa4(K,Na)2Ti4Al2(Si3O9)2(SiO4)4O2 · 6H2OOrth.
16.14.7Lourenswalsite(K,Ba)2(Ti,Mg,Ca,Fe)4(Si,Al,Fe)6O14(OH)12Hex.
16.14.9KimzeyiteCa3Zr2(SiO4)(AlO4)2Iso.
16.14.10EllenbergeriteMg6(Mg,Ti,Zr,◻)2(Al,Mg)6Si8O28(OH)10Hex.
16.14.11Carlosturanite(Mg,Fe,Ti)21(Si,Al)12O28(OH)34•H2OMon. m : Bm
16.14.12EakeriteCa2SnAl2Si6O18(OH)2 · 2H2OMon.
16.14.13PlumalsitePb4Al2(SiO3)7
16.14.14WickenburgiteCaPb3Al2Si10O24(OH)6Trig. 3m : P3 1c
16.14.15MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
16.14.16Hancockite{CaPb}{Al2Fe3+}(Si2O7)(SiO4)O(OH)Mon.
16.14.17BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
16.14.18MathewrogersitePb7FeAl3GeSi12O36(OH,H2O)6Trig.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Labuntsovite-MnHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Semenov, E.I. and Burova, T.A. (1955) On the new mineral, labuntsovite, and the so-called titanoelpidite. Doklady Akademii Nauk SSSR., 101, 1113-1116 (in Russian). [English abstract in American Mineralogist (1956) 41: 163.]
Golovina, N.I., Shilov, G.V., Chukanov, N.V., and Pekov, I.V. (1998) Crystal structure of the manganese-rich analog of labuntsovite. Doklady Akad. Nauk: 362(3): 350–352 (in Russian).
Chukanov, N.V., Pekov, I.V., Rastsvetaeva, R.K., Nekrasov, A.N. (1999) Labuntsovite: solid solutions and features of the crystal structure. Canadian Mineralogist: 37: 901-910.
Jambor, J.L., Pertsev, N.N., and Roberts, A.C. (1999) New mineral names. American Mineralogist: 84: 1195-1198.
Chukanov, N.V., Pekov, I.V., and Khomyakov, A.P. (2002) Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy: 14: 165-173.

Internet Links for Labuntsovite-MnHide

Localities for Labuntsovite-MnHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
GRICE, J.D. (1989) Mont Saint-Hilaire, Quebec: Canada's Most Diverse Mineral Locality. In: Famous mineral localities of Canada. Published by Fitzhenry & Whiteside Limited & the National Museum of Natural Sciences, 190 pages: 100-108; 166-175.; HORVÁTH, L., GAULT, R.A. (1990) The mineralogy of Mont Saint-Hilaire. Mineralogical Record, 21, 281-359.; CHUKANOV, N.V., PEKOV, I.V., ZADOV, A.E., VOLOSHIN, A.V., SUBBOTIN, V.V., SOROKHTINA, N.V., RASTVETAEVA, R.K., KRIVOVICHEV, S.V. (2003) Minerals of the labuntsovite group. Nauka, Moscow, 323 pages (in Russian).
      • Lajemmerais RCM
        • Varennes & St-Amable
HORVÁTH, L., PFENNINGER HORVÁTH, E., GAULT, R.A., and TARASSOFF, P. (1998) Mineralogy of the Saint Amable sill, Varennes and Saint Amable, Québec, Canada. Mineralogical Record, 29, 83 118.
Horváth, L., Pfenninger-Horváth, E., Gault, R. A., & Tarassoff, P. (1998): Mineralogy of the Saint-Amable Sill, Varennes and Saint-Amable, Québec. Mineralogical Record, 29: 83-118.
Namibia
 
  • Khomas Region
    • Windhoek Rural
      • Aris
Petersen, O. V., Niedermayr, G., Pekov, I. V., Balić Žunić, T. and Brandstätter, F. (2004): Tsepinit-Na und Labuntsovit-Mn, seltene Mineralien aus dem Phonolith von Aris, Namibia. Mineralien-Welt, 15 (2), 44-48. (in German)
Norway
 
  • Vestland
    • Askvoll
      • Dalsfjorden
Furnes, H., & Mitchell, J.G, Robins, B., Ryan, P. & Skjerlie, F.J. (1982). Petrography and geochemistry of peralkaline, ultrapotassic syenite dykes of Middle Permian age, Sunnfjord, West Norway. Norsk Geologisk Tidsskrift, 62, 147-159.
Russia
 
  • Aldan Shield
    • Chara and Tokko Rivers Confluence
[Lapis 1993:4 p.13-20]
  • Murmansk Oblast
    • Khibiny Massif
Pekov et al (2005) New Data on Minerals Vol 40 pp11-16; Azarova, Y. V., Shlyukova, Z. V., Zolotarev Jr, A. A., & Organova, N. I. (2009). Burovaite-Ca,(Na, K) 4Ca2 (Ti, Nb) 8 [Si4O12] 4 (OH, O) 8· 12H2O, a new labuntsovite-group mineral species and its place in low-temperature mineral formation in pegmatites of the Khibiny pluton, Kola Peninsula, Russia. Geology of Ore Deposits, 51(8), 774-783.
      • Koashva Mt
[World of Stones 95:5-6, p64]
      • Kukisvumchorr Mt
[World of Stones 95:5-6, p64]
Takai, Y., Uehara, S., Inoo, T. (2011) Minerals from Khibiny, Kola, Russia. Chigaku Kenkyu, 60 (1), 41-46.; Arzamastsev, A., Yakovenchuk, V., Pakhomovsky, Y., & Ivanyuk, G. (2008). The Khibina and Lovozero alkaline massifs: Geology and unique mineralization. In Guidbook for 33rd International Geological Congress Excursion (No. 47, p. 58).
Mikhailova, Y.A., Konopleva, N.G., Yakovenchuk, V.N., Ivanyuk, G.Y., Men’shikov, Y.P., and Pakhomovsky, Y.A. (2007): Geology of Ore Deposits 49(7), 590-598.
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    • Kovdor Massif
[World of Stones 95:5-6, p64]
    • Lovozersky District
[AmMin 85:1322]
      • Kuftnyun Mountain
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
[AmMin 85:1562]; Pekov, I. et al (2003): New Data on Minerals: 38: 20-33.
    • Northern Karelia
www.koeln.netsurf.de/~w.steffens/vuori.htm
    • Turii Cape
USA
 
  • Arkansas
    • Hot Spring Co.
      • Magnet Cove
Rocks & Min.:64:300-307.
 
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