SUPPORT US. Covid-19 has significantly affected our fundraising. Please help!
登录注册
主页关于 MindatMindat手册Mindat的历史版权Who We Are联系我们于 Mindat.org刊登广告
捐赠给 MindatCorporate Sponsorship赞助板页已赞助的板页在 Mindat刊登 广告的广告商于 Mindat.org刊登广告
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe Elements书籍及杂志
搜索矿物的性质搜索矿物的化学Advanced Locality Search随意显示任何一 种矿物Random Locality使用minID搜索邻近产地Search Articles搜索词汇表更多搜索选项
搜索:
矿物名称:
地区产地名称:
关键字:
 
Mindat手册添加新照片Rate Photos产区编辑报告Coordinate Completion Report添加词汇表项目
Mining Companies统计会员列表Mineral Museums矿物展及活动The Mindat目录表设备设置The Mineral Quiz
照片搜索Photo GalleriesSearch by Color今天最新的照片昨天最新的照片用户照片相集过去每日精选照片相集Mineral Photography

Kalicinite

This page is currently not sponsored. Click here to sponsor this page.
Hide all sections | Show all sections

About KaliciniteHide

Formula:
KHCO3
Colour:
Colourless, white, yellowish
Hardness:
1 - 2
Crystal System:
Monoclinic
Name:
In allusion to the composition, containing potassium (Latin = KALIum)
This page provides mineralogical data about Kalicinite.


Classification of KaliciniteHide

Approved, 'Grandfathered' (first described prior to 1959)
5.AA.20

5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
A : Alkali carbonates
13.1.2.1

13 : ACID CARBONATES
1 : Miscellaneous
11.1.8

11 : Carbonates
1 : Carbonates of the alkali metals and ammonium

Physical Properties of KaliciniteHide

Transparency:
Transparent
Colour:
Colourless, white, yellowish
Hardness:
1 - 2 on Mohs scale

Optical Data of KaliciniteHide

Type:
Biaxial (-)
RI values:
nα = 1.380 nβ = 1.482 nγ = 1.578
2V:
Measured: 81° , Calculated: 82°
Max Birefringence:
δ = 0.198
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v weak

Chemical Properties of KaliciniteHide

Formula:
KHCO3
IMA Formula:
KH(CO3)

Crystallography of KaliciniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 15.11 Å, b = 5.67 Å, c = 3.71 Å
β = 103.75°
Ratio:
a:b:c = 2.665 : 1 : 0.654
Unit Cell V:
308.74 ų (Calculated from Unit Cell)
Morphology:
Fine-crystalline aggregates. Crystals shiort prismatic (artificial material).

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File    Best | x | y | z | a | b | c
Rotation
Stop | Start
Labels
Console Off | On | Grey | Yellow
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003172KaliciniteKagi H, Nagai T, Loveday J S, Wada C, Parise J B (2003) Pressure-induced phase transformation of kalicinite (KHCO3) at 2.8 GPa and local structural changes around hydrogen atoms American Mineralogist 88 1446-145120030293
0003173KaliciniteKagi H, Nagai T, Loveday J S, Wada C, Parise J B (2003) Pressure-induced phase transformation of kalicinite (KHCO3) at 2.8 GPa and local structural changes around hydrogen atoms American Mineralogist 88 1446-145120030.2293
0003174KaliciniteKagi H, Nagai T, Loveday J S, Wada C, Parise J B (2003) Pressure-induced phase transformation of kalicinite (KHCO3) at 2.8 GPa and local structural changes around hydrogen atoms American Mineralogist 88 1446-145120031.8293
0003175KaliciniteKagi H, Nagai T, Loveday J S, Wada C, Parise J B (2003) Pressure-induced phase transformation of kalicinite (KHCO3) at 2.8 GPa and local structural changes around hydrogen atoms American Mineralogist 88 1446-145120032.3293
0003176KaliciniteKagi H, Nagai T, Loveday J S, Wada C, Parise J B (2003) Pressure-induced phase transformation of kalicinite (KHCO3) at 2.8 GPa and local structural changes around hydrogen atoms American Mineralogist 88 1446-145120032.5293
0009145KaliciniteNitta I, Tomiie Y, Koo C H (1952) The crystal structure of potassium bicarbonate, KHCO3 Acta Crystallographica 5 292-29219520293
0009158KaliciniteNitta I, Tomiie Y, Koo C H (1954) On the relation among the results of various investigations on potassium bicarbonate, KHCO3 Acta Crystallographica 7 140-14119540293
0018502KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Acta Crystallographica B30 1155-11661974Synthetic0298
0018503KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Acta Crystallographica B30 1155-11661974Synthetic0219
0018504KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Note z-coordinate of O3 has been modified with a negative sign Acta Crystallographica B30 1155-11661974Synthetic095
0018505KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Acta Crystallographica B30 1155-11661974Synthetic0298
0018506KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Acta Crystallographica B30 1155-11661974Synthetic0219
0018507KaliciniteThomas J O, Tellgren R, Olovsson I (1974) Hydrogen-bond studies. LXXXIV. An X-ray diffraction study of the structures of KHCO3 and KDCO3 at 298, 219 and 95 K Acta Crystallographica B30 1155-11661974Synthetic095
CIF Raw Data - click here to close

Type Occurrence of KaliciniteHide

Geological Setting of Type Material:
Under a dead tree as a decomposition product of recent origin.

