Humberstonite
A valid IMA mineral species
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About Humberstonite
Formula:
Na7K3Mg2(SO4)6(NO3)2 · 6H2O
Colour:
Colorless
Lustre:
Vitreous
Hardness:
2½
Specific Gravity:
2.252
Crystal System:
Trigonal
Name:
Named in honor of James Thomas Humberstone (8 July 1850, Dover, England, UK - 12 June 1939, Iquique, Chile) chemist, who invented the Shanks System, a method to make sodium carbonate. He started the Peru Nitrate Company to extract saltpetre in the Tarapacá Province. The town of Humberstone, Chile, named after him, became part of a UNESCO World Heritage Site in 2005.
This page provides mineralogical data about Humberstonite.
Unique Identifiers
Mindat ID:
1944
Long-form identifier:
mindat:1:1:1944:2
GUID
(UUID V4):
(UUID V4):
d8c6ff70-f981-4f74-9aea-2c422bd0483a
IMA Classification of Humberstonite
Approved
IMA Formula:
K3Na7Mg2(SO4)6(NO3)2 · 6H2O
Approval year:
1967
First published:
1967
Classification of Humberstonite
7.DG.10
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3
32.2.2.1
32 : COMPOUND SULFATES
2 : Hydrated Compound Sulfates
32 : COMPOUND SULFATES
2 : Hydrated Compound Sulfates
13.10
13 : Nitrates
13 : Nitrates
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Hbe | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Humberstonite
Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{0001}
{0001}
Fracture:
Irregular/Uneven
Density:
2.252 g/cm3 (Measured) 2.252 g/cm3 (Calculated)
Optical Data of Humberstonite
Type:
Uniaxial (-)
RI values:
nω = 1.474(2) nε = 1.436(2)
Max Birefringence:
δ = 0.038
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Chemistry of Humberstonite
Mindat Formula:
Na7K3Mg2(SO4)6(NO3)2 · 6H2O
Crystallography of Humberstonite
Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 10.905(3) Å, c = 24.394(9) Å
Ratio:
a:c = 1 : 2.237
Unit Cell V:
2,512.26 ų (Calculated from Unit Cell)
Z:
3
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0005366 | Humberstonite | Burns P C, Hawthorne F C (1994) The crystal structure of humberstonite, a mixed sulfate-nitrate mineral The Canadian Mineralogist 32 381-385 | 1994 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.393 Å | (100) |
2.724 Å | (70) |
8.137 Å | (60) |
8.802 Å | (35) |
4.527 Å | (35) |
2.583 Å | (35) |
1.866 Å | (35) |
Comments:
Oficina Alemania, Chile. Data from the type description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
25 : Evaporites (prebiotic) | |
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47b : [Sulfates and sulfites] | |
47c : [Carbonates, phosphates, borates, nitrates] |
Type Occurrence of Humberstonite
General Appearance of Type Material:
Aggregates of thin, colorless, transparent, hexagonal-shaped crystals, up to 0.30 mm across.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, number USNM 120898.
Geological Setting of Type Material:
Playa salt deposits.
Associated Minerals at Type Locality:
Reference:
Ericksen, G.E., Fahey, J.J., Mrose, M.E. (1967) Humberstonite, Na7K3Mg2(SO4)6(NO3)2·6H2O: A new saline mineral from the Atacama Desert, Chile. Geological Society of America, Abstracts Annual Meetings: 1967: 59-59.
Synonyms of Humberstonite
Other Language Names for Humberstonite
Common Associates
Related Minerals - Strunz-mindat Grouping
7.DG. | Mathesiusite | K5(UO2)4(SO4)4(VO5) · 4H2O |
7.DG.05 | Darapskite | Na3(SO4)(NO3) · H2O |
7.DG.10 | Clinoungemachite | (Na, K, Fe, SO4) |
7.DG.10 | Ungemachite | K3Na8Fe(SO4)6(NO3)2 · 6H2O |
7.DG.15 | Bentorite | Ca6Cr2(SO4)3(OH)12 · 26H2O |
7.DG.15 | Charlesite | Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O |
7.DG.15 | Ettringite | Ca6Al2(SO4)3(OH)12 · 26H2O |
7.DG.15 | Jouravskite | Ca3Mn4+(SO4)(CO3)(OH)6 · 12H2O |
7.DG.15 | Sturmanite | Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12 · 25H2O |
7.DG.15 | Thaumasite | Ca3(SO4)[Si(OH)6](CO3) · 12H2O |
7.DG.15 | Carraraite | Ca3(SO4)[Ge(OH)6](CO3) · 12H2O |
7.DG.15 | Buryatite | Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O |
7.DG.15 | Birunite | Ca18(SiO3)8.5(CO3)8.5SO4 · 15H2O(?) |
7.DG.15 | Hielscherite | Ca3Si(SO4)(SO3)(OH)6 · 11H2O |
7.DG.15 | Kottenheimite | Ca 3Si(SO4)2(OH)6 · 12H2O |
7.DG.15 | Imayoshiite | Ca3Al(CO3)[B(OH)4](OH)6 · 12H2O |
7.DG.15 | Tatarinovite | Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O |
7.DG.15 | Siwaqaite | Ca6Al2(CrO4)3(OH)12 · 26H2O |
7.DG.15 | Chiyokoite | Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O |
7.DG.20 | Rapidcreekite | Ca2(SO4)(CO3) · 4H2O |
7.DG.25 | Tatarskite | Ca6Mg2(SO4)2(CO3)2(OH)4Cl4 · 7H2O |
7.DG.30 | Nakauriite | Cu8(SO4)4(CO3)(OH)6 · 48H2O |
7.DG.35 | Chessexite | (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O |
7.DG.40 | Carlosruizite | K6(Na,K)4Na6Mg10(SeO4)12(IO3)12 · 12H2O |
7.DG.40 | Fuenzalidaite | K6(Na,K)4Na6Mg10(SO4)12(IO3)12 · 12H2O |
7.DG.45 | Chelyabinskite | (Ca,Mg)3(SO4,CO3)2[Si(OH)6] · 9H2O (?) |
7.DG.55 | Ramazzoite | [Mg8Cu12(PO4)(CO3)4(OH)24(H2O)20][(H0.33SO4)3(H2O)36] |
7.DG.60 | Witzkeite | Na4K4Ca(NO3)2(SO4)4 · 2H2O |
Fluorescence of Humberstonite
none
Other Information
Notes:
Soluble in water and insoluble in acetone and ethyl alcohol.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Humberstonite
mindat.org URL:
https://www.mindat.org/min-1944.html
Please feel free to link to this page.
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References for Humberstonite
Reference List:
Mrose, Mary E., Fahey, Joseph J., Ericksen, and George E. (1970) Mineralogical studies of the nitrate deposits of Chile. III. Humberstonite. American Mineralogist, 55 (9-10) 1518-1533
Localities for Humberstonite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Chile (TL) | |
| Ericksen et al. (1967) |
| www.mineralatlas.com (2006) |
| Collao et al. (2002) |
Marta et al. (1996) +1 other reference | |
samples analysed by Gerhard Mohn and ... | |
China | |
| Okada et al. (1994) |
| Okada et al. (1994) |
| Yanling Tang (2005) |
Bingxiao Li (1992) +1 other reference | |
Okada et al. (1994) | |
| Yanling Tang (2005) |
Namibia | |
| Eckardt et al. (2010) |
Spain | |
| Benavente +2 other references |
| Benavente et al. (2018, September) |
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Oficina Alemania, Taltal, Antofagasta Province, Antofagasta, Chile