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Kirkiite

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About KirkiiteHide

Formula:
Pb10Bi3As3S19
Hardness:
Crystal System:
Monoclinic
Name:
After the type locality at the Agios Philippos Pb-Zn deposit, Kirki (Kirka), Xánthi Prefecture, Thraki (Thrace; Thracia) Department, Greece.
This page provides mineralogical data about Kirkiite.


Classification of KirkiiteHide

Approved
2.JB.30b

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb
3.4.17.1

3 : SULFOSALTS
4 : ø = 3
5.6.32

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
6 : Sulpharsenites etc. of Pb alone

Physical Properties of KirkiiteHide

Hardness:
3½ on Mohs scale

Chemical Properties of KirkiiteHide

Formula:
Pb10Bi3As3S19
Common Impurities:
Sb

Crystallography of KirkiiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 8.700(2) Å, b = 26.237(6) Å, c = 8.774(3) Å
β = 119.653(4)°
Ratio:
a:b:c = 0.332 : 1 : 0.334
Unit Cell V:
1740.2 ų
Comment:
Data from Pinto et al. (2006) for a sample with a composition very close to the endmember.

Type Occurrence of KirkiiteHide

Synonyms of KirkiiteHide

Other Language Names for KirkiiteHide

German:Kirkiit
Simplified Chinese:硫砷铋铅矿
Spanish:Kirkiita
Traditional Chinese:硫砷​​鉍鉛礦

Relationship of Kirkiite to other SpeciesHide

Other Members of this group:
ArsenmarcobaldiitePb12(As3.2Sb2.8)Σ6S21Tric. 1 : P1
GeocronitePb14(Sb,As)6S23Mon. 2/m : P21/m
GratonitePb9As4S15Trig. 3m : R3m
JordanitePb14(As,Sb)6S23Mon. 2/m : P21/m
MarcobaldiitePb12(Sb3As2Bi)Σ6S21Tric. 1 : P1

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Kirkiite associated with BismuthiniteBi2S3

Related Minerals - Nickel-Strunz GroupingHide

2.JB.Andorite VIAgPbSb3S6Orth. mm2 : Pmn21
2.JB.05DiaphoriteAg3Pb2Sb3S8Mon. 2/m : P21/b
2.JB.10CosalitePb2Bi2S5Orth. mmm (2/m 2/m 2/m)
2.JB.15FreieslebeniteAgPbSbS3Mon. 2/m : P21/b
2.JB.15MarriteAgPbAsS3Mon. 2/m : P21/b
2.JB.20CannizzaritePb48Bi56S132Mon. 2/m : P21/m
2.JB.20WittitePb9Bi12(S,Se)27Mon.
2.JB.25aJunoiteCu2Pb3Bi8(S,Se)16Mon. 2/m : B2/m
2.JB.25iNeyiteAg2Cu6Pb25Bi26S68Mon.
2.JB.25cNordströmiteCuPb3Bi7(Se4S10)Mon.
2.JB.25gNuffielditeCu1.4Pb2.4Bi2.4Sb0.2S7Orth.
2.JB.25dProuditeCuPb7.5Bi9.33(S,Se)22Mon. 2/m : B2/m
2.JB.25hWeibullitePb5Bi8Se7S11Orth.
2.JB.25bFelbertaliteCu2Pb6Bi8S19Mon. 2/m : B2/m
2.JB.25jRouxeliteCu2HgPb23Sb27S65.5Mon. 2/m : B2/m
2.JB.25fÁngelaiteCu2AgPbBiS4Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.25iCuproneyiteCu7Pb27Bi25S68Mon. 2/m : B2/m
2.JB.30aGeocronitePb14(Sb,As)6S23Mon. 2/m : P21/m
2.JB.30aJordanitePb14(As,Sb)6S23Mon. 2/m : P21/m
2.JB.30cTsugaruitePb28As15S50ClOrth.
2.JB.35cPillaitePb9Sb10S23ClO0.5Mon. 2/m : B2/m
2.JB.35aZinkenitePb9Sb22S42Hex. 6 : P63
2.JB.35bScainiitePb14Sb30S54O5Mon. 2/m : B2/m
2.JB.35dPellouxite(Cu,Ag)Pb10Sb12S27O(Cl,S)0.6Mon. 2/m : B2/m
2.JB.35fTubuliteAg2Pb22Sb20S53Mon. m : Pb
2.JB.35eChovanitePb15-2xSb14+2xS36Ox (x ~ 0.2)Mon. 2/m : B2/m
2.JB.40bAschamalmitePb6Bi2S9Mon. 2/m
2.JB.40aBursaitePb5Bi4S11 (?)Orth.
2.JB.40bEskimoiteAg7Pb10Bi15S36Mon.
2.JB.40aFizélyiteAg5Pb14Sb21S48Mon. 2/m
2.JB.40aGustaviteAgPbBi3S6Orth. mmm (2/m 2/m 2/m)
2.JB.40aLillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
2.JB.40cOurayiteAg3Pb4Bi5S13Orth.
2.JB.40aRamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
2.JB.40aRoshchiniteAg19Pb10Sb51S96Orth.
2.JB.40dSchirmeritePbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
2.JB.40aTreasuriteAg7Pb6Bi15S32Mon.
2.JB.40aUchucchacuaiteAgMnPb3Sb5S12Orth. mmm (2/m 2/m 2/m) : Pmmm
2.JB.40eUstarasitePb(Bi,Sb)6S10 (?)
2.JB.40aVikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
2.JB.40aXilingolitePb3Bi2S6Mon.
2.JB.40bHeyrovskýitePb6Bi2S9Orth. mmm (2/m 2/m 2/m) : Cccm
2.JB.40UM1988-05-S:AgBiCuHgPb(Hg,Ag,Cu,Pb)5Pb5Bi11S27
2.JB.40UM1988-06-S:AgBiCuHgPb(Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27
2.JB.40aAndorite IVPb18Ag15Sb47S96Mon. 2 : P2
2.JB.55GratonitePb9As4S15Trig. 3m : R3m
2.JB.60MarrucciiteHg3Pb16Sb18S46Mon. 2/m : B2/m
2.JB.65VurroitePb20Sn2(Bi,As)22S54Cl6Orth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