Synonyms of KaliciniteHide

Other Language Names for KaliciniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Kalicinite associated with BobierriteMg3(PO4)2 · 8H2O

Related Minerals - Nickel-Strunz GroupingHide

5.AA.05ZabuyeliteLi2CO3Mon. 2/m : B2/b
5.AA.10NatriteNa2CO3Mon.
5.AA.10Gregoryite(Na2,K2,Ca)CO3Hex.
5.AA.15NahcoliteNaHCO3Mon. 2/m
5.AA.25Teschemacherite(NH4)HCO3Orth. mmm (2/m 2/m 2/m) : Pccn
5.AA.30WegscheideriteNa5H3(CO3)4Tric. 1 : P1

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

11.1.1ZabuyeliteLi2CO3Mon. 2/m : B2/b
11.1.2NatriteNa2CO3Mon.
11.1.3NahcoliteNaHCO3Mon. 2/m
11.1.4WegscheideriteNa5H3(CO3)4Tric. 1 : P1
11.1.5ThermonatriteNa2CO3 · H2OOrth. mmm (2/m 2/m 2/m) : Pmmm
11.1.6TronaNa3H(CO3)2 · 2H2OMon. 2/m
11.1.7NatronNa2CO3 · 10H2OMon. 2/m : P2/m
11.1.9ShortiteNa2Ca2(CO3)3Orth. mm2 : Amm2
11.1.10NyerereiteNa2Ca(CO3)2Orth. mmm (2/m 2/m 2/m) : Cmcm
11.1.11NatrofairchilditeNa2Ca(CO3)2Orth.
11.1.12ZemkoriteNa2Ca(CO3)2Hex.
11.1.13PirssoniteNa2Ca(CO3)2 · 2H2OOrth. mm2 : Fdd2
11.1.14GaylussiteNa2Ca(CO3)2 · 5H2OMon. 2/m : B2/b
11.1.15BaylissiteK2Mg(CO3)2 · 4H2OMon.
11.1.16FairchilditeK2Ca(CO3)2Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
11.1.17BütschliiteK2Ca(CO3)2Trig. 3m (3 2/m) : R3m
11.1.18Teschemacherite(NH4)HCO3Orth. mmm (2/m 2/m 2/m) : Pccn

Other InformationHide

Notes:
Soluble in water (33.3 g. per 100 g. H2O at 20° C.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for KaliciniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Brooke (1823) Annals of Philosophy, London: 22: 42.
Pisani (1865) Comptes rendus de l’Académie des sciences de Paris: 60: 918 (as Kalicine).
Landero, Carlos F. De (1888) Sinopsis Mineralógica ó catálogo descriptivo de los Minerales. 528pp., Mexico: 255 (as Kalicit).
Ochsenius (1893) Zeitschrift für praktische Geologie, Berlin, hale a.S.: 198.
Groth, P. (1898) Tabellarische Übersicht der Mineralien nach ihren krystallographish-chemischen Beziehungen. Braunschweig.,4th. edition: 57.
Merwin (1930) Int. Crit. Tab.: 7: 27.
Dhar (1936) Curr. Sc.: 4: 867.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 136-137.
Nitta, I., Tomiie, Y. & Koo, C. H. (1952) The crystal structure of potassium bicarbonate, KHCO3. Acta Crystallographica, 5, 292-292.
Nitta, I., Tomiie, Y. & Koo, C. H. (1954) : On the relation among the results of various investigations on potassium bicarbonate, KHCO3. Acta Crystallographica, 7, 140-141.
Acta Crystallographica (1974): B30: 1155.
Kagi, H., Nagai, T., Loveday, J.S., Wada, C., Parise, J.B. (2003) Pressure-induced phase transformation of kalicinite (KHCo3) at 2.8 GPa and local structural changes around hydrogen atoms. American Mineralogist 88: 1446-1451.

Internet Links for KaliciniteHide

Localities for KaliciniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Saguenay-Lac-Saint-Jean
      • Le Fjord-du-Saguenay RCM
        • Saint-Honoré
Fournier, A. (1993)
FOURNIER, A. (1993) Magmat!c and hydrothermal controls of LREE mineralization of the St.-Honoré carbonatite, Québec. M.Sc. thesis, McGill University, Montreal, Canada. 95p.
Russia
 
  • Murmansk Oblast
J. Weissman collection; http://rruff.info/kalicinite/names/asc/
Sweden
 
  • Västernorrland County
    • Sundsvall
Sandström, F., Binett, T., Wiklund, C. & Vikström, J. (2010): Alnöområdets geologi och mineralogi. Litiofilen. 27 (2) :14-42
Switzerland (TL)
 
  • Valais
    • Sierre
C. R. Acad. Sci., Paris (1865): 60: 918; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 136.
Tanzania
 
  • Arusha region
    • Ngorongoro District
Zaitsev, A. N., & Keller, J. (2006). Mineralogical and chemical transformation of Oldoinyo Lengai natrocarbonatites, Tanzania. Lithos, 91(1), 191-207.
USA
 
  • Arizona
    • Maricopa Co.
Garvie, L.A.J. (2016): Mineralogy of paloverde (Parkinsonia microphylla) tree ash from the Sonoran Desert: A combined field and laboratory study. American Mineralogist: 101 : 1584-1595; http://forum.amiminerals.it/viewtopic.php?f=5&t=12875 (2016
  • Virginia
    • Montgomery Co.
Mineralogical Record:2(3):130-132
 
矿物 and/or 产地  
Mindat Discussions Facebook Logo Instagram Logo Discord Logo
版权所有© mindat.org1993年至2020年,除了规定的地方。 Mindat.org全赖于全球数千个以上成员和支持者们的参与。
隐私政策 - 条款和条款细则 - 联络我们 Current server date and time: 2020.11.29 13:15:04 Page generated: 2020.10.9 00:31:31
Go to top of page