5.6.1SartoritePbAs2S4Mon. 2/m : P21/m
5.6.2DufrénoysitePb2As2S5Mon. 2 : P21
5.6.3LiveingitePb9As13S28Mon.
5.6.4BaumhaueritePb12As16S36Tric. 1 : P1
5.6.5GratonitePb9As4S15Trig. 3m : R3m
5.6.6JordanitePb14(As,Sb)6S23Mon. 2/m : P21/m
5.6.7FülöppitePb3Sb8S15Mon. 2/m : B2/b
5.6.8ZinkenitePb9Sb22S42Hex. 6 : P63
5.6.9PlagionitePb5Sb8S17Mon. 2/m
5.6.10HeteromorphitePb7Sb8S19Mon. 2/m : B2/b
5.6.11LaunayiteCuPb10(Sb,As)12S20Mon.
5.6.12PlayfairitePb16(Sb,As)19S44ClMon.
5.6.13SemseyitePb9Sb8S21Mon. 2/m : B2/b
5.6.14MadocitePb19(Sb,As)16S43Orth.
5.6.15BoulangeritePb5Sb4S11Mon. 2/m : P21/b
5.6.17RobinsonitePb4Sb6S13Mon. 2/m : P21/m
5.6.18GuettarditePbAsSbS4Mon. 2/m : P21/b
5.6.19Twinnite Pb0.8Tl0.1Sb1.3As0.8S4Mon. 2/m
5.6.20VeenitePb16Sb9-xAs7+xS40, x ~ 0-0.5Mon. 2 : P21
5.6.21SorbyiteCuPb9(Sb,As)11S26Mon. 2/m : B2/m
5.6.22GeocronitePb14(Sb,As)6S23Mon. 2/m : P21/m
5.6.23GalenobismutitePbBi2S4Orth. mmm (2/m 2/m 2/m)
5.6.24CosalitePb2Bi2S5Orth. mmm (2/m 2/m 2/m)
5.6.25CannizzaritePb48Bi56S132Mon. 2/m : P21/m
5.6.26LillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
5.6.27GiessenitePb27Cu2(Bi,Sb)19S57Mon. 2/m
5.6.28Platynite
5.6.29XilingolitePb3Bi2S6Mon.
5.6.30WeibullitePb5Bi8Se7S11Orth.
5.6.31WittitePb9Bi12(S,Se)27Mon.
5.6.33UstarasitePb(Bi,Sb)6S10 (?)

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for KirkiiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Walia, D.S., Chang, L.L.Y. (1973) Investigations in the systems PbS-Sb2S3-As2S3 and PbS-Bi2S3-As2S3. Canadian Mineralogist: 12: 113-119.
American Mineralogist (1986): 71: 1278-1279.
Anthony, Bideaux, Bladh & Nichols (1990), Handbook of Mineralogy, Vol. I.
Borodaev, Y.S., Garavelli, A., Kuzmina, O.V., Mozgova, N.N., Organova, N.I., Trubkin, N.V., Vurro, F. (1998) Rare sulfosalts from Vulcano, Aeolian Islands, Italy. I. Se-bearing kirkiite, Pb10(Bi,As)6(S,Se)19. Canadian Mineralogist: 36: 1105-1114.
Pinto, D. (2005) Mineralogy, crystal-chemistry and structures of sulfosalts from Vulcano (Aeolian Islands, Italy): Ag-free lillianite, Cl-bearing galenobismutite, kirkiite and the new mineral vurroite. Plinius: 31: 197-202.
Makovický, E., Balić-Žunić, T., Karanoviæ, L., Poleti, D. (2006) The crystal structure of kirkiite, Pb10Bi3As3S19: Canadian Mineralogist: 44(1): 177-188.
Pinto, D., Balić-Žunić, T., Garavelli, A., Garbarino, C., Makovický, E., Vurro, F. (2006) First occurrence of close-to-ideal kirkiite at Vulcano (Aeolian Islands, Italy): chemical data and single crystal X-ray study. European Journal of Mineralogy: 18: 393-401.

Internet Links for KirkiiteHide

Localities for KirkiiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Greece (TL)
 
  • East Macedonia and Thrace
    • Evros
      • Kirki Mines (Kirka)
European Journal of Mineralogy (1990): 2: 711-723.; American Mineralogist, Volume 71, pages 1277-1282, 1986; N. Skarpelis (1998) Bull. Geol Soc. Greece 33:51-60
Italy
 
  • Sicily
    • Messina Province
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
BORODAEV Y.S., GARAVELLI A., VURRO F., KUZMINA O., MOZGOVA N.N., ORGANOVA N.I., TRUBKIN N. (1998): Rare sulfosalts from Vulcano, Aeolian Islands, Italy - 1 - Se-bearing kirkiite, Pb10(Bi,As)6(S,Se)19 - Canadian Mineralogist - 36, 1105 -1114 .
Mexico
 
  • Chihuahua
    • Carmargo Municipality
      • Sierra de las Encinillas
Mike Scott S105203 from Cureton from Geomar ID by Dr SA Williams
 
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